Diffusion in anisotropic porous media

An experimental system was constructed in order to measure the two distinct components of the effective diffusivity tensor in transversely isotropic, unconsolidated porous media. Measurements were made for porous media consisting of glass spheres, mica particles, and disks made from mylar sheets. Both the particle geometry and the void fraction of the porous media were determined experimentally, and theoretical calculations for the two components of the effective diffusivity tensor were carried out. The comparison between theory and experiment clearly indicates that the void fraction and particle geometry are insufficient to characterize the process of diffusion in anisotropic porous media. Roman Letters A interfacial area between - and -phases for the macroscopic system, m² - A _e area of entrances and exits of the -phase for the macroscopic system, m² - A interfacial area contained within the averaging volume, m² - a characteristic length of a particle, m - b average thickness of a particle, m - c _A concentration of species A, moles/m³ - c _o reference concentration of species A, moles/m³ - c _A intrinsic phase average concentration of species A, moles/m³ - c _a c _A–c _A, spatial deviation concentration of species A, moles/m³ - C c _A/c ₀, dimensionless concentration of species A - binary molecular diffusion coefficient, m²/s - D _eff effective diffusivity tensor, m²/s - D _xx component of the effective diffusivity tensor associated with diffusion parallel to the bedding plane, m²/s - D _yy component of the effective diffusivity tensor associated with diffusion perpendicular to the bedding plane, m²/s - D _eff effective diffusivity for isotropic systems, m₂/s - f vector field that maps c _A on to c _a , m - h depth of the mixing chamber, m     

A visualization study of the interaction of a free vortex with the wake behind an airfoil

The two-dimensional interaction of a single vortex with a thin symmetrical airfoil and its vortex wake has been investigated in a low turbulence wind tunnel having velocity of about 2 m/s in the measuring section. The flow Reynolds number based on the airfoil chord length was 4.5 × 10³. The investigation was carried out using a smoke-wire visualization technique with some support of standard hot-wire measurements. The experiment has proved that under certain conditions the vortex-airfoil-wake interaction leads to the formation of new vortices from the part of the wake positioned closely to the vortex. After the formation, the vortices rotate in the direction opposite to that of the incident vortex.List of symbols c test airfoil chord - C vortex generator airfoil chord - TA test airfoil - TE test airfoil trailing edge - TE _G vortex generator airfoil trailing edge - t dimensionless time-interval measured from the vortex passage by the test airfoil trailing edge: gDt=(T-T- _TE)·U/c - T time-interval measured from the start of VGA rotation - U free stream velocity - U vortex induced velocity fluctuation - VGA vortex generator airfoil - y distance in which the vortex passes the test airfoil - Z vortex circulation coefficient: Z=/(U · c/2) - vortex generator airfoil inclination angle - vortex circulation - vortex strength: =/2     

Bifurcation Phenomena from Standing Pulse Solutions in Some Reaction-Diffusion Systems

Bifurcation phenomena from standing pulse solutions of the problem is considered. (>0) is a sufficiently small parameter and is a positive one. It is shown that there exist two types of destabilization of standing pulse solutions when decreases. One is the appearance of travelling pulse solutions via the static bifurcation and the other is that of in-phase breathers via the Hopf bifurcation. Furthermore which type of destabilization occurs first with decreasing is discussed for the piecewise linear nonlinearities f and g.     

New concepts in relative permeabilities at high capillary numbers for surfactant flooding

