一次脉冲偏磁场作用下硬磁泡的形成

实验研究了一次脉冲偏场作用下外延石榴石膜硬磁泡的形成规律。通过实验和计算,证明了硬泡畴壁中同号的VBL一般地说并非一个脉冲产生一对。通过双重曝光照相法揭示出软畴段的硬化与畴段运动形式的关系,发现了最适于硬泡形成的两种运动形式,并阐明了“软硬磁泡形成的分界场”H_[b]的物理意义。 关键词：     

脉冲偏场作用下石榴石磁泡薄膜中布洛赫线的形成

实验研究了石榴石磁泡薄膜中不同脉冲宽度下产生的硬磁畴的动态特性.结果表明：由零偏场下产生的枝状畴收缩而成的哑铃畴均逆时针转动,与产生枝状畴时所用的脉冲偏场的脉冲宽度无关.而固定直流偏场下由软畴段硬化而成的哑铃畴的转动状态,则与所用的硬化脉冲偏场的脉冲宽度有关.低脉冲宽度下硬化成的哑铃畴均逆时针转动,随硬化脉冲宽度的升高,出现混合转动向顺时针转动的过渡.由此揭示了直流偏场和脉冲偏场在石榴石磁泡薄膜中形成正、负垂直布洛赫线的作用. 关键词： 磁畴 磁泡 垂直布洛赫线     

面内磁场对硬磁泡形成的影响

实验研究了面内磁场对一次脉冲偏磁场作用下外延石榴石薄膜中硬磁泡形成的影响,发现存在一个使硬磁泡不再形成的临界面内磁场H_in⁰,它与材料参量有关,通过实验,运用面内磁场对条状畴的作用和枝状畴的形成,定性解释了软硬磁泡形成的分界场H_[b]随面内磁场增大、快降以及缓降这三个物理过程。 关键词：     

垂直布洛赫线在畴段畴壁中的形成和消失

在不同的直流偏场下,对脉冲偏场作用后的磁泡膜中的磁畴观测结果表明:磁泡膨胀时的分枝生长往往伴随有大量垂直布洛赫线(以下称VBL)产生;它的正负与反向畴膨胀时所施加的直流偏场大小有确定关系;在幅度不太高的系列脉冲作用下畴端运动可使畴壁中形成大量VBL;足够强的脉冲偏场可使VBL消失。 关键词：     

石榴石磁泡膜中3类硬磁畴的形成方法

研究石榴石磁泡膜中硬磁畴畴壁中垂直布洛赫线的稳定性可为研制布洛赫线存储器提供有益的帮助 .3类硬磁畴的形成是研究硬磁畴稳定性的前提 .本文综述了在石榴石磁泡膜上形成硬磁畴的 2类方法———“脉冲偏场法”和“低直流偏场法” .结合文献中的典型样品 ,对用“脉冲偏场法”和“低直流偏场法”形成 3类硬磁畴的过程进行了简单介绍 .     

脉冲偏磁场作用下硬磁泡形成与温度的关系

用一次脉冲偏场法研究了外延石榴石磁泡薄膜条状畴畴壁中VBL群体形成与温度的关系。发现了与材料参量有关的临界温度T₀₂,当T>T₀₂时,硬磁泡不再形成。还发现了当T02时,VBL群体形成有两个明显不同的阶段,它们的分界温度为T₀₁。定性解释了第一个阶段的实验曲线并用双重曝光照相法揭示了两个阶段中导致软畴段硬化的运动形式的差别。 关键词：     

掺镁铌酸锂晶体亚微米畴结构特性研究

基于畴背向反转效应，利用外加短脉冲极化电场，通过对脉冲宽度、脉冲间隔以及脉冲个数的有效控制，在掺5mol％镁的铌酸锂晶体上得到周期为1.7μm的均匀亚微米畴结构，其纵向深度为30—50μm.同时，使用脉冲宽度为100ms的宽脉冲信号得到了畴带宽度仅为0.5μm的非对称微畴结构对亚微米畴结构产生的微观机制和物理过程进行了初步探讨. 关键词： 背向反转效应 掺镁铌酸锂晶体 周期极化     

