Thermal Management and Modeling of Forced Convection and Entropy Generation in a Vented Cavity by Simultaneous Use of a Curved Porous Layer and Magnetic Field

The effects of using a partly curved porous layer on the thermal management and entropy generation features are studied in a ventilated cavity filled with hybrid nanofluid under the effects of inclined magnetic field by using finite volume method. This study is performed for the range of pertinent parameters of Reynolds number (100≤Re≤1000), magnetic field strength (0≤Ha≤80), permeability of porous region (10−4≤Da≤5×10−2), porous layer height (0.15H≤tp≤0.45H), porous layer position (0.25H≤yp≤0.45H), and curvature size (0≤b≤0.3H). The magnetic field reduces the vortex size, while the average Nusselt number of hot walls increases for Ha number above 20 and highest enhancement is 47% for left vertical wall. The variation in the average Nu with permeability of the layer is about 12.5% and 21% for left and right vertical walls, respectively, while these amounts are 12.5% and 32.5% when the location of the porous layer changes. The entropy generation increases with Hartmann number above 20, while there is 22% increase in the entropy generation for the case at the highest magnetic field. The porous layer height reduced the entropy generation for domain above it and it give the highest contribution to the overall entropy generation. When location of the curved porous layer is varied, the highest variation of entropy generation is attained for the domain below it while the lowest value is obtained at yp=0.3H. When the size of elliptic curvature is varied, the overall entropy generation decreases from b = 0 to b=0.2H by about 10% and then increases by 5% from b=0.2H to b=0.3H.     

Exploring the Neighborhood of q-Exponentials

The q-exponential form eqx≡[1+(1−q)x]1/(1−q)(e1x=ex) is obtained by optimizing the nonadditive entropy Sq≡k1−∑ipiqq−1 (with S1=SBG≡−k∑ipilnpi, where BG stands for Boltzmann–Gibbs) under simple constraints, and emerges in wide classes of natural, artificial and social complex systems. However, in experiments, observations and numerical calculations, it rarely appears in its pure mathematical form. It appears instead exhibiting crossovers to, or mixed with, other similar forms. We first discuss departures from q-exponentials within crossover statistics, or by linearly combining them, or by linearly combining the corresponding q-entropies. Then, we discuss departures originated by double-index nonadditive entropies containing Sq as particular case.     

On the redox reactions between allyl radicals and NOx

NO_x mitigation is a central focus of combustion technologies with increasingly stringent emission regulations. NO_x can also enhance the autoignition of hydrocarbon fuels and can promote soot oxidation. The reaction between allyl radical (C₃H₅) and NO_x plays an important role in the oxidation kinetics of propene. In this work, we measured the absolute rate coefficients for the redox reaction between C₃H₅ and NO_x over the temperature range of 1000–1252 K and pressure range of 1.5–5.0 bar using a shock tube and UV laser absorption technique. We produced C₃H₅ by shock heating of C₃H₅I behind reflected shock waves. Using a Ti:Sapphire laser system with frequency quadrupling, we monitored the kinetics of C₃H₅ at 220 nm. Unlike low-temperature chemistry, the two target reactions, C₃H₅ + NO → products (R1) and C₃H₅ + NO₂ → products (R2), exhibited a strong positive temperature dependence for this radical-radical type reaction. However, these reactions did not show any pressure dependence over the pressure range of 1.5–5.0 bar, indicating that the measured rate coefficients are close to the high-pressure limit. The measured values of the rate coefficients resulted in the following Arrhenius expressions (in unit of cm³/molecule/s):$k_1\left({\mathrm{C}}_3{\mathrm{H}}_5+\text{NO}\right)=1.49\times {10}^{?10}\exp \left(?6083.6\frac{\mathrm{K}}{T}\right)\left(1017?1252K\right)$$k_2\left({\mathrm{C}}_3{\mathrm{H}}_5+\mathrm{N}{\mathrm{O}}_2\right)=1.71\times {10}^{?10}\exp \left(?3675.7\frac{\mathrm{K}}{T}\right)\left(1062?1250K\right)$To our knowledge, these are the first high-temperature measurements of allyl + NO_x reactions. The reported data will be highly useful in understanding the interaction of NO_x with resonantly stabilized radicals as well as the mutual sensitization effect of NO_x on hydrocarbon fuels.     

