Solute Concentration Profiles for Discontinuous Dissolution in Al-22 at. % Zn Alloy

The discontinuous dissolution reaction has been analyzed in an Al-22 at. % Zn alloy. A simulation method based on the Ziba-Pawowski equation has been used to determine the solute concentration profiles expected to form behind the receding cell boundary for various initial values of the solute concentration in the lamella at the / interface as well as the solute concentration in the newly formed solid solution at the tip of the lamella. A criterion for the applicability of the Ziba-Pawowski model has been formulated. The simulated profiles are in a very good agreement with the experimental ones obtained by using a special procedure involving in situ observation and high spatial X-ray measurements in a transmission electron microscope.     

The vibration and rotation of piezoelectric particles in high frequency electric fields observed by a thermoacoustic method

We have observed, by a thermoacoustic method, the acoustic resonance vibration of small (diameter 115 m) piezoelectric particles in high frequency (15 MHz) electric fields. The frequency dependence of the thermoacoustic signal gives direct information about the size distribution of the particles.In very strong rf electric fields we also observed a rotation of the vibrating particles by large angles — as originally suggested by Melcher and Shiren [3] — orienting the initially random rf dipoles parallel to the rf electric fields.The observed strong forces acting on vibrating piezoelectric particles in rf fields can probably be used as a new method of selectively extracting particles of a given size from a broad distribution of very small particles.     

Self interstitial trapping at Hf impurities in Niobium

After electron irradiation at 15 K of Niobium doped with¹⁸¹Hf the trapping of defects at the Hf impurities was observed by means of the perturbed angular correlation method. The results are interpreted as the formation of Hf-Nb mixed dumbbells which are formed at 5 K and are stable up to 80 K.     

Study ofA+A→0 with probability of reaction and diffusion in one dimension and in fractal substrata

We present Monte Carlo simulations of annihilation reactionA+A0 in one dimensional lattice and in three different fractal substrata. In the model, the particles diffuse independently and when two of them attempt to occupy the same substratum site, they react with a probabilityp. For different kinds of initial distributions and in the short an intermediate time regimes, the results for 0<p1 show that the density ofA particles approximately behaves as (t)=(t=0)f(t/t ₀), with the scaling functionf(x)1 forx1,f(x)x ^–y forx1. The crossover timet ₀, behaves ast _{0 0eff} ^–1y where theeffective initial density _0eff depends on (t=0) and on the kind of initial distribution. For a given substratum of spreading dimensiond _s, the exponenty(d _s/2<y<1) depends only onp and its value increases asp decreases (y1 whenp0). In the very long time regime it is expected thatp(t)t ^–ds/2 independently ofp.     

Beitrag zum Phasendiagramm von Zn-Sb

Zusammenfassung In der vorliegenden Arbeit werden die Ergebnisse der Röntgenstrukturstudie der Phasen im System Zn-Sb beschrieben. Es wurde das Grundprisma, die Symmetrie und die Anzahl der stöchiometrischen Einheiten in der Zelle in -Zn₄Sb₃ bestimmt. Bei Zn₃Sb₂ wurde festgestellt, da die Hochtemperaturphase bei langsamer Abkühlung auf die Raumtemperatur in -Zn₄Sb₃ und Zn zerfällt.

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Zn-Sb

Zn-Sb. , -Zn₄Sb₃. Zn₃Sb₂ , -Zn₄Sb₃ u Zn.

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Ich danke allen Mtarbeitern des instituts für technische Physik für ihre unterstützung, die mir die Durchführung dieser Arbeit ermöglichte, insbesondere den Kollegen Dr. K. Toman und Dr. A. Línek.     

Detecting torsion from massive electrodynamics

A new method of detecting torsion in the case of massive electrodynamics is proposed. The method is based on the study of spectral lines of hydrogen-like atoms placed in a torsion field, where the interaction energy between the torsion vector field Q and an electric dipole is given by P · Q. All the methods designed so far have been based on spinning test particles interacting with magnetic fields in which the energy splitting is given by S · B on a Stern-Gerlach type experiment. We arrive at an energy splitting of order of 10^–21erg 10^–9eV, which is within the frequency band of radio waves.     

The critical point indices of ferroelectric and ferromagnetic phase transitions

Magnetic transitions are described by the critical indices0,1/3,4/3 while some ferroelectric transitions appear to give0,R~1/2,1. It is pointed out that these two sets of values for the critical indices are allowed by the scaling laws and stability conditions near the phase transitions.The authors thank Prof. R. S. Krishnan for his encouragement and Mr. B. Viswanathan for some discussions. The financial assistance from DAE and CSIR is also acknowledged.     

