S1 singlet excited-state absorption of DODCI

1 excited-state absorption cross-section spectrum of DODCI in ethylene glycol is determined in the wavelength range from 500 nm to 750 nm. The S₁ state is populated by amplified femtosecond dye laser pulses (wavelength 592 nm) and the S₁-state absorption and emission behaviour is probed with a femtosecond light continuum. A general analysis procedure is developed to extract absolute excited-state absorption cross-sections from the measured transmissions. For DODCI in ethylene glycol the wavelength regions of saturable absorption (mode-locking application), reverse saturable absorption (optical limiter application), and effective stimulated emission (laser application) are determined. Received: 25 July 1996     

Theoretical analysis of pulse development in a colliding pulse mode-locked dye laser

The pulse development in colliding pulse mode-locked dye lasers is analysed theoretically. The chosen parameters belong to a c.w. argon laser pumped linear resonator arrangement with rhodamine 6G in ethylene glycol as gain medium and DODCI (3,3-diethyloxadicarbocyanine iodide) in ethylene glycol as saturable absorber. The pulse shortening and pulse broadening effects in the laser oscillator are investigated. The steady-state pulse duration is determined by equal pulse broadening and pulse shortening within a single resonator round-trip. The detuning of the absorber jet out of the middle position of the resonator is considered. Multiple transits through the resonator are simulated to study the influence of various resonator and dye parameters on the pulse development and the background signal suppression. Fast relaxations within theS ₁ andS ₀-state of DODCI are necessary for sufficient background suppression to obtain femtosecond pulse trains.     

Theoretical analysis of S1-state lifetime measurements of dyes with picosecond laser pulses

Various methods for the determination of the S₁-state lifetime of dye solutions (laser dyes and modelocking dyes) are analysed. A general model of interaction of laser light with dye molecules is presented and reduced to a dye energy level scheme of six levels. Fluorescence emission, light amplification and absorption recovery techniques are investigated theoretically and their limitations revealed. The determination of the S₁-state lifetime of saturable absorbers by single picosecond pulse bleaching experiments is very thoroughly discussed. The influence of various laser and dye parameters on the bleaching experiments are analysed numerically. The results are compared with isotropic steady state two- and three-level dye models.     

Tunable passively Q-switched ytterbium-doped fiber laser using MoWS2/rGO nanocomposite saturable absorber

We demonstrated a tunable Q-switched ytterbium-doped fiber laser (YDFL) using MoWS₂/rGO nanocomposite as passive saturable absorber. Further, the Mo_1?xW_xS₂/rGO nanosheets, with x proportion of 0.2, are synthesized using hydrothermal exfoliation technique. The proposed nanocomposite-PVA based thin film is fabricated by mixing the MoWS₂/rGO nanosheets with polyvinyl alcohol (PVA). The fabricated thin film is sandwiched between two fiber ferrules to realize the proposed saturable absorber (SA). Further, the proposed MoWS₂/rGO-PVA based thin film SA exhibits a fast relaxation time and a high damage threshold which are suitable to realize a Q-switched pulsed laser with a tunable wavelength range of 10?nm that extends from 1028?nm to 1038?nm. For the highest pump power of 267.4?mW, the generated Q-switched pulses exhibit a narrow pulse width of 1.22 μs, the pulse repetition rate of 90.4?kHz, the highest pulse energy of 2.13?nJ and its corresponding average power of 0.193?mW. To the best of author’s knowledge, this is the first realization of a tunable Q-switching fiber laser in a 1?μm wavelength using MoWS₂/rGO nanocomposite saturable absorber.     

Optimization of passively Q-switched laser with V:YAG saturable absorber

By considering the Gaussian spatial distributions of the intracavity photon density and the initial population-inversion density, the coupled rate equations for a diode-pumped passively Q-switched laser with V³⁺:YAG saturable absorber are given. These coupled rate equations are solved numerically and the key parameters of an optimally coupled passively Q-switched laser with V³⁺:YAG at 1342 nm are determined. These key parameters include the parameters of the gain medium, the saturable absorber and the resonator, which can maximize the pulse energy of singly Q-switched pulse. The optimal calculations for a diode-pumped passively Q-switched a-Nd:GdVO₄ laser with V³⁺:YAG saturable absorber are presented to demonstrate the numerical simulation applicable.     

