共查询到19条相似文献,搜索用时 112 毫秒
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介绍了在大型激光装置上进行扩展X射线吸收精细结构(EXAFS)谱压缩物态参数测量的基本原理,以及为获得高质量EXAFS谱在神光Ⅲ原型装置上进行的实验研究。实验采用玻璃靶球、CH靶丸和金球作为EXAFS谱测量的背光源,通过多发次叠加、光子数累积的方法获得了信噪比良好的金属Ti在常温常压下的EXAFS谱,数据处理结果表明,实验测得的金属Ti EXAFS谱拟合结果与同步辐射实验拟合结果相吻合,表明实验设计的正确性与可靠性。对实验结果的分析表明,影响EXAFS谱质量的因素主要是光子计数、测量系统谱分辨率、噪声以及实验器件上的瑕疵。 相似文献
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同步辐射光源是目前世界上最好的光源,用它测量EXAFS谱自然效果极好.然而由于它设备庞大而昂贵,无法普及到一般实验室.转靶X光机比同步辐射装置要简单和便宜得多,但这种光源的性能不如同步辐射,每次实验所需时间也长得多.本文要介绍的激光EXAFS谱仪是用激光打到金属靶上所产生的X射线脉冲作为光源,并用拍照的方法记录EXAFS谱.其设备更加简单和便宜,而且测得EXAFS谱所需时间极短.当然这种方法也有它的局限性和缺点,例如一般只适用于测量较轻元素的EXAFS谱.激光EXAFS谱仪的结构如图所示. 相似文献
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在神光Ⅱ强激光装置上,用条纹晶体谱仪对埋点于黑腔靶内壁上的双示踪Ti和Cr材料的激光等离子体高离化态离子发射的X射线谱线进行实验测量,获得超高时间分辨的X射线细致结构谱线。用碰撞辐射模型计算了非局域热动平衡的等离子体布居数,组态平均速率系数由一级微扰理论计算,电子波函数由Hartree-Fock Slater自洽场方法计算,给出了Ti和Cr激光等离子体在电子密度为1019~1022cm-3范围内的He-α线强比与电子温度的关系曲线。采用等电子X射线谱线法,获得了黑腔靶激光等离子体冕区的电子温度随激光脉冲加热从低温到高温、然后缓慢下降的演化过程,其峰值达到2.05 keV。 相似文献
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对Arai的靶原级谱分布数据 ,通过插值、拟合处理 ,获得适用于数值积分的Δλ =0 0 0 2nm的谱分布数据 ,建立了新的谱分布数据文件 ,应用于FPM程序中。并对耐热钢GH131进行实验研究。理论强度与测量强度的相关性良好 ;基本参数法与理论影响系数法分析结果与确认值一致 ,对Cr,Ni分析的相对误差 <1 0 %。结果表明 :经处理的Arai的靶原级谱分布数据应用于FPM程序 ,提高了分析准确性 ,并扩大了基本参数法与理论影响系数法的应用范围。 相似文献
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Many modulation techniques have been widely applied to improve the quality of conventional spectra. Here a pressure-modulated EXAFS method is proposed to detect the small changes of local structure induced by the modulation of high pressure. In the experiment a dynamic diamond anvil cell was used to put a periodic load on the sample and lock-in amplifier to measure the modulated EXAFS signals. We have applied this technique to ZnSe and revealed a sensitivity to atomic displacement of 0.1 pm that is about ten times better than that of traditional EXAFS. 相似文献
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A theory program intended for use with extended X‐ray‐absorption fine structure (EXAFS) spectroscopy and based on the popular FEFF8 is presented. It provides an application programming interface designed to make it easy to integrate high‐quality theory into EXAFS analysis software. This new code is then used to examine the impact of self‐consistent scattering potentials on EXAFS data analysis by methodical testing of theoretical fitting standards against a curated suite of measured EXAFS data. For each data set, the results of a fit are compared using a well characterized structural model and theoretical fitting standards computed both with and without self‐consistent potentials. It is demonstrated that the use of self‐consistent potentials has scant impact on the results of the EXAFS analysis. 相似文献
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Nguyen Van Hung Vu Van HungHo Khac Hieu Ronald R. Frahm 《Physica B: Condensed Matter》2011,406(3):456-460
Anharmonic correlated Einstein model (ACEM) and statistical moment method (SMM) have been developed to derive analytical expressions for pressure dependence of the lattice bond length, effective spring constant, correlated Einstein frequency and temperature, Debye-Waller factors (DWF) or second cumulant, first and third cumulants in Extended X-ray Absorption Fine Structure (EXAFS) at a given temperature. Numerical results for pressure-dependent DWF of Kr and Cu agree well with experiment and other theoretical values. Simulated EXAFS of Cu and its Fourier transform magnitude using our calculated pressure-induced change in the 1st shell are found to be in a reasonable agreement with those using X-ray diffraction (XRD) experimental results. 相似文献
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J. Antonowicz A. Pietnoczka T. Drobiazg G.A. Almyras D.G. Papageorgiou G.A. Evangelakis 《哲学杂志》2013,93(15):1865-1875
