电化学获奖人优秀论文专辑序言

2018年是电化学专业委员会成立30周年. 30年来,中国的电化学事业取得了巨大发展,国际学术交流越来越频繁,研究水平业已跻身国际前列,在全球电化学学术领域占有重要一席之地. 在我国广大电化学工作者和国际同行的支持下,中国电化学科学的专业学术期刊——《电化学》也正在茁壮成长,成为我国科学研究的重要核心刊物. 　　 2017年在上海成功召开了两年一度的全国性学术会议——第19届全国电化学大会,围绕电化学科学和技术发展中的基础、应用和前沿问题,全面展示了中国电化学领域所取得的最新研究进展和成果,深入探讨了电化学领域所面临的机遇、挑战和未来发展方向,加强了科研合作和技术转化,必将进一步推动中国电化学学科的发展和进步. 　　 大会还颁发了系列重要奖项,其中中国电化学成就奖授予中国科学院长春应用化学研究所汪尔康院士,中国电化学贡献奖授予厦门大学杨勇教授和中国科学院大连化学物理研究所张华民教授、中国电化学青年奖授予复旦大学王永刚教授、苏州大学黄小青教授、中国科学院化学所胡劲松研究员和北京大学郭少军教授. 　　为了鼓励和支持中国学者——尤其是中青年学者——在《电化学》上发表高质量论文,办好我们中国人自己的电化学学术期刊,2015年《电化学》期刊名誉主编田昭武院士提议并设立《电化学》期刊优秀论文奖. 本届《电化学》期刊优秀论文奖授予重庆大学魏子栋教授、厦门大学毛秉伟教授、武汉大学庄林教授、辽宁科技大学陈星星教授和华北电力大学谭占鳌教授. 　　 为促进学术交流、提高办刊质量,《电化学》编辑部特邀此次大会上获奖的八位学者,撰写论文报道其最新进展研究. 本专辑基本反映了我国电化学学科在能源、环境和材料方面具有代表性的研究进展. 希望借助专辑的出版,能使广大读者了解我国电化学领域的研究现状、发展趋势和存在的问题及挑战,进一步提高《电化学》的学术影响力,推动我国电化学科学的发展. 　　 在此,对本专辑的所有作者、审稿人及编辑部工作人员的辛勤劳动表示衷心的感谢！衷心感谢广大电化学工作者对《电化学》的支持！     

Editorial 2006

Dear Authors and Readers, The year 2005 was a specially remarkable year filled with much excitement, success, joy and sadness. The new format of the Journal proved to meet everybody's satisfaction. It is much easier to read, and the figures and tables are better positioned as there is more space to accommodate them. Not only did we change the appearance, but we have restructured the leading body of the Journal reorganizing the former Editorial Board and assigning Associate Editors according to main subject areas. With this solution proved to be a much more operational and practical one, and contributed to the increase of the scientific level of the Journal. It is a commonplace, that we live in a more and more specialised world. This trend is palpable in thermal analysis and we can experience it as we receive submissions dealing with very specialised topics. In order to strengthen our peer-review system, we hoped that the decision to divide the Associate Editors into main subject areas, will assist them in their work to establish and build a network of support reviewers from that particular field. After a year we can already see the result of this effort and we are very happy to look at the longer-than-ever list of reviewers we acknowledge for their scientific support (find the list of names on the next pages). Here I need to complement you all, as I am convinced that your enthusiastic and conscientious work is the foundation of our success, as it is reflected in the Impact Factor 2004 reaching the unprecedented height of 1.478 compared to 1.094 for 2003. Last but not least the novelty of 2005 was the introduction of the 'Online First' section on the electronic site of JTAC. We have fought for the opportunity to provide better service to our authors in terms of through-over-time for long and this solution finally offered the possibility to achieve it. It was a jubilation when we could publish the first papers in the 'Online First' section at the first time, and we felt that the most appropriate way to share our happiness is to publish the papers of the already finalized 'Celebration Issue' that was a surprise gift to us celebrating the 36th anniversary of the Journal with not less than 36 outstanding communications from the most prestigious scientists. I owe a special thanks to my long time friend and colleague Prof. Shmuel Yariv organising this Issue - this very moving gift - and for the excellence how he executed the collection and preparation of the papers. Last, but not least I need to express my sincere gratitude to all of those contributed with their high standard work to this December issue. We would like to acknowledge all those who had been working with us in the past years, and now giving space to new members in the line of Regional and Associate Editors. Special thanks to Prof. Gavrichev, Prof. Ray and Prof. Walter, Regional Editors, furthermore to Dr. Emmerich, Prof. Jones and Prof. Beezer, Associate Editors for their valuable work, and support. At the same time we have the pleasure to welcome the new Regional Editors: Prof. T. Usacheva for Russia, Prof. P. Thomas and Prof. D. Bessiéres for English and French speaking teritorries respectively. Our new Associate Editors are: Prof. G. Pokol, Prof. S. C. Mojumdar, Prof. E. Boldyreva and Prof. P. Budrugeac. I would like to provide a forum for new ideas and here I would like to call on to all Editors to contribute to this initiation. I am planning to write a mid-year editorial where we would share these new ideas, i.e. the issue of 'Short Communications' and similar topics of wide interest. This year was just as tragic as it was sucessful in losing many of our colleagues.We could hardly recover from the news of the sudden death of Prof. M. Richardson, Prof. Maria Kurzawa and our close friend and Associate Editor Prof. Lisardo Nuñez Reguiera when we had to say our final good bye to our beloved teacher, a world wide acknowledged scientist and inventor Prof. F. Paulik. Finally, I would like to wish a prosperous new year, health and success in every aspect of your life to all of you.     

