液晶高分子各向异性粘弹性流体本构方程理论

将液晶高分子－各向异性流体的本构方程,建立在Oldroyd随体导数观点基础上。推广上随机Oldroyd B流体模型,提出共转OldroydB流体模型,同时将微观结构的影响通过宏观参数表示出来,使在宏观理论中包含微观结构的贡献,即引入取向物质函数,非线性各向异性黏度函数和各向异性松弛时间及推迟时间等,表征取向运动对黏度和松弛及推迟现象的影响,在此基础上开展了一类新的液晶高分子－Oldroyd型本构方程理论,由该类型本构方程得出的物质函数,液晶高分子流体的第一、第二法向应力差与实验结果一致,解释了液晶高分子溶液的第一、第二法向应力差的特殊流变学行为。     

An unsymmetric constitutive equation for anisotropic viscoelastic fluid

A continuum constitutive theory of corotational derivative type is developed for the anisotropic viscoelastic fluid–liquid crystalline (LC) polymers. A concept of anisotropic viscoelastic simple fluid is introduced. The stress tensor instead of the velocity gradient tensor D in the classic Leslie–Ericksen theory is described by the first Rivlin–Ericksen tensor A and a spin tensor W measured with respect to a co-rotational coordinate system. A model LCP-H on this theory is proposed and the characteristic unsymmetric behaviour of the shear stress is predicted for LC polymer liquids. Two shear stresses thereby in shear flow of LC polymer liquids lead to internal vortex flow and rotational flow. The conclusion could be of theoretical meaning for the modern liquid crystalline display technology. By using the equation, extrusion–extensional flows of the fluid are studied for fiber spinning of LC polymer melts, the elongational viscosity vs. extension rate with variation of shear rate is given in figures. A considerable increase of elongational viscosity and bifurcation behaviour are observed when the orientational motion of the director vector is considered. The contraction of extrudate of LC polymer melts is caused by the high elongational viscosity. For anisotropic viscoelastic fluids, an important advance has been made in the investigation on the constitutive equation on the basis of which a series of new anisotropic non-Newtonian fluid problems can be addressed. The project supported by the National Natural Science Foundation of China (10372100, 19832050) (Key project). The English text was polished by Yunming Chen.     

液晶高分子-各向异性流体挤出拉伸分岔研究

应用共转导数型本构方程研究了液晶高分子纺丝挤出过程的拉伸黏度,应用计算机符号运算软件 Maple得出解析表达式,拉伸黏度与拉伸率之间关系(随剪切速率变化)表明存在分岔现象,得出拉伸黏度显著高于相应的剪切黏度,解释了液晶高分子熔体挤出时不发生挤出胀大的物理机制．     

液晶高分子取向特征及其流变性质研究

研究液晶高分子取向特征及其流变性质，在向矢输运方程基础上，研究了管内Posieulle流动和纺丝拉伸流动中一维向矢部分，应用偏光显微镜研究了热致性和溶致性液晶高分子织构，显示出液晶态的各向异性特征，测定了溶致性液晶高分子羟基丙基纤维素（HPC）的流变特性。     

An investigation on internal thermal flow of non-Newtonian fluid

In the present paper an unsteady thermal flow of non-Newtonian fluid is investigated which is of the fiow into axisymmetric mould cavity. In the second part an unsteady thermal flow of upper-convected Maxwell fluid is studied, For the flow into mould cavity the constitutive equation of power-law fluid is used as a rheological model of polymer fluid. The apparent viscosity is considered as a function of shear rate and temperature. A characteristic viscosity is introduced in order to avoid the nonlinearity due to the temperature dependence of the apparent viscosity. As the viscosity of the fluid is relatively high the flow of the thermal fluid can be considered as a flow of fully developed velocity field. However, the temperature field of the fluid fiow is considered as an unsteady one. The governing equations are constitutive equation, momentum equation of steady flow and energy conservation equation of non-steady form. The present system of equations has been solved numerically by the splitting differen     

高强度液晶高分子纺丝纤维取向机制研究

在取向运动输运方程基础上，研究液晶高分子纺丝拉伸流动取向特征、定常取向运动和非定常运动．应用拉格朗日方法研究了轴对称纺丝拉伸流动稳定性．得出液晶高分子纺丝拉伸中分子取向有较高的稳定性，其取向运动具有高抗解取向性，较易形成高取向度，这是制成高强度和高模量纤维、薄膜和模塑制品的基础．     