We have used the X-ray absorption fine structure method and molecular dynamics (MD) simulations to characterize atomic order in Cu-Zr metallic glasses (MGs). The microstructure of these MGs is described in terms of interconnected icosahedral-like clusters (superclusters) which are basic building units reproducing the stoichiometry of the system. The equilibrium MD configurations are used as an input for ab initio calculations of the extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) spectra. The theoretical EXAFS and XANES spectra are compared with those measured for rapidly quenched glassy Cu-Zr alloys. We demonstrate that the experimental results are well reproduced by EXAFS modeling of the population of the superclusters derived from the MD configuration. The average local structural motif can be approximated by Cu-centered icosahedral-like cluster satisfying the condition of maximal local packing efficiency and approximating the system stoichiometry. The simulated XANES exhibits good agreement with experiment, indicating that the atomic order of the MD configuration is consistent with that of the real alloy structure over distances of about 1?nm. 相似文献
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Mark A. Newton 《Journal of synchrotron radiation》2007,14(4):372-381
The effects of focal spot size and the nature of powder samples (such as heterogeneous catalysts) on the quality of data obtainable from a dispersive EXAFS experiment are characterized at ID24 of the ESRF. Using examples of supported Pd catalysts, it is shown that, for a given photon flux, massive improvements in data quality can be achieved by increasing the size of the dispersive beam in the vertical, whilst concurrently applying a methodology to account for scattering effects emanating from the samples under study. These improvements are demonstrated using progressively practical and demanding examples. Questions regarding optimal beam dimensions for the study of such materials, how to counter undesirable effects that arise from the coherence of the source, how to obtain similar results consistently across the 5–30 keV bandwidth of ID24, and whether a methodology for simultaneous normalization in dispersive EXAFS is of significant utility in such circumstances are discussed. 相似文献
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J. Jaklevic J.A. Kirby M.P. Klein A.S. Robertson G.S. Brown P. Eisenberger 《Solid State Communications》1977,23(9):679-682
The fluorescence intensity is used to measure the X-ray absorption cross-section and is found to yield essentially the same results as a more conventional transmission experiment. However, the fluorescence method is shown to extend the sensitivity of the EXAFS technique by two or more orders of magnitude, and thus nake feasible the study of extremely dilute species. 相似文献
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S. Decoster C. J. Glover B. Johannessen R. Giulian D. J. Sprouster P. Kluth L. L. Araujo Z. S. Hussain C. Schnohr H. Salama F. Kremer K. Temst A. Vantomme M. C. Ridgway 《Journal of synchrotron radiation》2013,20(3):426-432
Lift‐off protocols for thin films for improved extended X‐ray absorption fine structure (EXAFS) measurements are presented. Using wet chemical etching of the substrate or the interlayer between the thin film and the substrate, stand‐alone high‐quality micrometer‐thin films are obtained. Protocols for the single‐crystalline semiconductors GeSi, InGaAs, InGaP, InP and GaAs, the amorphous semiconductors GaAs, GeSi and InP and the dielectric materials SiO2 and Si3N4 are presented. The removal of the substrate and the ability to stack the thin films yield benefits for EXAFS experiments in transmission as well as in fluorescence mode. Several cases are presented where this improved sample preparation procedure results in higher‐quality EXAFS data compared with conventional sample preparation methods. This lift‐off procedure can also be advantageous for other experimental techniques (e.g. small‐angle X‐ray scattering) that benefit from removing undesired contributions from the substrate. 相似文献