Apparent viscosity of a mixture of a Newtonian fluid and interacting particles

We investigate the behavior of fluid–particle mixtures subject to shear stress, by mean of direct simulation. This approach is meant to give some hints to explain the influence of interacting red cells on the global behavior of the blood. We concentrate on the apparent viscosity, which we define as a macroscopic quantity which characterizes the resistance of a mixture against externally imposed shear motion. Our main purpose is to explain the non-monotonous variations of this apparent viscosity when a mixture of fluid and interacting particles is submitted to shear stress during a certain time interval. Our analysis of these variations is based on preliminary theoretical remarks, and some computations for some well-chosen static configurations. To cite this article: A. Lefebvre, B. Maury, C. R. Mecanique 333 (2005).     

The use of Herschel–Quincke tubes to improve the efficiency of lined ducts

The scattering matrix results of Herschel–Quincke (HQ) resonators installed in combination with an acoustic liner (HQ-Liners) are presented in this paper. This approach aims at controlling both tonal and broadband noise to improve the liner efficiency. It uses circumferential arrays of Herschel–Quincke tubes on a main duct in a serial association with a locally reacting liner of known impedance. Results for the scattering matrix of this system are deduced from an analytical model and compared with experimental and numerical data showing a good agreement. Analysis of the scattering matrix coefficients points out the modal conversion properties that depend on the number of HQ tubes along the circumference. Results of the transmission loss show that the choice of an optimal HQ configuration with respect to the liner properties can substantially improve the liner efficiency.     

Unraveling the Crystal Structure of Lanthanide–Murexide Complexes: Use of an Ancient Complexometry Indicator as a Near‐Infrared‐Emitting Single‐Ion Magnet

Herein, we provide some structural evidence of the complexation color‐change of murexide solutions in presence of lanthanide, which has been used for decades in complexometric studies. For Ln=Sm to Lu and Y, the compounds crystallize as monomeric [Ln(Murex)₃] ? 11 H₂O with an N3O6 tricapped square‐antiprism environment, which are stable up to 250 °C. Single‐ion magnet (SIM) behavior is then observed on the Yb^III derivative in an original nine‐coordinated environment. In‐field slow relaxation (Δ=(15.6±1) K; τ₀=2.73×10^?6 s) is observed with a very narrow distribution of the relaxation time (α_max=0.09). Magnetic and photophysical properties can be correlated. On one hand the analysis of NIR emission spectrum permits to have access to crystal field parameters and to compare them with those extracted from dc measurements. On the other hand, magnetic measurements permit to identify the nature of the M _J states involved in the ²F_5/2→²F_7/2 luminescence spectrum. The gap between the low‐lying states is in agreement with the energy barrier obtained from magnetic slow‐relaxation measurement.     

2,2′‐Bipyrimidine as Efficient Sensitizer of the Solid‐State Luminescence of Lanthanide and Uranyl Ions from Visible to Near‐Infrared

Treatment of Ln(NO₃)₃?nH₂O with 1 or 2 equiv 2,2′‐bipyrimidine (BPM) in dry THF readily afforded the monometallic complexes [Ln(NO₃)₃(bpm)₂] (Ln=Eu, Gd, Dy, Tm) or [Ln(NO₃)₃(bpm)₂]?THF (Ln=Eu, Tb, Er, Yb) after recrystallization from MeOH or THF, respectively. Reactions with nitrate salts of the larger lanthanide ions (Ln=Ce, Nd, Sm) yielded one of two distinct monometallic complexes, depending on the recrystallization solvent: [Ln(NO₃)₃(bpm)₂]?THF (Ln=Nd, Sm) from THF, or [Ln(NO₃)₃(bpm)(MeOH)₂]?MeOH (Ln=Ce, Nd, Sm) from MeOH. Treatment of UO₂(NO₃)₂?6H₂O with 1 equiv BPM in THF afforded the monoadduct [UO₂(NO₃)₂(bpm)] after recrystallization from MeOH. The complexes were characterized by their crystal structure. Solid‐state luminescence measurements on these monometallic complexes showed that BPM is an efficient sensitizer of the luminescence of both the lanthanide and the uranyl ions emitting visible light, as well as of the Yb^III ion emitting in the near‐IR. For Tb, Dy, Eu, and Yb complexes, energy transfer was quite efficient, resulting in quantum yields of 80.0, 5.1, 70.0, and 0.8 %, respectively. All these complexes in the solid state were stable in air.     

