A possible mechanism for stabilizing elongational flow in certain polymeric liquids at constant temperature and composition

Summary A new calculation of the stability of elongational flow of a liquid filament is based on an idealized treatment of the effects of non-uniformity of filament diameter. Two uniform cylindrical filaments of different initial cross-sectional areas are connected by a fictitious deformable clamp which transmits tensile force without interfering with the assumed homogeneous elongational flow of each filament. A uniform tensile force is suddenly applied and kept constant. For a Newtonian liquid, the area ratio rapidly tends to infinity. For a rubberlike liquid, the area ratio at first increases but then becomes constant; this suggests that finite deformation of a Gaussian molecular network may provide a possible mechanism for spinnability at constant temperature and composition.

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Zusammenfassung Eine neuartige Berechnung der Stabilität des Dehnungs-Fließverhaltens wird auf einer idealisierten Behandlung des Einflusses der Ungleichförmigkeit des Fadendurchmessers aufgebaut. Das Modell besteht aus zwei gleichförmigen zylindrischen Fäden von verschiedenem Ausgangsquerschnitt mit einer fiktiven Verbindung, die Zugkräfte überträgt ohne die angenommenen homogenen Dehnungs-Fließzustände der beiden Fäden zu beeinträchtigen. Eine konstante Zugkraft wird gleichförmig und sprungartig aufgebracht. Für eine Newtonsche-Flüssigkeit geht das Verhältnis der Fadenquerschnitte sehr schnell gegen unendlich. Für eine gummiartige Flüssigkeit nimmt das Verhältnis zuerst zu, bleibt dann aber konstant. Das erlaubt den Schluß, daß endliche Deformation eines Gauss schen molekularen Netzwerks einen möglichen Mechanismus für die Spinnbarkeit bei konstanter Temperatur und Zusammensetzung zu liefern vermag.

     

The effect of background particulates on the delayed transition of a heated 9:1 ellipsoid

An experimental study was done to quantify the effects of a variety of background particulates on the delayed laminar-turbulent transition of a thermally stabilized boundary layer in water. A Laser-Doppler Velocimeter system was used to measure the location of boundary layer transition on a 50 mm diameter, 9:1 fineness ratio ellipsoid. The ellipsoid had a 0.15 m RMS surface finish. Boundary layer transition locations were determined for length Reynolds numbers ranging from 3.0 × 10⁶ to 7.5 × 106. The ellipsoid was tested in three different heating conditions in water seeded with particles of four distinct size ranges. For each level of boundary layer heating, measurements of transition were made for clean water and subsequently, water seeded with 12.5 m, 38.9 m, 85.5 m and 123.2 m particles, alternately. The three surface heating conditions tested were no heating, T = 10°C and T = 15°C where T is the difference between the inlet model heating water temperature, T _i, and free stream water temperature, T . The effects of particle concentration were studied for 85.5 m and 123.2 m particulates.The results of the study can be summarized as follows. The 12.5 m and 38.9 m particles has no measurable effect on transition for any of the test conditions. However, transition was significantly affected by the 85.5 m and 123.2 m particles. Above a length Reynolds number of 4 × 10⁶ the boundary layer transition location moved forward on the body due to the effect of the 85.5 m particles for all heating conditions. The largest percentage changes in transition location from clean water, were observed for 85.5 m particles seeded water.Transition measurements made with varied concentrations of background particulates indicated that the effect of the 85.5 m particles on the transition of the model reached a plateau between 2.65 particulates/ml concentration and 4.2 particles/ml. Measurements made with 123.3 m particles at concentrations up to 0.3 part/ml indicated no similar plateau.     

On surface waves in generalized thermoelasticity

Knowles' representation theorem for harmonically time-dependent free surface waves on a homogeneous, isotropic elastic half-space is extended to include harmonically time-dependent free processes for thermoelastic surface waves in generalized thermoelasticity of Lord and Shulman and of Green and Lindsay.r , , r , , .This work was done when author was unemployed.     