Flooding oil reservoirs with surfactant solutions can increase the amount of oil that can be recovered. Macroscopic modelling of the process requires relative permeabilities to be functions of saturation and capillary number. With only limited experimental data, relative permeabilities have usually been assumed to be linear functions of saturation at high capillary numbers. The experimental data is reviewed, some of which suggest that this assumption is not necessarily correct. The basis for the assumption is therefore reviewed and it is concluded that the linear model corresponds to microscopically segregated flow in the porous medium. Based on new but equally plausible complementary assumptions about the flow pattern, a mixed flow model is derived. These models are then shown to be limiting cases of a droplet model which represents the mixing scale within the porous medium and gives a physical basis for interpolating between the models. The models are based on physical concepts of flow in a porous medium and so the approach described here represents a significant improvement in the understanding of high capillary number flow. This is shown by the fact that fewer parameters are needed to describe experimental data.Notation A total cross-sectional area assigned to capillary bundle - A ⁽ⁱ⁾ physical cross-sectional area of tube i - c ⁽ⁱ⁾ ordered configurational label for droplets in tube i - c configuration label for tube i (order not considered) - D defined by Equation (26) - E(...) expectation value with respect to the trinomial distribution - S _r ⁽⁾ fractional flow of phase - k absolute permeability - k _r relative permeability of phase - k _r ⁰ endpoint relative permeability of phase - L capillary tube length in bundle model - m ⁽ⁱ⁾ number of droplets of phase a occupying tube i - n exponent for phase a in Equation (2) - N number of droplets in bundle model - N _c capillary number - p pressure - p(c') probability of configuration c - Q ⁽ⁱ⁾ total volume flow rate in tube i - S saturation of phase - S flowing saturation of phase - S _r residual saturation of phase - S _r ⁽⁾ saturations when fractional flow of phase is 1 in the case of varying residual saturations for three-phase flow ( ) - t _c residence time for droplet configuration c - v ⁽ⁱ⁾ total fluid velocity in bundle tube i - , phase label - p pressure differential across capillary bundle - ⁽ⁱ⁾ tube conductivity defined by Equation (7) - viscosity of phase - interfacial tension - gradient operator - ... average over tube droplet configurations     

Extended Korn's inequalities and the associated best possible constants

We are concerned with the coerciveness of the strain energy E(u) (in linear elasticity) associated with a displacement vector u on the Sobolev space H¹ () or its subspaces, a domain in ⁿ representing an isotropic elastic body—certain specific cases are called Korn's inequalities. Sufficient (and necessary) conditions on the Lamé moduli for E(·) to be coercive (or uniformly positive) on such spaces are given, and the associated best possible constants are obtained for some cases.     

Uniqueness and the maximum principle for quasilinear elliptic equations with quadratic growth conditions

In this paper, we show that the maximum principle holds for quasilinear elliptic equations with quadratic growth under general structure conditions.Two typical particular cases of our results are the following. On one hand, we prove that the equation (1) {ie77-01} where {ie77-02} and {ie77-03} satisfies the maximum principle for solutions in H ¹()L(), i.e., that two solutions u ₁, u ₂H¹() L() of (1) such that u ₁u₂ on , satisfy u ₁u₂ in . This implies in particular the uniqueness of the solution of (1) in H ₀ ¹ ()L().On the other hand, we prove that the equation (2) {ie77-04} where fH^–1() and g(u)>0, g(0)=0, satisfies the maximum principle for solutions uH¹() such that g(u)¦Du|{²L¹(). Again this implies the uniqueness of the solution of (2) in the class uH ₀ ¹ () with g(u)¦Du|{²L¹().In both cases, the method of proof consists in making a certain change of function u=(v) in equation (1) or (2), and in proving that the transformed equation, which is of the form (3) {ie77-05}satisfies a certain structure condition, which using ((v₁ -v ₂)⁺)ⁿ for some n>0 as a test function, allows us to prove the maximum principle.     

Flow of soft solids squeezed between planar and spherical surfaces

The force to squeeze a Herschel–Bulkley material without slip between two approaching surfaces of various curvature is calculated. The Herschel–Bulkley yield stress requires an infinite force to make plane–plane and plane–concave surfaces touch. However, for plane–convex surfaces this force is finite, which suggests experiments to access the mesoscopic thickness region (1–100 m) of non-Newtonian materials using squeeze flow between a plate and a convex lens. Compared to the plane–parallel surfaces that are used most often for squeeze flow, the dependence of the separation h and approach speed V on the squeezing-time is more complicated. However, when the surfaces become close, a simplification occurs and the near-contact approach speed is found to vary as V h⁰ if the Herschel–Bulkley index is n<1/3, and V h^(3n-1)/(2n) if n 1/3. Using both plane–plane and plane–convex surfaces, concordant measurements are made of the Herschel–Bulkley index n and yield stress ₀ for two soft solids. Good agreement is also found between ₀ measured by the vane and by each squeeze-flow method. However, one of the materials shows a limiting separation and a V(h) behaviour not predicted by theory for h<10 m, possibly owing to an interparticle structure of similar lengthscale.     

