Electrohydraulic effect in water-plant heterodisperse systems I. Compositions of the solid residue and the aqueous phase

The electrohydraulic (EH) treatment of water-plant heterodisperse systems leads to the partial degradation of the main components of the plant materials: lignin, cellulose, and carbohydrates. The presence of p-hydroxyphenyl and guaiacyl structures has been established on the basis of the results of the GLC analysis of the ether-extracted phenolic products of plant materials subjected to EH treatment. It has been shown that part of the carbohydrates passes into the aqueous phase in the form of free monosaccharides: pentoses and hexoses.Institute of Chemistry of Plant Substances of Uzbekistan Academy of Sciences, Tashkent. Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk. Siberian Institute of Terrestrial Magnetism, the Ionosphere, and the Propagation of Radio Waves, Siberian Branch, Russian Academy of Sciences, Irkutsk. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 707–711, November–December, 1992.     

Crystal structure of 1,2-bis-(phenylseleno)-1,2-dichlorethene

Vladimir State Pedagogical Institute. Institute for Elementorganic Compounds, Russian Academy of Sciences. Irkutsk Institute for Organic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated from Zhurnal Strukturnoi Khimii, Vol. 33, No. 4, pp. 153–154, July–August, 1992.     

Dealkylation of dialkyl chalgogenides by the action of alkanechalcogenolate anions

Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 664033 Irkutsk. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 10 pp. 2456–2457, October, 1992.     

Unexpected reaction of 2-mercaptoquinoline with 4-hydroxy-4-methyl-2-pentynenitrile

Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1694–1695, December, 1995. Original article submitted November 21. 1995.     

Electrohydraulic effect in water-plant heterodisperse systems I. Compositions of the solid residue and the aqueous phase

The electrohydraulic (EH) treatment of water-plant heterodisperse systems leads to the partial degradation of the main components of the plant materials: lignin, cellulose, and carbohydrates. The presence of p-hydroxyphenyl and guaiacyl structures has been established on the basis of the results of the GLC analysis of the ether-extracted phenolic products of plant materials subjected to EH treatment. It has been shown that part of the carbohydrates passes into the aqueous phase in the form of free monosaccharides: pentoses and hexoses. Institute of Chemistry of Plant Substances of Uzbekistan Academy of Sciences, Tashkent. Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk. Siberian Institute of Terrestrial Magnetism, the Ionosphere, and the Propagation of Radio Waves, Siberian Branch, Russian Academy of Sciences, Irkutsk. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 707–711, November–December, 1992.     

X-ray spectral investigation of the redistribution of electron density during complexation

Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated from Zhurnal Strukturnoi Khimii, Vol. 33, No. 2, pp. 67–78, March–April, 1992.     

Reaction of benzothiazol-2-one with 4-hydroxy-4-methyl-2-pentynonitrile

Reaction between the title compounds gave the unexpected 3-[5,5-dimethyl-2,5-dihydrofur-4-yl-2-(3-isopropanol-2-propenonitrile)imino]benzothiazol-2-one, as a result of the addition of two cyanoacetylene molecules.Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 4, pp. 1003–1005, April, 1992.     

Crystal structure investigation of ternary molybdates Li3Ba2Ln3(MoO4)3 (Ln=Gd,Tm)

Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Institute of Physics, Siberian Branch, Russian Academy of Sciences. Buryat Institute of Natural Sciences, Siberian Branch, Russian Academy of Sciences. Translated from Zhurnal Strukturnoi Khimii, Vol. 33, No. 3, pp. 126–130, May–June, 1992.     