Static and dynamic behaviour of a rigid rotor on journal bearings

This experimental investigation concerns the static and dynamic behaviour of a rigid balanced rotor on journal bearings. Running conditions were chosen in order to obtain relatively high eccentricity ratios near the instability threshold speeds.The results, compared also with the theoretical predictions of some authors, have substantially shown the importance of examining the static behaviour near the instability threshold speed to allow a correct interpretation of some aspects of the dynamic behaviour.In order to clarify the discrepancies between the observed and the theoretically predicted dynamic behaviour, some further tests have been carried out.

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Sommario E' stato esaminato sperimentalmente sia il comportamento statico che quello dinamico di un rotore rigido e bilanciato sostenuto da cuscinetti cilindrici lubrificati.Le condizioni di funzionamento sono state scelte in modo tale che, in prossimità della soglia di instabilità, il valore del rapporto di eccentricità risultasse relativamente grande.I risultati, confrontati anche con le indicazioni teoriche di altri autori, hanno sostanzialmente evidenziato l'importanza dell'esame del comportamento statico in prossimità della soglia di instabilità al fine di interpretare correttamente alcuni aspetti del fenomeno dell'instabilità.Sono state inoltre effettuate una serie di ulteriori indagini con lo scopo di chiarire le discordanze fra il comportamento dinamico osservato e quello previsto dalla teoria.

     

Oberflächenspannung von leichtem und schwerem Wasser

Zusammenfassung Für die Oberflächenspannung von leichtem Wasser wurde von der Arbeitsgruppe III der International Association for the Properties of Steam eine Rahmentafel und eine einfache Interpolationsgleichung erarbeitet und als internationaler Standard empfohlen. Die Rahmentafel basiert auf allen bekannten Messungen der Oberflächenspannung, die einzelnen Meßreihen wurden entsprechend der Meßgenauigkeit gewichtet. Die Form der Interpolationsgleichung läßt sich physikalisch begründen. Sie stellt einen erweiterten Ansatz nach van der Waals dar, wobei der Exponent der Gleichung mit den Scaling-Laws in Übereinstimmung ist. Weiter wird für den praktischen Gebrauch eine einfache Beziehung für den Laplace-Koeffizienten und die Dichtedifferenz zwischen der flüssigen und gasförmigen Phase von leichtem Wasser angegeben.Für schweres Wasser kann die gleiche Form der Interpolationsgleichung verwendet werden, deren Koeffizienten angegeben sind. Allerdings beruht diese Gleichung nur auf einer Meßreihe.

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Surface tension of normal and heavy water

A Skeleton Table and simple interpolation equation for the surface tension of light water was developed by the Working Group III of the International Association for the Properties of Steam and is recommended as an International Standard.The Skeleton Table is based on all known measurements of the surface tension and individual data were weighted corresponding to the accuracy of the measurements. The form of the interpolation equation is based on a physical concept. It represents an extension of van der Waals-equation, where the exponent conforms to the Scaling Laws. In addition for application purposes simple relations for the Laplace-coefficient and for the density difference between the liquid and gaseous phases of light water are given. The same form of interpolation equation for the surface tension can be used for heavy water, for which the coefficients are given. However, this equation is based only on a single set of data.

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Formelzeichen A Oberfläche - B_o Koeffizient - F freie Energie - S Entropie - T Temperatur - T_K kritische Temperatur - U innere Energie - V Volumen - W Arbeit - a Laplace-Koeffizient - a, a_O Koeffizient - b, b₁ Koeffizient - c Koeffizient - g Erdbeschleunigung - Exponent der isochoren Wärmekapazität - Exponent der Koexistenzkurve - Exponent des Laplace-Koeffizienten - Exponent der Korrelationslänge - Exponent der Oberflächenspannung - Exponent der Oberflächenspannung - reduzierte Temperaturdifferenz - Korrelationslänge - Dichte der flüssigen Phase - Dichte der gasförmigen Phase - _o KoeffizientM     