专辑简介

On the request of Prof.Shi-Gang Sun,Editor-in-Chief of Journal of Electrochemistry,I served asthe guest editor for this International Special Issueon Current Electrochemistry.The Journal of Electrochemistry was founded in1995 associated to     

Doug Ruthven and Jörg Kärger: Their individual and collective contributions to the field of zeolite science and engineering

Prof. Doug Ruthven and Prof. Jörg Kärger are two giants in the field of zeolite science and engineering. Over their academic careers encompassing almost forty years each, they have contributed significantly to the advancement of fundamental understanding of adsorption and diffusion in zeolites as well as their industrial applications. The author, in the beginning of his academic career, had an opportunity to spend two years as a post-doctoral fellow in Prof. Ruthven’s laboratory at the University of New Brunswick (1975–1977). This experience actually motivated me to spend my academic career in working in the field of zeolite adsorption and diffusion. Nearly thirty years later, I spent a year as a Gast Mercator Professor at the University of Leipzig in the laboratory of Prof. Kärger (2005–2006). These two opportunities at two different ends of my academic career provided me with unique perspectives to reflect on the important contributions made by Professors Ruthven and Kärger to the field of zeolite science and technology. This article summarizes my personal perspectives on the breadth and depth of their contributions.     

多碱化学的研究—纪念恩师戴安邦教授逝世一周年

本文为戴安邦教授及其学生们关于多碱化学的研究的回顾和总结 ,叙述了他的早期工作 ,Cr3 的水解聚合 ,富马酸和马来酸存在下Cr3 的水解聚合 ,及稀土离子的水解聚合。这项研究对实用领域是有益的 ,诸如核化学 ,鞣革及塑料与金属的粘接     

多碱化学的研究—纪念恩师戴安邦教授逝世一周年

本文为戴安邦教授及其学生们关于多碱化学的研究的回顾和总结,叙述了他的早期工作,Cr³⁺的水解聚合,富马酸和马来酸存在下Cr³⁺的水解聚合,及稀土离子的水解聚合。这项研究对实用领域是有益的,诸如核化学,鞣革及塑料与金属的粘接。     

