共查询到20条相似文献,搜索用时 31 毫秒
1.
D. N. Sandzhiev K. G. Abdulvakhidov V. Yu. Shonov I. P. Raevskii 《Technical Physics》2009,54(11):1622-1625
The structure, microstructure, and temperature and field dependences of the dielectric properties of thin (0.5–8.0μm) Sn2P2S6 ferroelectric films deposited onto glass and aluminum foil substrates by thermal vacuum evaporation in a quasi-closed volume
are studied. The film-thickness and frequency dependences of the dielectric properties and the unipolarity of the C–V characteristics are explained by the presence of near-surface Schottky-type barrier layers. 相似文献
2.
Christelle Navone Jean-Pierre Pereira-Ramos Rita Baddour-Hadjean Raphael Salot 《Ionics》2010,16(7):577-580
We report for the first time the use of lithiated crystalline V2O5 thin films as positive electrode in all-solid-state microbatteries. Crystalline LixV2O5 films (x ≈ 0.8 and 1.5) are obtained by vacuum evaporation of metallic lithium deposited on sputtered c-V2O5. An all-solid-state lithium microbattery of Li1.5V2O5/LiPON/Li exhibited a typical reversible capacity of 50 μAh/cm2 in the potential range 3.8/2.15 V which exceeds by far the results known on all-solid-state lithium batteries using amorphous
V2O5 films and lithiated amorphous LixV2O5 thin films as positive electrode. Hence, the present work opens the possibility of using high performance crystalline lithiated
V2O5 thin films in rocking-chair solid-state microbatteries. 相似文献
3.
The Ac electrical conductivity and the dielectric relaxation properties of the [(C3H7)4N]2Cd2Cl6 polycrystalline sample have been investigated by means of impedance spectroscopy measurements over a wide range of frequencies
and temperatures, 209 Hz–5 MHz and 361–418 K, respectively. The purpose is to make a difference between the electrical and
dielectric properties of the polycrystalline sample and single crystal. Besides, a detailed analysis of the impedance spectrum
suggests that the electrical properties of the material are strongly temperature-dependent. Plots of (Z" versus Z') are well
fitted to an equivalent circuit model consisting of a series combination of grains and grains boundary elements. Moreover,
the temperature dependence of the electrical conductivity in the different phases follows the Arrhenius law and the frequency
dependence of σ (ω) follows the Jonscher’s universal dynamic law. Furthermore, the modulus plots can be characterized by full
width at half height or in terms of a nonexperiential decay function φ(t) = exp(t/t)β. Finally, the imaginary part of the permittivity constant is analyzed with the Cole–Cole formalism. 相似文献
4.
Hao Wang Y. Wang J. Feng C. Ye B. Y. Wang H. B. Wang Q. Li Y. Jiang A. P. Huang Z. S. Xiao 《Applied Physics A: Materials Science & Processing》2008,93(3):681-684
High-k gate dielectric hafnium dioxide films were grown on Si (100) substrate by pulsed laser deposition at room temperature. The
as-deposited films were amorphous and that were monoclinic and orthorhombic after annealed at 500°C in air and N2 atmosphere, respectively. After annealed, the accumulation capacitance values increase rapidly and the flat-band voltage
shifts from −1.34 V to 0.449 V due to the generation of negative charges via post-annealing. The dielectric constant is in
the range of 8–40 depending on the microstructure. The I–V curve indicates that the films possess of a promising low leakage
current density of 4.2×10−8 A/cm2 at the applied voltage of −1.5 V. 相似文献
5.
Solid polymer electrolytes (SPE) based on poly-(vinyl alcohol) (PVA)0.7 and sodium iodide (NaI)0.3 complexed with sulfuric acid (SA) at different concentrations were prepared using solution casting technique. The structural
properties of these electrolyte films were examined by X-ray diffraction (XRD) studies. The XRD data revealed that sulfuric
acid disrupt the semi-crystalline nature of (PVA)0.7(NaI)0.3 and convert it into an amorphous phase. The proton conductivity and impedance of the electrolyte were studied with changing
sulfuric acid concentration from 0 to 5.1 mol/liter (M). The highest conductivity of (PVA)0.7(NaI)0.3 matrix at room temperature was 10−5 S cm−1 and this increased to 10−3 S cm−1 with doping by 5.1 M sulfuric acid. The electrical conductivity (σ) and dielectric permittivity (ε′) of the solid polymer electrolyte in frequency range (500 Hz–1 MHz) and temperature range (300–400) K were carried out.
The electrolyte with the highest electrical conductivity was used in the fabrication of a sodium battery with the configuration
Na/SPE/MnO2. The fabricated cells give open circuit voltage of 3.34 V and have an internal resistance of 4.5 kΩ. 相似文献
6.