Transport in ordered and disordered porous media II: Generalized volume averaging

In this paper we develop the averaged form of the Stokes equations in terms of weighting functions. The analysis clearly indicates at what point one must choose a media-specific weighting function in order to achieve spatially smoothed transport equations. The form of the weighting function that produces the cellular average is derived, and some important geometrical theorems are presented.Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - A _p surface area of a particle, m² - d _p 6V _p/A_p, effective particle diameter, m - g gravity vector, m/s² - I unit tensor - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p general characteristic length for volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - l characteristic length (pore scale) for the-phase - l _i i=1, 2, 3 lattice vectors, m - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - m _D special convolution product weighting function for disordered media - m _M master convolution product weighting function for ordered and disordered media - n unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p_m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p p p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function, m - r position vector, m - r position vector locating points in the-phase, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - V velocity vector in the-phase, m/s - vm superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - V volume of the-phase contained in the averaging volume, m³ - V _p volume of a particle, m³ - v traditional superficial volume averaged velocity, m/s - v v p _m spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * . weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m² - V /V, volume fraction of the-phase     

Evaluation of the dynamic-mechanical properties of solids from a cooperative model for stress relaxation

For many solid materials the stress relaxation process obeys the universal relationF = – (d/d lnt)_max = (0.1 ± 0.01) ( ₀ — _i ), regardless of the structure of the material. Here denotes the stress,t the time, ₀ the initial stress of the experiment and _i the internal stress. A cooperative model accounting for the similarity in relaxation behaviour between different materials was developed earlier. Since this model has a spectral character, the concepts of linear viscoelasticity are used here to evaluate the corresponding prediction of the dynamic mechanical properties, i.e. the frequency dependence of the storageE () and lossE () moduli. Useful numerical approximations ofE () andE () are also evaluated. It is noted that the universal relation in stress relaxation had a counterpart in the frequency dependence ofE (). The theoretical prediction of the loss factor for high-density polyethylene is compared with experimental results. The agreement is good.     

Nearly viscometric flows in the new rheometers

Summary The linear time-dependent behaviour of elasticoviscous liquids may be determined by conventional rheometers, or by any one of a number of new rheometers which have recently appeared in which the test fluid is contained between two surfaces which rotate with the same angular velocity about axes which are not coincident. (The Orthogonal, Balance and Eccentric-Cylinder rheometers are perhaps the most well known examples of such instruments at the present time.) In this communication, we consider the more general situation in the new rheometers in which the angular velocities of the two surfaces are different.The first part of the paper is concerned with experimental results from the Eccentric-Cylinder Rheometer, with particular reference to the case in which the speeds of the two members are almost the same. The results throw light on the important problem of lag brought about by bearing friction.The main body of work concerns a study of the potential use of the combined steady and oscillatory shear type of flow generated when the instrument members are driven at different speeds. The Balance rheometer is concluded to be of very little use in this connection, and most of the attention is confined to the nearly-viscometric flows generated in the Orthogonal and Eccentric-Cylinder rheometers. It is concluded that the analysis for the Orthogonal Rheometer is too complicated to have any predictive value, but that generalized Eccentric-Cylinder flow may be useful in the context of model assessment.With 4 figures     

Interpolation formulas for maxwell viscosity of certain metals as a function of shear-strain intensity and temperature

The purpose of this study is the construction of interpolation formulas for the dependence of Maxwell viscosity, a quantity which is the reciprocal of shear-strain relaxation time , on shear-strain intensity and temperature for several metals: iron, aluminum, copper, and lead. This function was interpolated in various temperature and deformation velocity ranges in accordance with available experimental data for iron (0 10⁷ sec^–1, 200 ° T 1500 °); aluminum (0 10⁷ sec^–1, 300 ° T 900 °); copper (0 10⁵ sec^–1, 300 ° T 1300 °); lead (0 10⁶ sec^–1, 90 ° T 400 °); temperatures in °K.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 4, pp. 114–118, July–August, 1974.     