Calculation of the pressure on the side surface of bodies consisting of a spherical segment joined to an inverted cone in a supersonic stream

The results of investigations of inviscid flow over inverted cones with nose consisting of a spherical segment were published for the first time in Soviet literature in [1–4]. In the present paper, a numerical solution to this problem is obtained using the improved algorithms of [5, 6], which have proved themselves well in problems of exterior flow over surfaces with positive angles of inclination to the oncoming flow. It is shown that the Mach number 2 M , equilibrium and nonequilibrium physicochemical transformations in air (H = 60 km, V = 7.4 km/sec, R₀ = 1 m), and the angle of attack 0 40° influence the investigated pressure distributions. A comparison of the results of the calculations with drainage experiments for M = 6, = 0-25° confirms the extended region of applicability of the developed numerical methods. Also proposed is a simple correlation of the dependence on the Mach number in the range 1.5 M of the shape of the shock wave near a sphere in a stream of ideal gas with adiabatic exponent = 1.4.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 178–183, January–February, 1981.     

Inertial Manifolds on Squeezed Domains

Let be an arbitrary smooth bounded domain in and > 0 be arbitrary. Squeeze by the factor in the y-direction to obtain the squeezed domain = {(x,y)(x,y)}. In this paper we study the family of reaction-diffusion equations

Representation of the rheological properties of polymer melts in terms of complex fluidity

In dynamic rheological experiments melt behavior is usually expressed in terms of complex viscosity ^* () or complex modulusG ^* (). In contrast, we attempted to use the complex fluidity ^* () = 1/µ ^* () to represent this behavior. The main interest is to simplify the complex-plane diagram and to simplify the determination of fundamental parameters such as the Newtonian viscosity or the parameter of relaxation-time distribution when a Cole-Cole type distribution can be applied. ^* () complex shear viscosity - () real part of the complex viscosity - () imaginary part of the complex viscosity - G ^* () complex shear modulus - G() storage modulus in shear - G() loss modulus in shear - J ^* () complex shear compliance - J() storage compliance in shear - J() loss compliance in shear - shear strain - rate of strain - angular frequency (rad/s) - shear stress - loss angle - ^* () complex shear fluidity - () real part of the complex fluidity - () imaginary part of the complex fluidity - ₀ zero-viscosity - ₀ average relaxation time - h parameter of relaxation-time distribution     

An exact solution for non-darcy free convection from a horizontal line source of heat

In this paper we consider the free convection from a horizontal line source of heat which is embedded in an unbounded porous medium saturated with a fluid at rest under gravity. The convective fluid and the porous medium are in local thermal equilibrium.

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Eine exakte Lösung der nicht-darcy'schen freien Konvektion von einer horizontalen, linienförmigen Wärmequelle

Zusammenfassung In dem Aufsatz wird die freie Konvektion von einer horizontalen, linienförmigen Wärmequelle untersucht, die in ein unbegrenztes poröses Medium eingebettet ist. Die Poren des porösen Mediums sind mit einem Fluid gefüllt, das unter Schwerkrafteinfluß ruht. Das strömende Fluid und das poröse Medium sind örtlich im thermischen Gleichgewicht.

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Nomenclature c _p specific heat of convective fluid - F _o parameter,=/(vl>g - g acceleration due to gravity - k thermal conductivity of the saturated porous medium - l typical length scale of body - Q heat flux per unit length of a line source - Ra Rayleigh number, =gQl/²c_p - Ra _x local Rayleigh number, =xg Qx/ a²c_p - T temperature - T temperature of ambient fluid - u, x andy components of velocity - x, y coordinates vertically upwards and normal to axis of plume - X, Y non-dimensional coordinates vertically upwards and normal to axis of plume Greek symbols equivalent themal diffusivity - coefficient of thermal expansion - similarity variable - non-dimensional temperature - x permeability of porous medium - viscosity of convective fluid - v kinematic viscosity of convective fluid - density of convective fluid - stream function - non-dimensional stream function - the Forchheimer's coefficient     

Anwendung des Übertragungsverfahrens bei stark abklingenden Lösungsfunktionen

Übersicht Bei stark abklingenden Funktionen wird die Übertragungsmatrix U() aufgespalten in die Anteilc U ₁() e^– und U ₂() e. Der zweite Term spielt am Rand = 0 keinc Rolle. Die unbekannten Anfangswerte sind über die Matrix U ₁(0) an die bekannten gebunden und eindeutig bestimmbar.