Adsorption kinetics and electrode processes

Prof. H. A. Laitinen (Urbana):We have used double layer capacity measurements to measure adsorption as a function of time during the life of slowly forming mercury drops. For many substances that are not extremely surface active, so that the solution concentration is 1 to 10 mM, the double layer capacity per unit area is essentially constant during the time interval of 5 to 15 sec of drop life. It appears, therefore, that adsorption equilibrium has essentially been attained during the later portions of drop life.Prof. P. Delahay:We have also used a similar method of following the differential capacity during drop life. I would agree that one can achieve conditions for which adsorption equilibrium with respect to bulk concentration is practically reached (high enough concentration and long drop time). But this is quite often not the case (drop time of 3–4 sec in polarography).Mr. G.C. Whitnack (China Lake, U.S.A.);In determination of nitrate esters in presence of phthalate esters we have observed considerable dropping of current height of nitrate ester wave before start of phthalate ester wave. Is this due to an adsorption process occurring at the DME?Prof. P. Delahay:It might well be, but I would hesitate to comment any further on this point because more information would be required. You probably have quite a complicated situation. Perhaps we can discuss the matter later?Prof. Dr. H. Fischer (Ettingen):Ich möchte hinzufügen, class es Fälle geben kann, in denen mcht allem der Blockierungseffekt don Grenzstrom verringert, sondern eine Veränderung des Diffusionsfilmes durch Sekundärreaktion des Inhibitors. Dies ist z.B. bei der Abscheidung von Wasserstoff an einer festen Elektrode (Fe) der Fall, wenn der Inhibitor sich spaltet in eine schwerlösliche Verbindung und ein Proton (RNH⁺ → [RN] + H⁺). Dies beobachtet man z.B, bei den Kationen von heterozyklischen Aminen (Acridin). Offentlich bildet sich eine diffusionshindernde Barriere aus.Prof. P. Delahay:The case of the hydrogen electrode is complicated, and I shall attempt to answer your question only in the case of an ideally smooth electrode. Then, diffusion toward the electrode (partially covered with an adsorbed substance) is little affected by adsorption because the size of “the holes” in the film is very small in comparison with the diffusion layer thickness. Of course, there is no diffusion where there is complete blocking.Prof. B. Breyer (Sydney):The importance of the chemical nature of the film adsorbed at the interface, which has been mentioned by Prof. delahay, seems to me to play a major part in the type of processes discussed. Thus it must be kept in mind that complex formation between the diachargeable ion and the adsorbed film might occur (cf. e.g. heyrovsky? and matyas, 1941). The fact that T1+ ion is little influenced by the presence of an adsorbed film at the electrode solution interface could then be partly explained by the notoriously low co-ordination tendency of that ion.Prof. P. Delahay:The difficulty involved in the “blocking” of the limiting current for thallium is due, I think, to the small size of this ion (large diffusion coefficient of Tl+ in comparison with other ions). Of course, complex ions can be relatively very bulky and this enhances “blocking”.Prof. E. Lange (Erlangen):I agree with prof. delahay that it is very important to investigate the connections between the adsorption and electrode reaction.This is easy for a steady state, e.g., each heterogeneous reaction between two phases that is accompanied by a transfer of ions or electrons, i.e. of electrical charges, from one phase to the other. In such a case, the Galvani tension does not change and the transfer between the two phases must be compensated by a corresponding transfer of charges within the phases.But in the non-steady state, also, an adsorption process may behave as an “electrode reaction” for instance, even an adsorption of a dipole molecule may cause a “transfer of charge” accompanied by a corresponding change of the Galvani tension. In this manner, it seems to me that for the non-steady state it is necessary to define precisely what one means by “electrode reaction”.Prof. P. Delahay:I entirely agree with Prof. i.ange about the necessity of clear definitions. I think that the fact that a steady state with respect to diffusion of the reductible or oxidizable substance has not been reached is not too serious because this scarcely affects the Galvani potential (large excess of supporting electrolyte).Variations in the amount of adsorbed organic substances indeed affect the Galvani potential (dipole orientation), but this effect is included in the dependence of the rate constant ks (at the standard potential) on the electrode coverage.Prof. N. Tanaka (Sendai, Japan).I am very grateful to Prof. delahay for his beautiful work on adsorption kinetics. I should like to make one comment in connection with the rotated dropping mercury electrode. The relation between log i and log t on the current — time curve was found to be 0.5 only in the absence of the surface-active substance. In the presence of surface-active substance, the slope of log i vs. log t changed at a certain point of the current — time curve. This can be explained when the slow adsorption of the surface-active substance on the surface of the electrode is taken into consideration.Prof. P. Delahay:Even for stirred solutions, adsorption equilibrium is not reached very rapidly. A simple calculation based on a model of the Nernst diffusion layer shows that perhaps 1–5 sec are required. Your conclusion is, therefore, quite correct.Prof. W. Kemula (Warsaw):We have recently published that, in several cases, the addition of extremely small concentrations of organic surface-active substances provokes at first a rise of the diffusion current, this current then being suppressed by additional quantities of the substance.     

RETRACTED: A simple spectrophotometric technique for the determination of carbaryl pesticides in various environments

This article has been retracted at the request of the Editors-in-Chief. Please see Elsevier Policy on Article Withdrawal (http://www.elsevier.com/locate/withdrawalpolicy). REASON: Considerable concern was raised about the research purportedly conducted at Sri Venkateswara University, India with the alleged involvement of Prof. P. Chiranjeevi. Questions were raised as to the volume of publications, the actual capacity (equipment, orientation and chemicals) of the laboratory in which Prof. Chiranjeevi worked, the validity of certain of the research data identified in the articles, the fact that a number of papers appear to have been plagiarized from other previously published papers, and some aspects of authorship. Professor Chiranjeevi was given the opportunity to respond to these allegations. Thereafter, a committee was constituted by the University to look into these allegations. Based on the enquiry committee report, we have been informed by the head of the Department of Chemistry at Sri Venkateswara University that the university authorities have taken disciplinary action against Prof. Chiranjeevi, as the university considers that there are grounds for such action. Therefore, based on the results of this investigation, the Editor is retracting this article.     