Limitation and improvement of PIV

In this second part of the paper, the Particle Image Distortion (PID) technique is described. It is proposed to overcome the limitations of conventional PIV due to the local deformations u/x, u/y, v/x and v/y in two-dimensional flows. Both simulation and experiment demonstrate that high accuracy and high spatial resolution are possible with this technique. The large time required to compute the cross-correlations, however, limits its wide applications at present.     

Das erweiterte Korrespondenzgesetz für die dynamische Idealviskosität und die Idealwärmeleitfähigkeit reiner Stoffe

Zusammenfassung Zur Berechnung der dynamischen Idealviskosität Ideal (T) und der Idealwärmeleitfähigkeit ideal (T) benötigt man die kritische TemperaturT _kr, das kritische spezifische Volum _kr, die MolmasseM, den kritischen Parameter _kr und die molare isochore WärmekapazitätC _v(T). Sowohl das theoretisch, als auch das empirisch abgeleitete erweiterte Korrespondenzgesetz ergeben eine für praktische Zwecke ausreichende Genauigkeit für die Meßwertwiedergabe, die bei den assoziierenden Stoffen und den Quantenstoffen jedoch geringer ist als bei den Normalstoffen.

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The extended correspondence law for the ideal dynamic viscosity and the ideal thermal conductivity of pure substances

For the calculation of the ideal dynamic viscosity Ideal (T) and the ideal thermal conductivity ideal (T) the critical temperatureT _kr, the critical specific volumev _kr, the molecular massM, the critical parameter _kr, and the molar isochoric heat capacityC _v(T) is needed. Not only the theoretically determined but also the empirically determined extended correspondence law gives for practical use a good representation of the measured data, which for the associating substances and the quantum substances is not so good as for the normal substances.

     

On laminar flow through a uniformly porous pipe

Numerous investigations ([1] and [4–9]) have been made of laminar flow in a uniformly porous circular pipe with constant suction or injection applied at the wall. The object of this paper is to give a complete analysis of the numerical and theoretical solutions of this problem. It is shown that two solutions exist for all values of injection as well as the dual solutions for suction which had been noted by previous investigators. Analytical solutions are derived for large suction and injection; for large suction a viscous layer occurs at the wall while for large injection one solution has a viscous layer at the centre of the channel and the other has no viscous layer anywhere. Approximate analytic solutions are also given for small values of suction and injection.

Nomenclature

General r distance measured radially - z distance measured along axis of pipe - u velocity component in direction of z increasing - v velocity component in direction of r increasing - p pressure - density - coefficient of kinematic viscosity - a radius of pipe - V velocity of suction at the wall - r ²/a ² - R wall or suction Reynolds number, Va/ - f() similarity function defined in (6) - u ₀() eigensolution - U(0) a velocity at z=0 - K an arbitrary constant - B _K Bernoulli numbers Particular Section 5 perturbation parameter, –2/R - ² a constant, –K - x / - g(x) f()/ Section 6 perturbation parameter, –R/2 - ² a constant, –K - g() f() - g _c ()=g() near centre of pipe - * point where g()=0 Section 7 2/R - ² K - t (1–)/ - w(t, ) [1–f(t)]/ - ₀, ₁ constants - g() f()– ₀ - ₀/ - ₀ a constant - * point where f()=0     

Lösungen und Schmelzen von Hochpolymeren

Zusammenfassung Die Modelle der ideal verdünnten Lösung und des unendlichen Netzes (Bueche) werden besprochen; für praktische Fälle werden die Modelle verdünnte Lösung mit Gelteilchen und unendliches Netz mit Verhängungsbereichen vorgeschlagen und diskutiert. Es wird eine Methode angegeben, aus dem Übergangspunkt verdünnte Lösung unendliches Netz den Verknäuelungsparameter Am auszurechnen.Einleitungsvortrag anläßlich der Arbeitstagung der Sektion Rheologie des Vereins Österreichischer Chemiker am 28. September 1965 in Graz.     