Stability of plane poiseuille flow of a viscous anisotropic fluid

Experimental investigations show that the presence in a fluid of fibers and rigid asymmetric particles leads to a greater stability of flow in tubes and lowers the turbulent frictional resistance in a certain range of Reynolds numbers [1]. In the present paper, the anisotropic structure of a fluid with additives is described by Ericksen's rheological model [2]. The parameters of the model are particularized in accordance with the paper [3] of Pilipenko, Kalinichenko, and Lemak, and in the limiting case of weak Brownian motion allowance is made for the effect of the predominant orientation of the particles and the influence of additives on the longitudinal and shear viscosity. The stability of the Poiseuille flow is considered in the linear formulation. In an anisotropic viscous fluid, an equation of Orr-Sommerfeld type has a singular point. A rule for choosing the path of integration avoiding the singular point is obtained on the basis of a generalization of the method of Dikii [4] proposed in an investigation of the stability of the flow of an ideal fluid. The results of numerical calculations of the neutral stability curve for two-dimensional perturbations are given.     

Permanent Waves in Slow Free-Surface Flow of a Herschel–Bulkley fluid

Unsteady flow of a viscoplastic fluid on an inclined plane is examined. The fluid is described by the three-parameter Herschel–Bulkley constitutive equation. The set of equations governing the flow is presented, recovering earlier results for a Bingham fluid and steady uniform motion. A permanent wave solution is then derived, and the relation between wave speed and flow depth is discussed. It is shown that more types of gravity currents are possible than in a Newtonian fluid; these include some cases of flows propagating up a slope. The speed of permanent waves is derived and the possible surface profiles are illustrated as functions of the flow behavior index.     

Numerical simulation of entry flow of the IUPAC-LDPE melt

Numerical simulations have been undertaken for the creeping entry flow of a well-characterized polymer melt (IUPAC-LDPE) in a 4:1 axisymmetric and a 14:1 planar contraction. The fluid has been modeled using an integral constitutive equation of the K-BKZ type with a spectrum of relaxation times (Papanastasiou–Scriven–Macosko or PSM model). Numerical values for the constants appearing in the equation have been obtained from fitting shear viscosity and normal stress data as measured in shear and elongational data from uniaxial elongation experiments. The numerical solutions show that in the axisymmetric contraction the vortex in the reservoir first increases with increasing flow rate (or apparent shear rate), goes through a maximum and then decreases following the behavior of the uniaxial elongational viscosity. For the planar contraction, the vortex diminishes monotonically with increasing flow rate following the planar extensional viscosity. This kinematic behavior is not in agreement with recent experiments. The PSM strain-memory function of the model is then modified to account for strain-hardening in planar extension. Then the vortex pattern shows an increase in both axisymmetric and planar flows. The results for planar flow are compared with recent experiments showing the correct trend.     

Squeeze film flow of ideal elastic liquids

An exact solution is presented for the squeeze film flow of an Oldroyd B. fluid. The solution demonstrates that the flow kinematics is similar to the Newtonian (or Maxwellian) one. Theoretical predictions for constant velocity squeezing are compared to experimental observation for well characterized non-shear thinning elastic fluids. It is shown both theoretically and experimentally that the effect of elasticity in a constant velocity squeeze film flow is to always reduce the load relative to the inelastic (Newtonian) prediction and that this load reduction falls between the upper and lower asymptote prediction by the exact solution for the Oldroyd B fluid. The upper load asymptote is given by the Stefan solution for the viscosity of the polymer solution and the lower asymptote is given by the Stefan solution for the viscosity of the solvent. Experimental observations agree with the theoretical prediction for the Oldroyd B fluid at low shear rates where it is shown that the steady and dynamic flow properties of the test fluids used in the experimental program are well represented by the Oldroyd B constitutive equation. With the exception of the work of Lee et al. [6] for constant load squeezing of a Maxwell fluid, this work represents one of the few cases where experimental observation of large effects due to elasticity are indeed predicted with a constitutive equation which actually describes the steady and dynamic shear properties of the fluids used in the experimental program.     

Flow of a generalized second grade non-Newtonian fluid with variable viscosity

A modified constitutive equation for a second grade fluid is proposed so that the model would be suitable for studies where shear-thinning (or shear-thickening) may occur. In addition, the dependence of viscosity on the temperature follows the Reynolds equation. In this paper, we propose a constitutive relation, (18), which has the basic structure of a second grade fluid, where the viscosity is now a function of temperature, shear rate, and concentration. As a special case, we solve the fully developed flow of a non-Newtonian fluid given by (11), where the effects of concentration are neglected.Received: 28 August 2003, Accepted: 3 March 2004, Published online: 25 June 2004 Correspondence to: M. Massoudi Dedicated to Professor Brian Straughan     