有机化学中新兴领域的积极开拓者——黄耀曾先生

黄耀曾先生(1912-2002),我国著名的有机化学家,中国科学院院士,我国有机氟化学的先驱者,我国金属有机化学的开拓者。曾任中央研究院化学研究所助理研究员,副研究员,上海第一医学院助教,讲师。中国科学院上海有机化学研究所副研究员,研究员,博士生导师;上海有机化学研究所副所长,中国科学院化学部常委,副主任,中国化学会常务理事,《有机化学》主编和国际《杂原子化学》顾问编委。他的研究工作不仅推动了有机化学的发展,而且在我国国防建设和经济建设中也做出了突出贡献。曾获全国科学大会奖,国家科学技术进步一等奖,国防科技事业荣誉证书,国家自然科学三等奖及二等奖,第三世界科学院化学奖,何梁何利基金科学与进步奖等众多奖项。几十年的学术生涯中,黄耀曾先生在国内外著名学术刊物上共发表论文230余篇,著译9本,培养了博士20名,其中有的当选为院士,有的已成为重要的科研骨干和领导,有的是著名的企业家。     

Meet the Board of ChemistryOpen: Sheshanath V. Bhosale

Sheshanath V. Bhosale received his PhD from Freie University Berlin (Germany) in supramolecular chemistry under the supervision of Prof. J. H. Fuhrhop in 2004. He then pursued his postdoctoral studies with Prof. S. Matile at University of Geneva (Switzerland) under the auspices of a Roche Foundation Fellowship. This was followed by a stay at Monash University (Australia) for 5 years as an ARC-APD Fellow. He worked at RMIT University, Melbourne (Australia) for 6 years as ARC-Future Fellowship. Currently, Prof. Bhosale is working at the Department of Chemistry, Goa University (India) as a UGC-FRP Professor, His research interests lie in the design and synthesis of π-functional materials, especially small molecules, for sensing, biomaterials, and supramolecular chemistry applications. So far, Prof. Bhosale has produced 185 research articles and his work has been cited more than 4400 times, giving him an h-index of 32. He currently serves as an active Editorial Board member for ChemistryOpen.     

Retraction: A New Sesquiterpene from Caragana intermediia and Its Anti‐Pyricularia oryzae P‐2b Activity

The following article from Chinese Journal of Chemistry , 'A New Sesquiterpene from Caragana intermediia and Its Anti–Pyricularia oryzae P–2b Activity' by Zhi–Hua Sun, Chang–Qi Hu, and Jin–Yi Wang, published online on May 15, 2008 in Wiley Online Library, and in print Volume 26 Issue 5, 2008, pages 831–834, has been retracted by agreement between the authors, the journal Editor in Chief, Prof. Guozhen Ji, and Wiley–VCH Verlag GmbH & Co. KGaA. The retraction has been agreed due to overlap between this article and the following article published in Chinese Chemical Letters , 'A new sesquiterpene from Caragana intermediia' by the same authors, Volume 18 Issue 11, 2007, pages 1379–1382.     

苟日新|日日新|又日新——-值王夔教授八十寿诞侧记我国生物无机化学研究

1984年中国化学会第一届全国生物无机化学会议在武汉召开,标志了我国生物无机化学研究的开始。作为我国生物无机化学研究的重要开创者之一,王夔教授积极倡导并开展了细胞生物无机化学研究。本文以王夔教授的研究为主,侧记了我国细胞层次的生物无机化学的某些重要进展。     

抗肿瘤中药微量元素硒的研究

与抗肿瘤作用关系密切的中药微量元素主要有Se、Ge、Zn、Cu、Fe、Mn、Mo、I、B、Si、Li等，本文介绍了近年来Se的研究。Se是人体健康必需的超微量元素．与某些地方病、癌的发生关系密切。是同时具备防癌和促免疫两种活性的理想防癌剂。大部分补气、补血、补肾、补阳等中药富含Se等微量元素，具有抗癌等药理作用．特别是人参等12种中药的抗癌作用尤明显。     

Ortho-hydroxy acetophenone oxime as an analytical reagent. Part II

Summary Gravimetric estimation of copper and nickel and their separation from each other as well as from other metals with good results by means of o-hydroxy acetophenone oxime have been described in this paper.Part I: Z. analyt. Chem. 154, 254 (1957).The author desires to express here his indebtedness to Prof. P. Rây for his kind interest and guidance and for the facilities to work in his laboratory.     