Peristaltic pumping of a second-order fluid in a planar channel

The peristaltic motion of a non-Newtonian fluid represented by the constitutive equation for a second-order fluid was studied for the case of a planar channel with harmonically undulating extensible walls. A perturbation series for the parameter ( half-width of channel/wave length) obtained explicit terms of 0(²), 0(²Re²) and 0(₁Re²) respectively representing curvature, inertia and the non-Newtonian character of the fluid. Numerical computations were performed and compared to the perturbation analysis in order to determine the range of validity of the terms.Presented at the second conference Recent Developments in Structured Continua, May 23–25, 1990, in Sherbrooke, Québec, Canada     

Free convection heat transfer from an isothermal plate with arbitrary inclination

This paper presents a new formulation for the laminar free convection from an arbitrarily inclined isothermal plate to fluids of any Prandtl number between 0.001 and infinity. A novel inclination parameter is proposed such that all cases of the horizontal, inclined and vertical plates can be described by a single set of transformed equations. Moreover, the self-similar equations for the limiting cases of the horizontal and vertical plates are recovered from the transformed equations by setting=0 and=1, respectively. Heated upward-facing plates with positive and negative inclination angles are investigated. A very accurate correlation equation of the local Nusselt number is developed for arbitrary inclination angle and for 0.001 Pr .

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Wärmeübertragung bei freier Konvektion an einer isothermen Platte mit beliebiger Neigung

Zusammenfasssung Diese Untersuchung stellt eine neue Formulierung der laminaren freien Konvektion von Flüssigkeiten mit einer Prandtl-Zahl zwischen 0,001 und unendlich an einer beliebig schräggestellten isothermen Platte dar. Ein neuer Neigungsparameter wird eingeführt, so daß alle Fälle der horizontalen, geneigten oder vertikalen Platte von einem einzigen Satz transformierter Gleichungen beschrieben werden können. Die unabhängigen Gleichungen für die beiden Fälle der horizontalen and vertikalen Platte wurden für=0 und=1 aus den transformierten Gleichungen wieder abgeleitet. Es wurden erwärmte aufwärtsgerichtete Platten mit positiven und negativen Neigungswinkeln untersucht. Eine sehr genaue Gleichung wurde für die lokale Nusselt-Zahl bei beliebigen Neigungswinkeln und für 0,001 Pr entwickelt.

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Nomenclature C _p specific heat - f reduced stream function - g gravitational acceleration - Gr local Grashof number,g(T _w –T _w ) x³/v² - h local heat transfer coefficient - k thermal conductivity - n constant exponent - Nu local Nusselt number,hx/k - p pressure - Pr Prandtl number, v/ - Ra local Rayleigh number,g(T _w –T )J x³/v - T fluid temperature - T _w wall temperature - T temperature of ambient fluid - u velocity component in x-direction - v velocity component in y-direction - x coordinate parallel to the plate - y coordinate normal to the plate Greek symbols thermal diffusivity - thermal expansion coefficient - (Ra¦sin¦)^1/4/( Ra cos()^1/5 - pseudo-similarity variable, (y/) - dimensionless temperature, (T–T )/(T _w–T ) - ( Ra cos)^1/5+(Rasin)^1/4 - v kinematic viscosity - 1/[1 +(Ra cos)^1/5/( Ra¦sin)^1/4] - density of fluid - Pr/(1+Pr) - _w wall shear stress - angle of plate inclination measured from the horizontal - stream function - dimensionless dynamic pressure     

Effect of Streamwise Streaky Structures on Turbulization of a Circular Jet

Experimental investigations of the influence of streamwise streaky structures on turbulization of a circular laminar jet are described. The qualitative characteristics of jet evolution are studied by smoke visualization of the flow pattern in the jet and by filming the transverse and longitudinal sections of the jet illuminated by the laser sheet with image stroboscopy. It is shown that the streaky structures can be generated directly at the nozzle exit, and their interaction with the Kelvin–Helmholtz ring vortices leads to emergence of azimuthal beams ( structures) by a mechanism similar to threedimensional distortion of the twodimensional Tollmien–Schlichting wave at the nonlinear stage of the classical transition in nearwall flows. The effect of the jetexhaustion velocity and acoustic action on jet turbulization is considered.     