Sn-state lifetime determination of dyes

The S _n -state lifetime is determined from two-step excited S _n -S₀fluorescence yield measurements with picosecond light pulses. The theoretical analysis includes single pulse and double pulse consecutive excitation and takes into account the anisotropy of excitation and emission. Experimental results of the single pulse two-step excitation technique are presented for the S₄-state lifetimes of the three mode-locking dyes 5, 9740 and 9860 for Nd-glass lasers.     

Steady state photoisomer accumulation in the absorber jet of the passively mode-locked femtosecond dye laser

In continuous were passively mode-locked dye lasers a steady state distribution of two isomers of the saturable absorber dye can be established. We report the first intracavity transmission measurement and estimation of the amount of the photoisomer of DODCI in the femtosecond CPM ring laser. Comparison with a simple model based on rate equations allows to estimate the quantum yield of a photo-back reaction. The obtained dependence of the photoisomer concentration on the laser wavelength and pulse energy can be used in theories describing the generation process for adequate estimation of its part in the modelocking regime.     

Optimization of pulse width of double passively Q-switched lasers with GaAs and Cr-doped saturable absorbers

Compared with a single passively Q-switched laser, a double passively Q-switched laser with a GaAs saturable absorber and a Cr⁴⁺-doped saturable absorber can produce more symmetric and shorter pulses with high pulse peak power. New normalized coupled rate equations for a double passively Q-switched laser with both a GaAs saturable absorber and a Cr⁴⁺-doped saturable absorber are solved numerically, where the single-photon absorption (SPA) and two-photon absorption (TPA) processes of GaAs are combined. The Gaussian spatial distributions of the intracavity photon density and the initial population-inversion density are considered. The optimization of a double passively Q-switched laser to obtain the shortest pulse width is performed, and a group of general curves are generated for the first time. The curves clearly show the dependence of the optimal normalized parameters on the parameters of the gain medium, the GaAs saturable absorber, the Cr⁴⁺-doped saturable absorber and the spatial distributions of the intracavity photon density. Sample calculations for a diode-pumped Nd³⁺:YVO₄ laser with both a GaAs saturable absorber and a Cr⁴⁺:YAG saturable absorber are presented to demonstrate the use of the curves and the related formulas.     

Spectroscopic and travelling-wave lasing characterisation of tetraphenylbenzidine and di-naphtalenyl-diphenylbenzidine

The organic light emitting diode (OLED) hole transport molecules N,N,N’,N’-tetraphenylbenzidine (TPB, triphenylamine dimer TAD or TPD) and N,N’-bis(2-naphtalenyl)-N,N’-bis(phenylbenzidine) (β-NPB, naphtyl-diphenylamine dimer β-NPD), dissolved in tetrahydrofuran (THF) and as neat film, are characterized by optical absorption and emission spectroscopy. The absorption and stimulated emission cross-section spectra, the fluorescence quantum distributions, fluorescence quantum yields, degrees of fluorescence polarization, and fluorescence lifetimes are determined. The lasing behaviour is studied by picosecond laser pulse excitation (excitation wavelength 347.15 nm, pulse duration 35 ps). The excited-state absorption at the pump laser wavelength is determined by saturable absorption measurement. Low-Q laser oscillation of TPB in THF is achieved by transverse pumping of the dye in a cell. The excited-state absorption of TPB in THF at the laser wavelength is extracted from the laser threshold. In TPB neat films, wave-guided travelling-wave lasing was obtained. No laser action was achieved for β-NPB because of small S₁-S₀ stimulated emission cross-section, and the presence of excited-state absorption in the fluorescence wavelength region. The TPB and β-NPB results are compared with the corresponding spectroscopic and lasing behaviour of the related methyl-substituted triphenylamine dimers, 3-methyl-TPD and 4-methyl-TPD, which are well established OLED hole transport materials.     