Preface

The fifth CBRATEC (V Congresso Brasileiro de Análise Térmica e Calorimetria) conference was held in April 02–05, 2006 in Poços de Caldas, MG. One third of the 370 participants was graduates and Ph.D. students well representing the continuous interest in thermal analysis among Brazilian researchers. The structure of conference was characteristic and refreshing, since every morning one of the leading Brazil thermoanalysts held an opened teaching course especially for the representatives of the young generation. After then plenary lecturers and keynote speakers (J. Rouquerol, Cs. Novák, D. Burlett, M. Suchyta and A. Riga) occupied the podium. The afternoon sessions consisted of mainly short lectures and poster exhibitions; both provided excellent possibility for the Ph.D. students to introduce their scientific work. The scope of conference covered practically all aspects of thermal analysis. Since 1998, when the first CBRATEC conference was held, the participation of young scientists and the organization of teaching courses played essential role for them. As an effort to increase international experiences, the universities pay continuous attention to foreign language education (first of all English), so the communication between the invited international researchers, the representatives of the instrument companies and the domestic conference attendants became much more efficient in recent years. During the conference the new Executive Committee was elected. Prof. Valter José Fernandes Junior was elected as President of ABRATEC supported by the members of the Executive (Jivaldo do Rosário Matos (Vice-President), Massao Ionashiro, Lázaro Moscardini D’Assunção, Clóvis Augusto Ribeiro, Elias Yuki Ionashiro, Carlos Isidoro Braga, Manoel Luiz Cunha Rodrigues, Rodrigo Maciel). In recognition of his continuous cooperation for the development of thermoanalytical researches in Brazil and its scientific divulgation in Thermal Analysis, the ‘Special Award’ of ABRATEC (Brazilian Association for Thermal Analysis and Calorimetry) was presented to Prof. Csaba Novák. For their outstanding achievements in developing the international relation of ABRATEC, Honourable Membership of the Thermoanalytical Sub-Branch of the Hungarian Chemical Society was presented to Prof. Jivaldo do Rosário Matos, Massao Ionashiro, Prof. Valter José Fernandes Junior and Prof. Éder Tadeu Gomes Cavalheiro at the opening ceremony. At last but not least, according to the decision of ICTAC Council during the 13^th ICTAC (2004, Chia Laguna, Italy) Brazil was elected as the host of ICTAC 14 in 2008. The Brazilian thermoanalytical community feels extremely honored to be entrusted with the organization of the 14^thICTAC Conference that will take place in São Pedro, SP, in September 14–19, 2008, where the scientists, researchers and students, who are acting in the field of thermal analysis and calorimetry are cordially invited. The link to the conference site is www.ictac14.com.br.     

"我"——"三草酸合铁(Ⅲ)酸钾晶体"的生长及影响因素

This article tries to personify potassium ferrioxalate crystal as "I" to describe the formation process and the factors affecting the growth of potassium ferrioxalate crystal. After growing into beautiful green crystals, I dreamed I was participating in the jewelry beauty contest. A serious of wonderful conversations between emerald and I revealed the properties and applications of potassium ferrioxalate crystal. It inspires and guides students to understand the growth of crystals and their properties, and it also stimulates students' interest in studying chemistry.     

药学专业留学生分析化学实验全英文教学的体会

留学生教育已成为我国高等教育的重要组成部分,而全英文教学是无中文基础的留学生的最佳选择。分析化学实验为药学专业本科生的必修课,本文针对药学专业留学生分析化学实验课的全英文教学过程,从课程的教学安排、教材选用、教学师资、授课方式和考评方式等方面讲述了教学实践中的体会,希望为开设同类课程的全英文教学提供借鉴和参考。     

Reconstitution of Motor Proteins through Molecular Assembly

What is the most favorite and original chemistry developed in your research group?The most favorite and original chemistry developed in my research group is about the reconstitution of motor proteins in artificially designed and assembled units.It is based on the molecular assembly technique,but the method is different from the conventional approach.     

“双一流”建设背景下化学拔尖班学生的国际化培养模式探索与实践

四川大学化学学院于2009年开始实施"化学拔尖学生培养试验计划",致力于培养化学领域领军人才。在化学学科入选教育部"双一流"学科建设的背景下,学院立足本专业特点、依托校院两级资源,从师资、课程、学生、办学等多方面构建拔尖学生国际化培养体系,做出了诸多尝试并取得了良好的成效。本文在对现有国际化建设策略讨论的基础上,进一步对加强拔尖学生全球胜任力进行思考、提出建议。