高功率激光整形脉冲波形控制技术

 针对神光-Ⅲ原型装置物理实验要求的三台阶整形脉冲（三个台阶的脉冲宽度比为1.5∶1.0∶0.5,强度比为1∶4∶16,脉冲总能量为500 J）,并根据该装置的系统构成和具备任意脉冲整形技术,开展了高功率激光整形脉冲波形控制技术研究,通过对基频光段的增益饱和效应和三倍频光的频率转换过程的分析,获得了脉冲时间波形在传输、放大及频率转换过程中的一些变化特点,在此基础上建立了一套简单的预测模型。经过反复迭代计算和多次全系统联机实验获得了实验结果,并在物理实验中得到了应用,初步形成了高功率激光整形脉冲波形的控制方法。     

源自软磁畴段的布洛赫线链行为研究

在从1967-1992年连续25年研制固态磁存储器的故事中,中国没有缺席。1970年代初,中国科学院物理研究所磁学室磁泡组11个人从生长基片单晶,制备单晶磁泡薄膜和进行磁泡测量三方面开始磁泡材料的研制。当时文章作者负责测量,设计制作了磁泡测量装置。为了表征磁泡薄膜,发现了含有"一盘"软磁畴段的H图形,并找到了"脉冲偏磁场作用下硬磁泡的形成"的研究课题。这使作者在1980年代初经受住了磁泡下马的冲击,迎来了1983年布洛赫线存储器方案的提出,发觉已具有研究其机理的条件,最终成为该存储器的终结者,并在1991年国际J.Mag.Mag.Mater.杂志第100纪念卷中荣幸地为"China"占了一席之地。从1992年以来,时间又过去了25年,但活生生的磁泡总在,当年报废的磁泡测量装置已经更新。盼望大学生和刚入门的研究者喜欢这台能显示赏心悦目的磁泡畴运动,能生动阐述铁磁学物理基础的研究导向性的物理实验设备。     

面内场对三类硬磁畴的影响

采用直流偏场整形的方法,研究了面内场对石榴石磁泡薄膜中三类硬磁畴的影响.得到面内场作用下三类硬磁畴畴壁中垂直布洛赫线(VBL)是逐步解体的,而且三类硬磁畴具有相同的临界面内场范围［H¹_ip,H²_ip］,其中H¹_ip是硬磁畴中VBL开始丢失时的临界面内场,H²_ip是VBL完全丢失 关键词： 硬磁畴 整形 垂直布洛赫线     

Studies on segmented polyurethane—urea elastomers: Structure and properties of segmented polyurethane—ureas having the binary hard segment components

Studies on the structure and properties of segmented polyurethane-ureas having binary hard segment components have been made using infrared dichroism, small-angle x-ray diffraction, and mechanical testing. The results clarify the effect of the domain structure of the hard segments on the mechanical hysteresis behavior of the segmented polyurethane—urea elastomers. Experiments were carried out for film specimens prepared from poly(tetramethylene glycol), 4, 4'-diphenylmethane diisocyanate, and chain extenders such as ethylenediamine and hydrazine. The domain structures of the hard segments were controlled by blending segmented polyurethane-ureas having different chain extenders. The chain-extending reactions were conducted both simultaneously and in a stepwise manner during polymerization using two different chain extenders. The experimental results revealed that the mechanical hysteresis greatly decreased for the specimens of segmented polyurethane-ureas with binary component hard segments which were randomly copolymerized using the mixture of two different chain extenders. It is suggested that the decrease of hysteresis is related to the microdomain structure of segmented polyurethane-ureas composed of small fragments of lamellae. The small lateral size is caused by the restriction of crystal growth in the direction of hydrogen bond formation due to the heterogeneous hard segment components. This hysteresis phenomenon could be verified by the fact that the transverse orientation of the hard segments decreased in the case of the segmented polyurethane-ureas having randomly copolymerized hard segments. To impart the property of ideal rubber elasticity to segmented polyurethane-urea, it is deduced that it is important to control the hard segment domain structure so that it does not form higher-order structures such as lamellae of large lateral size.     

FORMATION OF MULTI-BRANCHED DOMAINS IN GARNET BUBBLE FILMS BY LOW-BIAS-PULSE METHOD

The formation of multi-branched domains( MBDs) at low static bias field was first studied. With multiple branches, MBDs contain more or less same-signed vertical-Bloch-lines (VBLs) in their walls, Experiments. on four samples have shown that under certain conditions, the amount and hardness of the MBDs formed can be easily controlled, and so-called "low-bias-field method" is another effective way to form VBL chains. It was found that MBDs are formed due to the expansion of domain segments after compressed by a rectangular bias pulse. The number of VBLs nucleated in domain walls is affected by the space where the domains expand rapidly.     