Silver Nanoparticles Synthesized by Vapor Deposition onto an Ice Matrix

As a strategy for synthesizing metal nanoparticles, thermally evaporated Ag was deposited onto a thin (1.2nm) crystalline ice layer on hafnia (HfO₂) at 100K. The Ag atoms penetrate into the ice matrix but do not reach the underlying HfO₂ substrate. After controlled thermal desorption of water by heating to 300K, atomic force microscopy reveals Ag particle formation. Their lateral dimensions are between 5 and 20nm and, in many cases, their heights exceed the thickness of the original water layer. Fewer, higher and more regular Ag particles are formed in the presence, as compared to the absence, of ice. This is discussed in terms of two factors – Ag atoms reaching HfO₂ are thermally colder when they arrive from the ice matrix and desorption of water involves formation of liquid droplets, a process that concentrates Ag into the volumes occupied by the water droplets.     

Atomic in-plane disorder in Co/Pt superlattices

We have studied 111 and 001 oriented Co(3 Å)/Pt(18 Å) superlattices grown by molecular beam epitaxy via X-ray diffraction using synchrotron radiation. The diffraction peak shapes, for the scattering vector Q parallel to the film planes, were found to be characteristically different between these two films. For the 111 oriented sample, this broadening is characterized by a Lorentzian peak shape with a positional correlation length of the order of 50 Å. The data further indicate that the atomic correlation in the 111 sample has a long range orientational but only short range positional order.     

Comments on transitions in bulk tetramethyltin Sn(CH3)4 and as adsorbate on a (0001) graphite plane

In the case of tetramethyltin, whether in bulk form or in the form of an adsorbate on (0001) graphite basal plane, it was found that anomalies in the Mössbauer or X-ray diffraction parameters occur at similar temperatures, viz: 83 K, 95 K, and 125 K. It is therefore suggested that these anomalies can be associated in some way with intramolecular rearrangements and be affected by intramolecular motions.Sponsored by the U.S.-Israel Binational Science Foundation     

Influence of linear elastic stresses on dynamic magnetostriction of cold-rolled transformer steel

The anisotropy of dynamic magnetostriction is investigated without external stresses, in extension, and in compression. Results are obtained expressing the (B) dependence for constant elastic stresses and also — () for certain induction values. Oscillograph traces are taken of the (H) and B(H) hysteresis loops with the specimens under investigation in extension and compression.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 110–115, May, 1977.     

On ruelle's ξ-function for exponentially decreasing potentials

We show that Ruelle's generalised -function for a classical one-dimensional lattice spin system with two-body interaction (i) exp(-i )a(i) with >1 extends to a meromorphic function in the whole complex plane.     

Asymptotic behavior of densities for two-particle annihilating random walks

Consider the system of particles on ^d where particles are of two types—A andB—and execute simple random walks in continuous time. Particles do not interact with their own type, but when anA-particle meets aB-particle, both disappear, i.e., are annihilated. This system serves as a model for the chemical reactionA+B inert. We analyze the limiting behavior of the densities _A (t) and _B (t) when the initial state is given by homogeneous Poisson random fields. We prove that for equal initial densities _A (0)= _B (0) there is a change in behavior fromd4, where _A (t)= _B (t)C/t ^d /4, tod4, where _A (t)= _B (t)C/tast. For unequal initial densities _A (0)< _B (0), _A (t)e ^–cl ind=1, _A (t)e ^–Ct/logt ind=2, and _A (t)e ^–Ct ind3. The termC depends on the initial densities and changes withd. Techniques are from interacting particle systems. The behavior for this two-particle annihilation process has similarities to those for coalescing random walks (A+AA) and annihilating random walks (A+Ainert). The analysis of the present process is made considerably more difficult by the lack of comparison with an attractive particle system.     