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Summary For strongly decaying solution functions the transfer matrix U() is splitted into the parts U ₁() e^– and U ₂() e. The second term does not influence at the boundary = 0. The unknown initial values are related by the matrix U ₁(0) to the known values and they can be uniquely determined.

     

The wedge subjected to tractions: a paradox resolved

The classical two-dimensional solution provided by Lévy for the stress distribution in an elastic wedge, loaded by a uniform pressure on one face, becomes infinite when the opening angle 2 of the wedge satisfies the equation tan 2 = 2. Such pathological behavior prompted the investigation in this paper of the stresses and displacements that are induced by tractions of O(r ^–) as r0. The key point is to choose an Airy stress function which generates stresses capable of accommodating unrestricted loading. Fortunately conditions can be derived which pre-determine the form of the necessary Airy stress function. The results show that inhomogeneous boundary conditions can induce stresses of O(r ^–), O(r ^– ln r), or O(r ^– ln² r) as r0, depending on which conditions are satisfied. The stress function used by Williams is sufficient only if the induced stress and displacement behavior is of the power type. The wedge loaded by uniform antisymmetric shear tractions is shown in this paper to exhibit stresses of O(ln r) as r0 for the half-plane or crack geometry. At the critical opening angle 2, uniform antisymmetric normal and symmetric shear tractions also induce the above type of stress singularity. No anticipating such stresses, Lévy used an insufficiently general Airy stress function that led to the observed pathological behavior at 2.     

Gasdynamics of a plasma in a multiple-mirror magnetic trap with “point” mirrors

Equations are derived for the gasdynamics of a dense plasma confined by a multiple-mirror magnetic field. The limiting cases of large and small mean free paths have been analyzed earlier: ₀ and k, where is the length of an individual mirror machine, ₀ is the size of the mirror, and k is the mirror ratio. The present work is devoted to a study of the intermediate range of mean free paths ₀ k. It is shown that in this region of the parameters the process of expansion of the plasma has a diffusional nature, and the coefficients of transfer of the plasma along the magnetic field are calculated.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 6, pp. 14–19, November–December, 1974.The authors thank D. D. Ryutov for the statement of the problem and interest in the work.     

Asymptotic behavior of solutions of nonlinear elliptic equations

We study and obtain formulas for the asymptotic behavior as ¦x¦ of C ² solutions of the semilinear equation u=f(x, u), x (*) where is the complement of some ball in ⁿ and f is continuous and nonlinear in u. If, for large x, f is nearly radially symmetric in x, we give conditions under which each positive solution of (*) is asymptotic, as ¦x¦, to some radially symmetric function. Our results can also be useful when f is only bounded above or below by a function which is radially symmetric in x or when the solution oscillates in sign. Examples when f has power-like growth or exponential growth in the variables x and u usefully illustrate our results.     

Thermal free convection from a solid sphere

Summary Thermal free convection from a sphere has been studied by melting solid benzene spheres in excess liquid benzene (Pr=8,3; 10⁸<Gr<10⁹). Overall heat transfer as well as local heat transfer were investigated. For the effect of cold liquid produced by the melting a correction has been applied. Results are compared with those obtained by other workers who used alternative experimental methods.Nomenclature coefficient of heat transfer - d characteristic length, here diameter of sphere - thermal conductivity - g acceleration of free fall - cubic expansion coefficient - T temperature difference between wall and fluid at infinity - kinematic viscosity - density - c specific heat capacity - a thermal diffusivity (=/c) - D diffusion coefficient - Nu dimensionless Nusselt number (=d/) - Nu* the analogous number for mass transfer (=kd/D) - mean value of Nusselt number - Gr dimensionless Grashof number (=gd ³T/ ²) - Gr* the analogous number for mass transfer (=gd ³x/ ²) - Pr dimensionless Prandtl number (=/a) - Sc dimensionless Schmidt number (=/D)     