Investigation of the kinetics of conjugated diolefins using UV absorption spectroscopy

Conjugated diolefins are not only crucial intermediates in larger hydrocarbon pyrolysis and oxidation, but also key species in the formation and growth of polycyclic aromatic hydrocarbons (PAHs). In this work, we employed a sensitive UV laser diagnostic to measure absorption cross-sections and decomposition rates of three conjugated diolefins, namely 1,3-butadiene, 2-methyl-1,3-butadiene (isoprene), and 2,3-dimethyl-1,3-butadiene. The single-pass UV absorption diagnostic achieved a ppm-level detection limit between the wavelengths of 212.5 and 220.5 nm. The use of dilute conditions (119 – 500 ppm fuel in argon) enabled nearly isothermal measurements despite reaction enthalpy. Temperature-dependent absorption cross-sections were measured from room temperature to 1850 K and pressures ranging 0.75 – 1.50 bar in a shock tube. Decomposition of the molecules was observed at temperatures above ∼ 1350 K, and all three molecules exhibited similar activation energy. Around 1800 K, 2,3-dimethyl-1,3-butadiene decomposed twice as fast as isoprene and 4 times faster than 1,3-butadiene. Our measured overall decomposition rate coefficients are given as (unit of s ^− 1, ± 20% uncertainty):$\begin{array}{ccc}& & k_1\left(1,3-\text{butadiene}\right)=9.65\times {10}^9{e}^{\left(\frac{-24,338K}{T}\right)}(1411-1823\mathrm{K})\hfill \\ & & k_2\left(\text{isoprene}\right)=1.86\times {10}^{10}{e}^{\left(\frac{-24,341K}{T}\right)}(1464-1829\mathrm{K})\hfill \\ & & k_3\left(2,3-\text{dimethyl}-1,3-\text{butadiene}\right)=8.64\times {10}^{10}{e}^{\left(\frac{-25,845K}{T}\right)}(1401-1822\mathrm{K})\hfill \end{array}$1,3-Butadiene decomposition rate coefficients agree well with previous measurement at similar pressures. To our knowledge, this work reports first measurements of the decomposition rate coefficients of isoprene and 2,3-dimethyl-1,3-butadiene. As an additional application of the current UV diagnostic, we measured 1,3-butadiene decay time-histories during fuel-lean oxidation and compared our data with the predictions of AramcoMech 3.0. We updated the model with our measured 1,3-butadiene decomposition rate coefficients, which significantly improved the model prediction of fuel oxidation.     

Experimental determination of interfacial energy for solid Al in the Al-Sn-Mg eutectic system with Bridgman-type apparatus

The equilibrated grain boundary groove shape of solid Al in equilibrium with Al-Sn-Mg eutectic liquid was observed by using a Bridgman type directional solidification apparatus. The ratio of the thermal conductivity of the equilibrated liquid to the thermal conductivity of solid Al has been obtained as 0.91. In addition, the average Gibbs-Thomson coefficient, $\bar{\mathrm{\Gamma }}=(4.20\pm 0.35)\times {10}^{-8}\mathrm{Km}$, the solid-liquid interfacial energy, ${\sigma }_{SL}=180.68\pm 23.48\text{mJ}/{\text{m}}^2$ and the grain boundary energy, ${\sigma }_{GB}=309.30\pm 29.47\text{mJ}/{\text{m}}^2$, in the Al/Al-Sn-Mg system have been calculated from the measured grain boundary shapes.     

Along the Lines of Nonadditive Entropies: q-Prime Numbers and q-Zeta Functions

The rich history of prime numbers includes great names such as Euclid, who first analytically studied the prime numbers and proved that there is an infinite number of them, Euler, who introduced the function ζ(s)≡∑n=1∞n−s=∏pprime11−p−s, Gauss, who estimated the rate at which prime numbers increase, and Riemann, who extended ζ(s) to the complex plane z and conjectured that all nontrivial zeros are in the R(z)=1/2 axis. The nonadditive entropy Sq=k∑ipilnq(1/pi)(q∈R;S1=SBG≡−k∑ipilnpi, where BG stands for Boltzmann-Gibbs) on which nonextensive statistical mechanics is based, involves the function lnqz≡z1−q−11−q(ln1z=lnz). It is already known that this function paves the way for the emergence of a q-generalized algebra, using q-numbers defined as 〈x〉q≡elnqx, which recover the number x for q=1. The q-prime numbers are then defined as the q-natural numbers 〈n〉q≡elnqn(n=1,2,3,⋯), where n is a prime number p=2,3,5,7,⋯ We show that, for any value of q, infinitely many q-prime numbers exist; for q≤1 they diverge for increasing prime number, whereas they converge for q>1; the standard prime numbers are recovered for q=1. For q≤1, we generalize the ζ(s) function as follows: ζq(s)≡〈ζ(s)〉q (s∈R). We show that this function appears to diverge at s=1+0, ∀q. Also, we alternatively define, for q≤1, ζq∑(s)≡∑n=1∞1〈n〉qs=1+1〈2〉qs+⋯ and ζq∏(s)≡∏pprime11−〈p〉q−s=11−〈2〉q−s11−〈3〉q−s11−〈5〉q−s⋯, which, for q<1, generically satisfy ζq∑(s)<ζq∏(s), in variance with the q=1 case, where of course ζ1∑(s)=ζ1∏(s).