Ultra-high piezoelectric response in 〈<Emphasis Type="Bold">110</Emphasis>〉- oriented polydomain Pb(Mg<Subscript>1/3</Subscript>Nb<Subscript>2/3</Subscript>)O<Subscript>3</Subscript>- PbTiO<Subscript>3</Subscript> single crystals

The piezoelectric constant and electromechanical coupling coefficients of 110-oriented polydomain0.71Pb(Mg_1/3Nb_2/3)O₃-0.29PbTiO₃ single crystals were determined experimentally by using resonance methods. It was confirmed that the single-crystal system has large electromechanical coupling coefficients k₃₃ (91%), k₃₃ (83%), and k₃₁ (81%), and piezoelectric constant d₃₃ (1400 pC/N), which are comparable to those of 001-oriented crystals, and we also found that the values of k₃₃ and k₃₁ are sensitive to the cuts of the crystals. X-ray-diffraction measurements on 110-oriented crystals have shown that the origin of the high piezoelectric response should be attributed to the orthorhombic distortion. Our results show that the 110-oriented crystals are also promising for a wide range of electromechanical transducer applications, since the 110-oriented crystals can be grown from 110-oriented seed crystals in the modified Bridgman technique. PACS 77.80.Bh; 77.84.Dy; 77.65.Bn     

Infrared absorption enhancement of monolayer species on thin evaporated Ag films by use of a Kretschmann configuration: Evidence for two types of enhanced surface electric fields

Infrared absorption enhancement of m- and p-nitrobenzoic acid deposited on thin-evaporated silver films has been investigated using the Kretschmann's ATR coupling method. The absorption spectra provide direct evidence that enhancement is prominent only for vibrations of the first monolayer adsorbed on the Ag surface. It is shown that all of the vibrational modes observed obey the normal dipole selection rule. Moreover, it was found that there exist two types of absorption enhancement; the first is enhanced (300) by both p- and s-polarized radiation, and the second is enhanced (60) by p-polarized radiation alone. The Ag film thickness optimum is about 50 Å in the former case and about 200 Å in the latter. The enhancement insensitive to the polarization state of radiation can well be explained by the excitation of the transverse collective electron resonance of the Ag islands, whereas that obtained by p-polarized radiation may be due to the excitation of delocalized surface plasmons modified by surface roughness. The image-dipole effect may also be significant in the mechanisms.     

A model of Piron's preparation-question structures in Ludwig's selection structures

We give a model of the basic Jauch-Piron (JP) approach to quantum physics, i.e., of preparation-question structure (with four basic axioms and without axioms C, P, A), in terms of Ludwig's selection structure; in the latter structure the primitive notion of individual sample of a physical entity is formally described (without making reference to any probability concept). Once we interpret Piron's concept of question in Ludwig's context of a selection structure, we find that there is no difficulty in formalizing notions such as performable together questions; moreover, results such as = or ()= can be formally proved. We develop the theory along the lines of the JP approach; the set of JP propositions is derived and it turns out to be a complete lattice, as happens in Piron's theory, but with a different physical interpretation of the lattice operations. Finally, we study some connections between the standard Ludwig foundation and our approach.     

Silver diffusion in cadmium sulfide single crystals

An experimental study was made of the penetration of silver by the thermal-diffusion method into cadmium sulfide. The silver was deposited on the samples by thermal evaporation in vacuum. Optical and electrical-probing methods were used to study the rates of surface and bulk diffusion at various temperatures. The temperature dependence of the diffusion coefficient was established for the purity used. After the penetration of the silver impurity, the low-resistivity ( 0.1 · cm), nonphotosensitive cadmium sulfide samples displayed high resistivity ( 10⁶-10⁸ · cm) and photosensitivity.Translated from Izvestiya VUZ. Fizika, No. 7, pp. 12–16, July, 1970.     

On the dynamics of a quantum system which is classically chaotic

We investigate the dynamics of one anisotropic spin in an external time-dependent magnetic field. The classical dynamics of the system is nonintegrable (and very similar to the standard map). We present results on this model for a quantum spin (i.e. for finite values of the spin lengthS). In particular we discuss the semiclassical regime,S1, using the concept of Wigner functions to define a suitable probability distribution. In regular regions of phase space the time evolution of the probability distribution shows an algebraic decay of correlations as in quantum mechanics. In chaotic regions of phase space it is characterised by a positive Lyapunov exponent which depends onS. In these regions semiclassical trajectories coincide with classical ones fort <₀ where ₀InS.     

A new method for complex spectral measurement in millimeter and submillimeter wave range

New method for measuring complex transmission or reflection coefficients has been proposed and demonstrated using a simple setup. High measurement quality was achieved: phase sensitivity 0.005 rad., amplitude reproduceability 1%, dynamic range to 10⁷ ÷ 10⁸ (previously 10⁴), phase shift range to be measured 10⁵. It is effective for BWT-Spectroscopy due to the absence of any mechanical adjustments during electronic frequency scan.