A. K. Panchal D. K. Rai Meril Mathew C. S. Solanki 《Journal of nanoparticle research》2011,13(6):2469-2473
40 alternate a-Si/SiN
x
multilayer are incorporated as an absorber layer in a p–i–n solar cell. The device is fabricated using hot-wire chemical
vapor deposition (HWCVD) technique. The structure of the multilayer film is examined by high resolution transmission electron
microscopy (HR-TEM) which shows distinct formation of alternate a-Si and SiN
x
layers. The a-Si and SiN
x
layers have thickness of ~3.5 and 4 nm, respectively. The photoluminescence (PL) of multilayer film shows bandgap energy
of ~2.52 eV, is larger than that of the c-Si and a-Si. Dark and illuminated current–voltage (I–V) characterization of the ML films shows that these ML are photosensitive. In the present work, it is seen that the p–i–n
structure with i-layer as ML quantum well (QW) structures show photovoltaic effect with relatively high open-circuit voltage
(V
OC). The increment of bandgap energy in PL and high V
OC of the device is attributed to the quantum confinement effect (QCE). 相似文献
7.
Jing Kong Jiurong Liu Fenglong Wang Liqiang Luan Masahiro Itoh Ken-ichi Machida 《Applied Physics A: Materials Science & Processing》2011,105(2):351-354
Large-scale octahedral Fe3O4 nanocrystallines with crystalline size of 100−500 nm were synthesized by a facile solvent-thermal method for electromagnetic
wave application. The Fe3O4 nanocrystallines showed a higher saturation magnetization (M
s
) value of 86.8 emu/g and larger coercivity (H
cj
) value of 255 Oe than that of magnetite polycrystallines because of their good crystallization and dispersion. The epoxy
resin composites with 40 vol% Fe3O4 powders provided good electromagnetic wave absorption performance (RL < −20 dB) in the range of 2.0–4.3 GHz over the absorber
thicknesses of 3.5–6.8 mm. A minimum RL value of −47 dB was observed at 3.1 GHz with a thickness of 4.8 mm. 相似文献
8.
Metal-insulator-metal (MIM) capacitors were fabricated using ZrO2 films and the effects of structural and native defects of the ZrO2 films on the electrical and dielectric properties were investigated. For preparing ZrO2 films, Zr films were deposited on Pt/Si substrates by ion beam deposition (IBD) system with/without substrate bias voltages and oxidized at 200 °C for 60 min under 0.1 MPa O2 atmosphere with/without UV light irradiation (λ = 193 nm, Deep UV lamp). The ZrO2(∼12 nm) films on Pt(∼100 nm)/Si were characterized by X-ray diffraction pattern (XRD), field emission scanning electron microscopy (FE-SEM) and high-resolution transmission electron microscopy (HRTEM), capacitance-voltage (C-V) and current-voltage (I-V) measurements were carried out on MIM structures. ZrO2 films, fabricated by oxidizing the Zr film deposited with substrate bias voltage under UV light irradiation, show the highest capacitance (784 pF) and the lowest leakage current density. The active oxygen species formed by UV irradiation are considered to play an important role in the reduction of the leakage current density, because they can reduce the density of oxygen vacancies. 相似文献
9.
Mingfu Zhang Hengzhi Chen Bin Yang Wenwu Cao 《Applied Physics A: Materials Science & Processing》2009,97(4):741-744
Layered-perovskite ferroelectric Bi2.85La0.15TiNbO9 (LBTN) optical waveguiding thin films were grown on fused silica substrates by pulsed laser deposition (PLD). X-ray diffraction
(XRD) revealed that the film is highly (00l) textured. We observed sharp and distinct transverse electric (TE) and transverse magnetic (TM) multimodes and measured the
refractive indices of LBTN thin films at 632.8 nm. The ordinary and extraordinary refractive indices were calculated to be
n
TE=2.358 and n
TM=2.464, respectively. The film homogeneity and the film-substrate interface were analyzed using an improved version of the
inverse Wentzel–Kramer–Brillouin (iWKB) method. The refractive index of the film remains constant at n
0 within the waveguiding layer. The average transmittance of the film is 70% in the wavelength range of 400–1400 nm and the
optical waveguiding properties were evaluated by the optical prism coupling method. Our results showed that the LBTN films
are very good electro-optical active material. 相似文献
10.
Y. Köseoğlu M. Bay M. Tan A. Baykal H. Sözeri R. Topkaya N. Akdoğan 《Journal of nanoparticle research》2011,13(5):2235-2244
We present a systematic investigation on the structural and magnetic properties of Mn0.2Ni0.8Fe2O4 nanoparticles synthesized by a polyethylene glycol (PEG)-assisted hydrothermal route. XRD, FT-IR, TEM and VSM were used for
the structural, morphological, dielectric properties and magnetic investigation of the products, respectively. Average crystallite
size of product was estimated using Line profile fitting as 6 ± 1 nm and particle size as 6.5 ± 1.0 nm from TEM micrographs.
Magnetization measurements have shown that the particles have a blocking temperature of 134 K. Magnetization and the coercive
field of the sample increase by decreasing the temperature. The conductivity measurements reveal the semiconducting behaviour
for the sample. Temperature-dependent dielectric properties: dielectric permittivity (ε) and ac conductivity (σac) for the sample were studied as a function of applied frequency in the range from 1 Hz to 3 MHz. These studies indicated
that the dielectric dispersion curve for the sample showed usual dielectric dispersion which can be explained on the basis
of Koop’s theory, which is based on the Maxwell–Wagner model for the interfacial polarization of homogeneous double structure. 相似文献
11.