Ultrafast time-resolved photography of femtosecond laser induced modifications in BK7 glass and fused silica

The dynamics of absorption after excitation of fused silica and BK7 glass with femtosecond laser radiation are visualized by transient absorption spectroscopy. Focusing laser radiation with pulse durations in the picosecond time regime in BK7 glass generates free electrons with relaxation by emission of radiation or by formation of defects. The temporal and spatial emission characteristics are observed by high-speed photography in the streak mode. The beam waist moves within the pulse duration towards the incoming laser radiation by self-focusing and with the laser radiation absorbed by multi-photon processes. The dynamics of the long lasting stress formation is visualized by time-resolved Nomarski-Photography. The modification of the glass is investigated during and after irradiation with ultra-short pulsed laser radiation (100 fs<t_p<3 ps) at the wavelength =810 nm. The formation of a sound wave in fused silica and BK7 glass is observed and the mechanical stress, depending on the excitation pulse duration, is measured. PACS 06.60.Jn; 42.50.Md; 78.47.-p; 81.16.-c; 82.53.-k     

Strong-excitation and weak-excitation photodisintegration of DODCI

The disintegration yield of the organic dye DODCI dissolved in ethylene glycol and methanol due to cw excitation to the S1-state and due to intense picosecond pulse excitation to higher excited singlet states is determined. In the S1-state DODCI molecules disintegrate after about 5×104 excitation cycles while rhodamine 6G molecules in ethanol survive about 13×106 excitation cycles. In higher excited singlet states the DODCI molecules disintegrate on average after about 10 to 30 excitation cycles, while rhodamine 6G gets destroyed after about 140 excitation cycles.     

Optimization of the pulse energy of GaAs saturable absorber Q-switched lasers

By taking into account the single-photon absorption (SPA) and two-photon absorption (TPA) processes of GaAs, the Gaussian spatial distributions of the intracavity photon density and the initial population-inversion density, and the pumping and the spontaneous emission during the pulse formation, the new normalized rate equations of a GaAs saturable absorber Q-switched laser are solved. The key parameters of an optimally coupled GaAs saturable absorber Q-switched laser are determined, including the optimal normalized coupling parameter and the optimal normalized GaAs saturable absorber parameters, which can maximize the pulse energy, and a group of general curves are generated for the first time, which clearly show the dependence of the optimal key parameters on the parameters of the gain medium, the GaAs saturable absorber, and the resonator. In addition, the influence including the space variation, the pumping and the spontaneous emission is also shown. Sample calculations for a diode-pumped Nd³⁺:YVO₄ laser with a GaAs saturable absorber are presented to demonstrate the use of the curves and the relevant formulas.     

Specific features of the two-photon absorption of cationic symmetric polymethine dyes

The two-photon absorption of a number of cationic symmetric polymethine dyes based on 3H-indolium and benzothiazolium is experimentally studied upon excitation by nanosecond radiation from a Nd:YAG laser (1064 nm, 12 ns). The two-photon absorption cross section of dye molecules is determined by the two-quantum standard method. The influence of the spectral-luminescent properties and structure of the polymethine dyes on the two-photon absorption cross section is discussed. It is shown that, upon excitation in the range of the long-wavelength band of the dyes studied (the S ₀ → S ₁ transition), the maximum of their two-photon absorption is blue shifted. The reasons for a considerable increase in the two-photon absorption of symmetric polymethine dyes upon their excitation in the range of the S ₂ state are discussed. Using the data of quantum-chemical calculations, it is shown that, along with changes in the selection rules for two-photon transitions, this increase is connected with an increase in the size of the delocalized π electron cloud of HOMOs involved in the S ₀ → S ₂ transition.     