Bloch方程的解析解及其在水峰抑制和特形脉冲设计中的应用

用Laplace变换方法求出了Bloch方程在各种不同物理条件下的解析解,这些解析解物理图象清楚,便于分析,克服了数值解中的困难.解析解和相应的结论已用于水峰抑制和特形脉冲的设计.对于水峰抑制,本文指出抑制效果是有极限的,并给出了抑制效果的极限以及最佳抑制时间的近似计算公式.在特形脉冲的模拟过程中,我们发现只有同时考虑全部四类解析解,才能得到正确的模拟结果,另外,模拟还表明,要在保持激励频谱形状不变的条件下,得到不同倾倒角的脉冲必须改变激励脉冲的形状,相应实验的结果与我们给出的上述结论完全吻合。     

Effect of Symmetry and H‐bond Strength of Hard Segments on the Structure‐Property Relationships of Segmented,Nonchain Extended Polyurethanes and Polyureas

Segmented, nonchain extended polyurethanes and polyureas based on PTMO soft segments (SS) and hard segments (HSs) based on only single molecules of a diisocyanate were synthesized. Type and nature of the diisocyanate was systematically varied in order to analyze the effect of HS symmetry and type of linkage between the HS and SS on the structure‐property relationship of these segmented copolymers. Results showed that the increased symmetry of the diisocyanates allows a more efficient packing of the HSs which leads to a microphase‐separated structure with the crystalline hard ribbon or thread‐like domains percolated throughout the SS matrix, even with a low HS content (ca. 13 wt.%). The service window of these segmented copolymers was significantly influenced by the symmetry and type of linkage between the HS and SS. Most copolymers also showed evidence of strain hardening accented by the strain induced crystallization of the PTMO SS.     

聚酯聚氨酯分子动力学的核磁共振研究

测量了对聚酯聚氨酯在浓溶液状态下质子自旋-晶格弛豫时间随温度的变化,对其中有代表性的基团进行了详细的研究,根据BPP理论用各向同性模型计算分子局部运动的相关时间,从计算结果来看,聚酯聚氨酯的局部分子运动是符合BPP理论的,硬链段的局部分子运动比软链段的局部分子运动要慢得多,两者相差至少一个数量级以上;质子的自旋-晶格弛豫时间主要是偶极-偶极作用的影响;强烈的氢键有相互作用使得硬链段基因的局部运动相关时间接近;通过形成氢键不同的NH峰的相关时间和活化能的观察可以研究软、硬段间的相互作用。     

Properties of segmented polyurethane zwitterionomer elastomers

Four series of polyurethane zwitterionomers based on different soft segment polyols [polyethylene oxide (PEO), polypropylene oxide (PPO), polytetramethylene oxide (PTMO), and polybutadiene (PBD)] were synthesized, and their properties were investigated using differential scanning calorimetry, dynamic mechanical spectroscopy, infrared dichroism, and stress-strain testing. Two different molar ratios of hard segment [4,4′-diphenylmethane diisocyanate (MDI)] to chain extender [N-methyl diethanol-amine (MDEA)] to soft segment polyol, each with three different levels of ionization, were prepared based on the four different polyols. Zwitterionization was accomplished by quaternizing the tertiary amine of MDEA with γ-propane sultone. For the PBD materials, the un-ionized samples exhibited a high degree of phase separation, and ionization served mainly to improve domain cohesion. Increasing ionic content improved material strength while sacrificing extensibility. For the polyether materials the un-ionized samples were not highly phase separated, and ionization improved both the degree of phase separation and hard segment domain cohesion. These morphological changes led to greatly improved mechanical properties. The tensile properties of the ionized PEO and PTMO materials were superior to the tensile properties of the PPO and PBD materials. This was attributed to the ability of the PEO and PTMO segments to crystallize under strain. The effects of segment length (by comparison with a previous study) and hard segment content on mechanical properties are also discussed.     

脉冲偏场作用下硬磁泡的形成

对低频脉冲偏场产生磁泡的过程中硬磁泡的形成条件进行了实验研究。发现硬磁泡的百分比p随着脉冲偏场强度的增加而迅速减小,同时发现存在一临界脉冲偏场强度H_po,当H_p≥H_po时,所产生的磁泡都是软磁泡。 关键词：