Zur Verknüpfung von Stoffübergang und physikalischen bzw. chemischen Wandvorgängen in technischen Reaktoren

In technical reactors like catalytic honeycombreactors with a reaction at the wall and with an unknown field of concentrationc _A (r,z) the diffusive flux _A,D.w is replaced by the transferflux _A,. The transferflux _A, i.e. the Sherwood-number only depends on processes, which effect the diffusive flux, i.e. the gradient of concentration c _A /r¦ _w . For vaporisation with a constant concentrationc _A,w at the wall or for a heterogeneous reaction with a variable concentrationc _A,w the fluidstream would be such a process. In any case Sherwood-numberSh depends only on Bodenstein-numberBo and is — even for a heterogeneous reaction — no function of Damköhler-number. Only in case of a homogeneous reaction in the fluid phase there is a influence on the gradient of concentration and it followsSh (Bo, Da _I).According toSh _neu (Bo, Da _II) the gradient of concentration c _A /r in _A,D is replaced in _A, by the mean concentration and not, as usual, by the difference of concentration . Both concentrations depends on the Damköhler-numberDa _II. The difference of concentrations shows either no or only little dependence ofDa _II (this illustrates the quality of representation of _A,D,w by _A, ). If is defined by , than _neu depends onDa _II Sh _neu =Sh _neu (Bo, Da _II). According to this definition of _neu no new facts will arise. The common theoretical or experimental values of orSh are applicable to every process with heterogeneous reactions. In analogous cases the following explanations are also valid for heat-transfer at the wall, if a heterogeneous reaction takes place.Zusammenfassung In technischen Reaktoren, wie z. B. einem katalytischen Wabenrohrreaktor, in denen sich das Konzentrationsfeldc _A (r, z) nicht genau ermitteln läßt, ersetzt die Übergangsstromdichte _A, vereinfachend die Diffusionsstromdichte _A,D,w an die Wand. Die Übergangsstromdichte _A, bzw. dieSh-Zahl ist nur von den Vorgängen abhängig, die die Diffusionsstromdichte an die Wand, _A,D,w , d. h. den Konzentrationsgradienten c _A /r¦ _w beeinflussen. Bei Verdampfung mit konstanter Wandkonzentrationc _A,w oder bei einer heterogenen Reaktion an der Wand mit veränderlichemc _A,w ist ein solcher Vorgang z. B. die Strömung, d. h. in beiden Fällen istSh =Sh (Bo) und hängt auch bei einer heterogenen Reaktion nicht von der Damköhler-II-Zahl ab. Nur wenn in der strömenden Phase (zusätzlich) eine homogene Reaktion vorliegt [12], hat diese einen Einfluß auf den Gradienten und es giltSh =Sh (Bo, Da _I).Die AbhängigkeitSh _neu (Bo, Da _II) entsteht definitorisch dadurch, daß der in _A,D auftretende Gradient c _A /r in _A, z. B. durch eine mittlere Konzentration ( _neu), statt wie üblich durch eine Konzentrationsdifferenz , erfaßt wird. Beide Konzentrationen sind von der DamköhlerzahlDa _II abhängig, ihre Differenz aber nicht bzw. wenig (worin sich die Güte der Abbildbarkeit von _A,D,w durch _A, verdeutlicht). Läßt man also in der Definitionsgleichung für die Stoffübergangszahl die veränderliche Wandkonzentrationc _A,w weg, dann entsteht eine entsprechende starke Abhängigkeit der Größe _neu (bzw.Sh _neu) von derDa-II-Zahl:Sh _neu=Sh _neu (Bo, Da _II). Neue Sachverhalte werden mit solchen Definitionen von _neu nicht begründet. Die üblichen theoretisch oder experimentell ermittelten - oderSh-Werte können beim Auftreten von Stoffwandlungsvorgängen an der Wand für reaktionstechnische Berechnungen verwendet werden. Die folgenden Ausführungen gelten bei gegebener Analogie auch für den Wärmeübergang mit physikalischen oder chemischen Wandvorgängen, wie Verdampfung oder chemischer Wandreaktion.     