Transformation of aromatic compounds under the action of the basidiomycetesPhanerochaete sanguinea andCoriolus villosus

The pathways of the transformation of some aromatic compounds by rhe basidiomycetesPhanerochaete sanguinea andCoriolus villosus have been studied. It has been shown that the degradation of these compounds has an oxidative nature and depends on the type of substituents in the benzene ring and the propane chain. A difference has been found in the mechanisms of the reactions of the two fungi that is a consequence of the different compositions of their enzyme complexes.Wood Chemistry Division, Institute of Organic Chemistry, Siberian Division of the Russian Academy of Sciences, Irkutsk. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 808–819, November–December, 1994.     

Thermal methods for the synthesis of thiophene, selenophene, and their derivatives. (Review)

The literature data concerned with thermal reactions producing thiophene, selenophene, and their derivatives are systematized and reviewed. The mechanisms of these reactions are examined and conditions for the formation of thiophene and selenophene heterocycles are formulated.Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664039, Russia; e-mail: vlad@irioch.ira.ru. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 3–18, January, 2000.     

Carbohydrates,carbohydrate ethers,and alcohols of Salsola collina

Institute of Organic Chemistry; Siberian Institute of Plant Physiology and Biochemistry, Siberian Branches, Academy of Sciences of the USSR, Irkutsk. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 420–421, May–June, 1991.     

Reaction of lithioalkoxyallenes with isothio-cyanates: Synthesis of pyrroles and 5,6-dihydropyridines

We have found a novel synthesis route for 2,3-disubstituted pyrroles and 5,6-dihydropyridines, starting from lithiated alkoxyallenes, and organic isothiocyanates.Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033. Preparative Organic Chemistry Group, Utrecht University, The Netherlands. Translated from Khimya Geterotsiklicheskikh Soedinenii, Vol. 32, No. 7, pp. 917–918, July, 1996. Original article submitted April 17, 1996.     

Chemical composition of Potentilla fruitcosa III. Flavonoids and free sterols

Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Irkutsk. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 285–286, March–April, 1991.     

Reaction of 3-thiolene 1,1-dioxide with PH-acids

The nucleophilic addition of 2-phenylethylphosphine, bis(2-phenylethyl)phosphine oxide, and bis(2-phenylpropyl)phosphine oxide to 3-thiolene 1,1-dioxide catalyzed by the KOH-DMSO system leads to bis(3-thioanil) (2-phenylethyl)phosphine oxide, bis(2-phenylethyl) (3-thianil)phosphine oxide, and bis(2-phenylpropyl) (3-thioanil)phosphine oxide, respectively.Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033 Irkutsk. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1195–1198, September, 1998.     

First example of the formation of highly ordered supermolecular structures in a series of gibberellin derivatives

The 3-O-palmitate and 3-O-tridecanoate of gibberellin A₃ have been synthesized and monomolecular Langmuir-Blodgett films have been obtained from them.Novosibirsk Institute of Organic Chemistry, Siberian Division of the Russian Academy of Sciences. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 793–795, November–December, 1994.     

Selective synthesis of di(propen-1-yl)sulfone and di(propen-1-yl)sulfoxide

Convenient selective methods of synthesis of the title compounds, based on oxidation of di(propen-1-yl)sulfide with 30% H₂O₂, have been developed.Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 664033 Irkutsk. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 675–679, March, 1992.     

Interpretation of photoelectron spectra in the AM1 semiempirical method. 3. 2-Substituted benzimidazoles

Analysis of photoelectron spectra of 2-substituted benzimidazoles showed that their orbital structure is determined by the form and energy position of the fragment orbital (-symmetry) of the substituent.For previous communication, see [1].Irkutsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk 664033. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 4, pp. 880–884, April, 1992.     

Ultraviolet absorption of flavonoids VI. Protonation constants of some dihydroxyflavones

Summary The protonation (basicity) constants of six disubstituted flavones have been determined by the spectrophotometric method.Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 587–590, September–October, 1975.     

Influence of structural factors on delocalization of spin density in nitroxyl radicals of the imidazoline series

Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated from Zhurnal Strukturnoi Khimii, Vol. 32, No. 6, pp. 42–51, November–December, 1991.