管内上随体Maxwell流体非定常流动

本文研究了上随体Maxwell流体在圆管内非定常流动规律,对于上随体Maxwell流体模型,导出了特殊的运动方程,分别应用隐式差分格式和Kantorovich变分法,求得数值解,对两类方法的结果进行比较,揭示了粘弹流效应对管内非定常流动规津的影响,根据上述研究认为,以上的特殊的变分方法适应于研究非定常流动。     

A differential constitutive equation for polymer melts

A modification of the Giesekus constitutive equation is derived by incorporating (approximately, via the Peterlin approximation) the finite extensibility of polymer molecules into dumbbell kinetic theory along with the anisotropic hydrodynamic drag suggested by Giesekus. The constitutive equation that is obtained retains much of the simplicity of Giesekus' constitutive equation, but it involves terms that are cubic in the stress as well as those that are quadratic. It is shown that the constitutive equation quantitatively describes the steady elongational viscosity of the IUPAC polymer melt A (including the strain softening of the melt), but it cannot describe the elongational and shear viscosities simultaneously. It is also shown that the constitutive equation satisfies the Lodge-Meissner relation for shear strains less than unity.     

Viscous Spreading of Non-Newtonian Gravity Currents on a Plane

A gravity current originated by a power-law viscous fluid propagating on a horizontal rigid plane below a fluid of lower density is examined. The intruding fluid is considered to have a pure Ostwald power-law constitutive equation. The set of equations governing the flow is presented, under the assumption of buoyancy-viscous balance and negligible inertial forces. The conditions under which the above assumptions are valid are examined and a self-similar solution in terms of a nonlinear ordinary differential equation is derived. For the release of a time-variable volume of fluid, the shape of the gravity current is determined numerically using an approximate analytical solution derived close to the current front as a starting condition. A closed-form analytical expression is derived for the special case of the release of a fixed volume of fluid. The space-time development of the gravity current is discussed for different flow behavior indexes.     

Non-isothermal polymer melt flow in sudden expansions

This paper presents numerical results for laminar, incompressible and non-isothermal polymer melt flow in sudden expansions. The mathematical model includes the mass, momentum and energy conservation laws within the framework of a generalized Newtonian formulation. Two constitutive relations are adopted to describe the non-Newtonian behavior of the flow, namely Cross and Modified Arrhenius Power-Law models. The governing equations are discretized using the finite difference method based on central, second-order accurate formulas for both convective and diffusive terms. The pressure–velocity coupling is treated by solving a Poisson equation for pressure. The results are presented for two commercial polymers and demonstrate that important flow parameters, such as pressure drop and viscosity distribution, are strongly affected by heat transfer features.     

Surface tension driven oscillations of a bubble in a viscoelastic liquid

Small amplitude surface tension driven oscillations of a spherical bubble in a dilute polymer solution are considered. The rheological properties of the liquid are modelled by using a 3-constant constitutive equation of the Oldroyd type. The Laplace transform of the solution of the initial value problem is inverted numerically. As in the Newtonian fluid case, both a discrete and a continuous spectrum occurs. In addition to the non-dimensional parameters in the corresponding problem for a Newtonian fluid, the results depend on two other parameters: the ratio of the relaxation time of the polymer solution and the time scale of the flow (the Deborah number) and the product of the polymer concentration and the intrinsic viscosity. For small bubbles in an aqueous solution having a small relaxation time, significant additional damping is found even for dilute solutions.     

Sensitivity of shear rate in artificial grafts using automatic differentiation

An accurate numerical simulation of blood requires the solution of incompressible Navier–Stokes equations coupled with specific constitutive models. We consider a generalized Newtonian fluid model in which viscosity depends on shear rate, accounting for the shear‐thinning behavior of blood. Previous work on the design of an artificial graft indicated that there is an influence of the fluid model on the solution of the partial differential equation‐constrained shape optimization problem. Therefore, we carry out a sensitivity analysis of the actual implementation of the flow solver using automatic differentiation (AD). We compare the sensitivities of shear rate with respect to viscosity for different configurations and validate the truncation‐error‐free sensitivities obtained from AD with those based on divided differencing and, if available, with analytic derivatives. Copyright © 2009 John Wiley & Sons, Ltd.     

流体黏性对输流管道运动方程及临界流速的影响

考虑实际流体黏性引起的管内流速非均匀分布,针对层流和两种不同的湍流流态,对理想流体情况下输流管道运动方程中的离心力项进行了修正,得到的修正系数分别为1.333(圆管层流)、1.020(光滑管壁圆管湍流)和1.037～1.055(粗糙管壁圆管湍流).根据修正后的运动方程得到的上述3种情况下的发散失稳临界流速比理想流体流动情况下依次分别低13.4%,1.0%和1.8%～2.6%.流体黏性对输流管道运动方程及临界流速的影响只与流态有关,雷诺数决定流态,而黏性系数通过雷诺数间接起作用.