Two-phase flow in heterogeneous porous media III: Laboratory experiments for flow parallel to a stratified system

Two-phase flow in stratified porous media is a problem of central importance in the study of oil recovery processes. In general, these flows are parallel to the stratifications, and it is this type of flow that we have investigated experimentally and theoretically in this study. The experiments were performed with a two-layer model of a stratified porous medium. The individual strata were composed of Aerolith-10, an artificial: sintered porous medium, and Berea sandstone, a natural porous medium reputed to be relatively homogeneous. Waterflooding experiments were performed in which the saturation field was measured by gamma-ray absorption. Data were obtained at 150 points distributed evenly over a flow domain of 0.1 × 0.6 m. The slabs of Aerolith-10 and Berea sandstone were of equal thickness, i.e. 5 centimeters thick. An intensive experimental study was carried out in order to accurately characterize the individual strata; however, this effort was hampered by both local heterogeneities and large-scale heterogeneities.The theoretical analysis of the waterflooding experiments was based on the method of large-scale averaging and the large-scale closure problem. The latter provides a precise method of discussing the crossflow phenomena, and it illustrates exactly how the crossflow influences the theoretical prediction of the large-scale permeability tensor. The theoretical analysis was restricted to the quasi-static theory of Quintard and Whitaker (1988), however, the dynamic effects described in Part I (Quintard and Whitaker 1990a) are discussed in terms of their influence on the crossflow.Roman Letters A interfacial area between the -region and the -region contained within V, m² - a vector that maps onto , m - b vector that maps onto , m - b vector that maps onto , m - B second order tensor that maps onto , m² - C second order tensor that maps onto , m² - E energy of the gamma emitter, keV - f fractional flow of the -phase - g gravitational vector, m/s² - h characteristic length of the large-scale averaging volume, m - H height of the stratified porous medium , m - i unit base vector in the x-direction - K local volume-averaged single-phase permeability, m² - K - {K}, large-scale spatial deviation permeability - { K} large-scale volume-averaged single-phase permeability, m² - K ^* large-scale single-phase permeability, m² - K ^** equivalent large-scale single-phase permeability, m² - K local volume-averaged -phase permeability in the -region, m² - K local volume-averaged -phase permeability in the -region, m² - K - {K } , large-scale spatial deviation for the -phase permeability, m² - K ^* large-scale permeability for the -phase, m² - l thickness of the porous medium, m - l characteristic length for the -region, m - l characteristic length for the -region, m - L length of the experimental porous medium, m - characteristic length for large-scale averaged quantities, m - n outward unit normal vector for the -region - n outward unit normal vector for the -region - n unit normal vector pointing from the -region toward the -region (n = - n ) - N number of photons - p pressure in the -phase, N/m² - p ₀ reference pressure in the -phase, N/m² - local volume-averaged intrinsic phase average pressure in the -phase, N/m² - large-scale volume-averaged pressure of the -phase, N/m² - large-scale intrinsic phase average pressure in the capillary region of the -phase, N/m² - - , large-scale spatial deviation for the -phase pressure, N/m² - p_c , capillary pressure, N/m² - p _c capillary pressure in the -region, N/m² - p capillary pressure in the -region, N/m² - {p _c } ^c large-scale capillary pressure, N/m² - q -phase velocity at the entrance of the porous medium, m/s - q -phase velocity at the entrance of the porous medium, m/s - S_wi irreducible water saturation - S /, local volume-averaged saturation for the -phase - S _i initial saturation for the -phase - S _r residual saturation for the -phase - S ^* { }^*/}^*, large-scale average saturation for the -phase - S saturation for the -phase in the -region - S saturation for the -phase in the -region - t time, s - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the -phase, m/s - {v } large-scale averaged velocity for the -phase, m/s - v local volume-averaged phase average velocity for the -phase in the -region, m/s - v local volume-averaged phase average velocity for the -phase in the -region, m/s - v -{v } , large-scale spatial deviation for the -phase velocity, m/s - v -{v } , large-scale spatial deviation for the -phase velocity in the -region, m/s - v -{v } , large-scale spatial deviation for the -phase velocity in the -region, m/s - V large-scale averaging volume, m³ - y position vector relative to the centroid of the large-scale averaging volume, m - {y}^c large-scale average of y over the capillary region, m Greek Letters local porosity - local porosity in the -region - local porosity in the -region - local volume fraction for the -phase - local volume fraction for the -phase in the -region - local volume fraction for the -phase in the -region - {}^* { }^*+{ }^*, large-scale spatial average volume fraction - { }^* large-scale spatial average volume fraction for the -phase - mass density of the -phase, kg/m³ - mass density of the -phase, kg/m³ - viscosity of the -phase, N s/m² - viscosity of the -phase, Ns/m² - V /V , volume fraction of the -region ( + =1) - V /V , volume fraction of the -region ( + =1) - attenuation coefficient to gamma-rays, m^-1 - -      