Influence of the Metal Ion on the Two‐Photon Absorption Properties of Lanthanide Complexes Including Near‐IR Emitters

The synthesis of tris(2‐thenoyltrifluoroacetonate)lanthanide(III) complexes featuring a diethylaminostyryl‐2,2′‐bipyridine coligand was achieved for lanthanum; the near‐infrared (NIR) emitters neodymium, erbium, and ytterbium; and the transition‐metal yttrium. The photophysical properties were thoroughly studied, and it was demonstrated that the conjugated bipyridine ligand acts as a good antenna for the sensitization of the NIR emitters. The two‐photon absorption (TPA) properties of all five complexes were investigated by using both two‐photon excited fluorescence and the Z‐scan method. We demonstrate that the nature of the rare earth ion has almost no influence on the TPA properties centered on the conjugated bipyridyl ligand. Finally, we show that Yb^III is sensitized by a two‐photon antenna effect, and that Nd^III is mostly sensitized by a one‐photon process involving direct excitation of forbidden f–f transitions.     

Sound absorption and transmission through flexible micro-perforated panels backed by an air layer and a thin plate

This paper describes theoretical and experimental investigations into the sound absorption and transmission properties of micro-perforated panels (MPP) backed by an air cavity and a thin plate. A fully coupled modal approach is proposed to calculate the absorption coefficient and the transmission loss of finite-sized micro-perforated panels-cavity-panel (MPPCP) partitions with conservative boundary conditions. It is validated against infinite partition models and experimental data. A practical methodology is proposed using collocated pressure-velocity sensors to evaluate in an anechoic environment the transmission and absorption properties of conventional MPPCPs. Results show under which conditions edge scattering effects should be accounted for at low frequencies. Coupled mode analysis is also performed and analytical approximations are derived from the resonance frequencies and mode shapes of a flexible MPPCP. It is found that the Helmholtz-type resonance frequency is deduced from the one associated to the rigidly backed MPPCP absorber shifted up by the mass-air mass resonance of the flexible non-perforated double-panel. Moreover, it is shown analytically and experimentally that the absorption mechanisms at the resonances are governed by a large air-frame relative velocity over the MPP surface, with either in-phase or out-of-phase relationships, depending on the MPPCP parameters.     

ELENA: the extra low energy anti-proton facility at CERN

At the last LEAP conference in Vancouver 2011 the authors stated that a project ”ELENA”, as an abbreviation for Extra Low ENergy Antiproton ring and as first discussed in 1982 for LEAR by H. Herr et al., was freshly proposed with a substantial new design and revised layout and that it was under consideration to be built at CERN. ELENA is an upgrade of the Anti-proton Decelerator (AD) at CERN and is devoted to special experiments with physics using low energy anti-protons. The main topics are the anti-hydrogen production and consecutive studies of the features of this anti-matter atom as well as the anti-proton nucleon interaction by testing the QED to high precision. During the last years the project underwent several steps in presentations at different committees at CERN and was finally approved such that the construction has started. ELENA will increase the number of useful anti-protons by about two orders of magnitude and will allow to serve up to four experiments simultaneously. Very first and convincing results from the experiments at the AD have been published recently. For high precision physics, however, it appears to be cumbersome, time consuming and ineffective when collecting the needed large numbers and high densities of anti-proton clouds with the present AD. Both the effectiveness and the availability for additional experiments at this unique facility will drastically increase, when the anti-proton beam of presently 5 MeV kinetic energy is reduced by the additional decelerator ELENA to 100 keV.