An experimental study of the lateral migration of a droplet in a creeping flow

The distribution of droplets in a plane Hagen-Poiseuille flow of dilute suspensions has been measured by a special LDA technique. This method assumes a well defined relation between the velocity of the droplets and their lateral position in the channel. The measurements have shown that the droplet distribution is non-uniform and depends on the viscosity ratio between the droplets and the carrier liquid. The results have been compared with a theory by Chan and Leal describing the lateral migration of suspended droplets.List of symbols a particle radius, m - d half width of the channel, m - Re flow Reynolds number, = 2 _m · d · /µ - flow velocity, m/s - _m flow velocity at the channel axis, m/s - We Weber number, = 2 _m ^Emphasis>/2 · d · / - x distance from center line (x = 0) of the channel, m - non-dimensional distance from the channel center line, _x ^d - y distance along the channel (y = 0 at channel inlet), m - non-dimensional distance along the channel, = y/2d - non-dimensional, normalized distance along the channel, = · _m · µ/ - interfacial tension, N/m - viscosity ratio of dispersed (droplet) phase to viscosity of continuous phase - µ viscosity of continuous phase, Pa · s - density of continuous phase, kg/m³ - phase density difference, kg/m³ Experiments were performed at Max-Planck-Institut, Göttingen     

Eine analytische Näherungslösung für die eingefrorene laminare Grenzschichtströmung eines binären Gemisches

Zusammenfassung Für die eingefrorene laminare Grenzschichtströmung eines teilweise dissoziierten binären Gemisches entlang einer stark gekühlten ebenen Platte wird eine analytische Näherungslösung angegeben. Danach läßt sich die Wandkonzentration als universelle Funktion der Damköhler-Zahl der Oberflächenreaktion angeben. Für das analytisch darstellbare Konzentrationsprofil stellt die Damköhler-Zahl den Formparameter dar. Die Wärmestromdichte an der Wand bestehend aus einem Wärmeleitungs- und einem Diffusionsanteil wird angegeben und diskutiert. Das Verhältnis beider Anteile läßt sich bei gegebenen Randbedingungen als Funktion der Damköhler-Zahl ausdrücken.

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An analytical approximation for the frozen laminar boundary layer flow of a binary mixture

An analytical approximation is derived for the frozen laminar boundary layer flow of a partially dissociated binary mixture along a strongly cooled flat plate. The concentration at the wall is shown to be a universal function of the Damkohler-number for the wall reaction. The Damkohlernumber also serves as a parameter of shape for the concentration profile which is presented in analytical form. The heat transfer at the wall depending on a conduction and a diffusion flux is derived and discussed. The ratio of these fluxes is expressed as a function of the Damkohler-number if the boundary conditions are known.

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Formelzeichen A Atom - A₂ Molekül - C Konstante in Gl. (20) - c₁=1/(2C) Konstante in Gl. (35) - c_p spezifische Wärme bei konstantem Druck - D binärer Diffusionskoeffizient - Ec=u ² /(2h_f) Eckert-Zahl - h spezifische Enthalpie - h_t=h+u²/2 totale spezifische Enthalpie - h _A ⁰ spezifische Dissoziationsenthalpie - K_w Reaktionsgeschwindigkeitskonstante der heterogenen Wandreaktion - 1= /( ) Champman-Rubesin-Parameter - Le=Pr/Sc Lewis-Zahl - M Molmasse - p statischer Druck - Pr= c_pf/ Prandtl-Zahl - q_w Wärmestromdichte an der Wand - q_cw, q_dw Wärmeleitungsbzw. Diffusionsanteil der Wärmestromdichte an der Wand - universelle Gaskonstante - R=/(2M_a) individuelle Gaskonstante der molekularen Komponente - Re_x= u x/ Reynolds-Zahl - Sc=/( D) Schmidt-Zahl - T absolute Temperatur - T_d=h _A ⁰ /R charakteristische Dissoziationstemperatur - u, v x- und y-Komponenten der Geschwindigkeit - U=u/u normierte x-Komponente der Geschwindigkeit - x, y Koordinaten parallel und senkrecht zur Platte Griechische Symbole - =A/ Dissoziationsgrad - Grenzschichtdicke - ₂ Impulsverlustdicke - Damköhler-Zahl der Oberflächenreaktion - =T/T normierte Temperatur - =y/ normierter Wandabstand - Wärmeleitfähigkeit - dynamische Viskosität - , ^* Ähnlichkeitskoordinaten - Dichte - Schubspannung Indizes A auf ein Atom bezogen - M auf ein Molekül bezogen - f auf den eingefrorenen Zustand bezogen - w auf die Wand bezogen - auf den Außenrand der Grenzschicht bezogen     