Mathematics and Rheology

Summary The great advances made in Rheology during the last forty years owe much to the application of mathematics. But in some cases, there have been misunderstandings. As a result, rheologists have sometimes been unnecessarily restricted. Mathematics is limited only by self-consistency: Rheology deals with the physical world.In particular, three terms are discussed: infinity, zero and negative, all of which have at least two meanings which have been confused. Rheological phenomena cannot be explained merely by mathematical formulation. Unnecessary mathematics should be avoided but professional rheologists must not shirk mathematics.This paper was read in an abbreviated form, at aConference of the British Society of Rheology in April 1971 The Proceedings were not published.     

Die Eigenschaften von Wasser und Wasserdampf nach „The 1968 IFC Formulation“

Zusammenfassung Diese Arbeit enthält Druck-Temperatur-Diagramme für 6 spezifische Zustandsgrößen und 16 erste Ableitungen und zusammengesetzte Größen von Wasser und Wasserdampf, die nach einem Gleichungssystem berechnet wurden, das unter dem Namen The 1968 IFC Formulation for Scientific and General Use von der 6. Internationalen Konferenz für die Eigenschaften des Wasserdampfes angenommen wurde. Einige Konsequenzen der thermodynamischen Konsistenz, das Verhalten im kritischen Gebiet und bei sehr kleinen Drücken werden diskutiert. Ferner werden die kinematische Viskosität und die Temperaturleitfähigkeit, sowie eine Beziehung zwischen dynamischer Viskosität und isenthalpem Drosselkoeffizienten angegeben.

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This paper contains pressure-temperature diagrams for 6 properties and 16 first derivatives and combined terms for water and steam. These were calculated from a system of equations accepted by the 6^th International Conference on the Properties of Steam, and called The 1968 IFC Formulation For Scientific and General Use. Some consequences of thermodynamic consistency, and the behaviour in the critical region and at very small pressures are discussed. Further, the kinematic viscosity and the thermal diffusivity and a relation between the dynamic viscosity and the throttling coefficient at constant enthalpy are given.

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Bezeichnungen (s. auch Tabelle 1) k Temperaturleitfähigkeit:k=/c _p - p Druck - r spezifische Verdampfungsenthalpie:r=h –h - T thermodynamische oder Kelvin-Temperatur - t Celsius-Temperatur - dynamische Viskosität - Wärmeleitfähigkeit - v kinematische Viskosität:=/ - Dichte:=1/v Indices und Sättigungswerte des Dampfes und der Flüssigkeit Differenz der Sättigungswerte, z. B. h=h –h