Optimization of diode-pumped passively Q-switched mode-locked c-cut Nd:GdVO4 laser with a GaAs saturable absorber

By considering the single-photon absorption (SPA) and two-photon absorption (TPA) processes in the GaAs saturable absorber, the coupled rate equations for a diode-pumped passively Q-switched and mode-locked (QML) laser with GaAs coupler under Gaussian approximation are given. The key parameters of an optimally coupled passively QML laser can be obtained by numerically solving these equations. These key parameters include the parameters of the gain medium, the saturable absorber and the resonator, which can maximize the pulse energy of singly Q-switched envelope. Sample calculations for a diode-pumped passively Q-switched mode-locked c-cut Nd:GdVO₄ laser with a GaAs saturable absorber are presented to demonstrate the optimal method applicable.     

Reflective carbon nanotube as the saturable absorber for mode-locked 1064 nm laser

With a reflective single-walled carbon nanotube as the saturable absorber, a laser diode-pumped passively mode-locked Nd:YVO₄ laser at 1064 nm was realized for the first time. The pulse duration of 12 ps was produced with a repetition rate of 83.7 MHz. The peak power and the single pulse energy of the mode-locking laser were 1.28 kW and 15.4 nJ, respectively.     

飞秒激光空气等离子体发射光谱的实验研究

对强飞秒激光聚焦在空气中所激发的等离子体的发射光谱进行了实验研究.结果表明,光谱特征表现为短波段(截至波长为340 nm)强烈的连续谱和长波段(波长在800 nm附近)强度相对较低的线光谱.在脉冲宽度(50 fs)保持不变而不断调节激光脉冲能量时,等离子体光谱形状的特征基本相似;当激光脉冲能量(1 mJ)保持不变而脉冲宽度从50 fs增加至500 fs和1 ps时,连续谱的峰值(500 nm)显得格外突出,并开始呈现出线光谱特征. 关键词： 飞秒激光 激光空气等离子体 发射光谱 线光谱     

Diode-pumped passively mode-locked Yb:LSO/SESAM laser

Diode-end-pumped passively mode-locked Yb³⁺:Lu₂SiO₅ (Yb:LSO) lasers both in the picosecond and the femtosecond regimes were demonstrated in this paper. The mode-locked lasers were initiated by using of semiconductor saturable absorber mirrors (SESAM). In the absence of intra-prisms for pulse compression, the laser emitted 1.6 W of output power with pulses width of about 4.3 ps. A pair of SF10 prisms was inserted into the laser cavity, pulses as short as 699 fs was generated around a center wavelength of 1043.6 nm with an average output power of 800 mW and a peak power of 11.0 kW.     

Femtosecond oscillator on Yb:KYW crystal pumped by laser diode with fiber output

A femtosecond laser based on an Yb:KYW crystal with direct longitudinal pumping by a high-power semiconductor injection laser with a fiber output is described. Femtosecond pulses were generated in the self-longitudinal-mode-locking operating condition due to the use of a semiconductor saturable absorber. The average power of the oscillator was as high as 3.5 W at a central wavelength of 1035 nm, the pulse length and pulse repetition rate being 200 fs and 85.5 MHz, respectively. The product of the pulse length and the radiation spectrum width was 1.3 times higher than the theoretical limit for the pulse shape described by the function sech². The designed master oscillator can be also used as a stand-alone source of femtosecond radiation pulses for material microprocessing and primary source for femtosecond laser amplification systems.     

Passive compression of KrCl excimer laser pulses in naphthalene solutions

The width of KrCl laser pulses has been compressed from 5.2 ns to less than 800 ps using naphthalene as the saturable absorber dye. It was found that the width of the compressed laser pulse decreased with both the input laser intensity and the concentration of naphthalene in the solution. The pulse shortening mechanism is attributed to excited state S₂-S_n transitions in naphthalene.     

Quantum-dot-based saturable absorber for femtosecond mode-locked operation of a solid-state laser

A quantum-dot-based saturable absorber has been demonstrated to initiate the generation of femtosecond pulses from a passively mode-locked solid-state laser. Control and tuning of the pulse duration from 58 ps to 158 fs was achieved. The 158 fs transform-limited pulses at 1280 nm are the shortest pulses that were produced from the Cr:forsterite laser passively mode locked by an InAs/InGaAs quantum-dot semiconductor saturable absorber mirror.