Finite element simulation of solidification problems

The modelling of liquid-solid phase change phenomena is extremely important in many areas of science and engineering. In particular, the solidification of molten metals during various casting methods in the foundry, provides a source of important practical problems which may be resolved economically with the aid of computational models of the heat transfer processes involved. Experimental design analysis is often prohibitively expensive, and the geometries and complex boundary conditions encountered preclude any analytical solutions to the problems posed. Thus the motivation for numerical simulation and computer aided design (CAD) systems is clear, and several mathematical/computational modelling techniques have been brought to bear in this area during recent years.This paper reports on the application of the finite element method to solidification problems, principally concerning industrial casting processes. Although convective heat transfer has been modelled, the work herein considers only heat conduction, for clarity. The heat transfer model has also been coupled with thermal stress analysis packages to predict mechanical behaviour including cracking and eventual failure, but this is reported elsewhere.Following the introduction, the mathematical and computational modelling tools are described in detail, for completeness. A discussion on the handling of the phase change interface and latent heat effects is then presented. Some aspects of the solution procedures are examined next, together with special techniques for dealing with the mold-metal interface. Finally, some numerical examples are presented which substantiate the capabilities of the finite element model, in both two and three dimensions.Nomenclature c heat capacity - C capacitance matrix - f time function - F loading term - h heat convection coefficient - H specific enthalpy - |J| Jacobian determinant - || patch approximation to |J| - k thermal conductivity - K conductance matrix - L latent heat - unit outward normal - N _i nodal shape function - q known heat flux - R _i nodal heat capacity - S phase change interface - t time - T temperature - known boundary temperature - T vector of nodal temperatures - T _a ambient temperature - T _c solidification temperature - T _L liquidus temperature - T ₀ initial temperature - T _s solidus temperature - x space coordinates - interface heat transfer coefficient - iteration parameter - boundary of domain - T solidification range - t timestep magnitude - vector gradient operator - convergence tolerance - timestepping parameter - t known vector in alternating-direction formulation - Laplace modifying parameter - (, ) local space coordinates - density - time limit - () shape function factor - () shape function factor - domain of interest     

Stochastic response of structures with small geometric imperfections

Summary A probabilistic model of the geometric imperfections of a real structure is proposed, in order to provide a general theory of the stochastic response of structures in presence of small random deviations from the perfect scheme. The main statistical measures of the stochastic response are derived and an application to the study of a particular conservative elastic system is developed.

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Sommario Si propone una teoria generale della risposta probabilistica di strutture, in presenza di piccole deviazioni aleatorie dei dati iniziali rispetto allo schema geometrico perfetto. Si deducono le principali proprietà statistiche della risposta della struttura a sollecitazioni esterne deterministiche, e si sviluppa una applicazione riguardante il comportamento aleatorio di un particolare sistema elastico conservativo.

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List of symbols element of the sample space of events - _kn random variables modelling the structural imperfections - P(o) probability density of random variables - random imperfection of the unloaded structure - u additional displacement of the loaded structure - u_o deterministic fundamental solution for the perfect structure - difference between the additional displacement of the loaded structure and the deterministic fundamental solution for the perfect structure - V₁=u₁ buckling mode of the perfect structure - _i intrinsic coordinates of the structure - suitable measure of the magnitude of the random imperfections - scalar geometric variable representing the internal product - random imperfection divided by - single scalar variable denoting the magnitude of the prescribed loads - potential energy of the structure - potential energy of the perfect structure - difference between and - _c lowest critical load - _s real local maximum for the magnitude of the prescribed loads - _c divided by _S - E{} expected value of a random variable - ² variance of a random variable - , random variables defined by Eq. (21)