L. Nedelcu A. Ioachim M. I. Toacsan M. G. Banciu I. Pasuk M. Buda N. Scarisoreanu V. Ion M. Dinescu 《Applied Physics A: Materials Science & Processing》2008,93(3):675-679
Ba0.6Sr0.4TiO3 (BST) bulk ceramic synthesized by solid state reaction was used as target for thin films grown by pulsed laser deposition
(PLD) and radiofrequency beam assisted PLD (RF-PLD). The X-ray diffraction patterns indicate that the films exhibit a polycrystalline
cubic structure with a distorted unit cell. Scanning Electron Microscopy investigations showed a columnar microstructure with
size of spherical grains up to 150 nm. The capacitance–voltage (C–V) characteristics of the BST films were performed by applying
a DC voltage up to 5 V. A value of 280 for dielectric constant and 12.5% electrical tunability of the BST capacitor have been
measured at room temperature. 相似文献
12.
ZrO2 thin films have been prepared on Pt-coated silicon substrates and directly on n-Si(100) substrates by the pulsed laser deposition (PLD) technique using a ZrO2 ceramic target under different deposition conditions. X-ray diffraction showed that the films prepared at 400 °C in 20 Pa oxygen ambient remained amorphous. Differential thermal analysis was carried out to study the crystallization behavior of ZrO2. The dielectric constant of ZrO2 was determined to be around 24 by measuring a Pt/ZrO2/Pt capacitor structure. Sputtering depth profile X-ray photoelectron spectroscopy was used to investigate the interfacial characteristics of ZrO2/n-Si stacks. A Zr silicate interfacial layer was formed between the ZrO2 layer and the silicon substrate. The equivalent oxide thickness (EOT) and leakage current densities of the films with 6.6 nm physical thickness post-annealed in O2 and N2 ambient were investigated. An EOT of 1.65 nm with a leakage current of 36.2 mA/cm2 at 1 V gate voltage for the film post-annealed in N2 has been obtained. ZrO2 thin films prepared by PLD have acceptable structure and dielectric properties required by a candidate material of high-k gate dielectrics. PACS 77.55.+f; 81.15.Fg; 73.40.Qv 相似文献
13.
Guang Yang Aiping Chen Ming Fu Hua Long Peixiang Lu 《Applied Physics A: Materials Science & Processing》2011,104(1):171-175
By controlling the oxygen pressure, single-phase CuO and Cu2O thin films have been obtained on quartz substrates using a pulsed laser deposition technique. The structure properties and
linear optical absorption of the films were characterized by X-ray diffraction and UV–VIS spectroscopy. By performing z-scan measurements using a femtosecond laser (800 nm, 50 fs), the real and imaginary parts of the third-order nonlinear susceptibility,
Re χ
(3) and Im χ
(3), of the films were determined. Both CuO and Cu2O films exhibited large optical nonlinearities, which is comparable to those in some representative semiconductor films such
as ZnO and GaN films using femtosecond laser excitation. Compared with Cu2O films, the CuO films showed larger third-order nonlinear optical effects under off-resonance excitation. Furthermore, the
mechanisms of the optical nonlinearities in CuO and Cu2O films are explained in the main text. It was suggested that the reasons of the difference in their nonlinear refractive
effects may be related to the different electronic structure in CuO and Cu2O materials. 相似文献
14.
M. Behar C. D. Denton R. C. Fadanelli I. Abril E. D. Cantero R. Garcia-Molina L. C. C. Nagamine 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2010,59(2):209-213
We report the results of an experimental-theoretical study on the stopping
power of ZrO2 films for swift H and He ion beams. The experiments,
using the Rutherford Backscattering technique, were done for protons with
incident energies in the range 200–1500 keV and for α-particle beams
with energies in the range 160–3000 keV. The theoretical calculations were
done in the framework of the dielectric formalism using the MELF-GOS model
to account for the ZrO2 target electronic response. It is shown that
for both ion beams, the agreement between theory and experiment is quite
remarkable. 相似文献
15.
Nanoporous SiO2 thin films with ultra-low
dielectric constants were synthesized using a molecular template method.
Uniform films with pore size between 10 and 20 nm were obtained as observed
by N2 adsorption/desorption isotherms and transmission electron
microscopy. Fourier transform infrared spectroscopy (FTIR) and differential
thermal analysis were carried out to investigate the effect of n-hexane
washing on structural properties before and after the surface modification
process. The results showed that –OH bonds were substituted with –CH3 bonds in the films as a result of modification of trimethylchlorosilane
(TMCS)/n-hexane solution. Four kinds of model were used to analyze the
relationship between porosity and dielectric constant of the films, where
the dielectric constant was determined from capacitance-voltage
measurements. The investigation indicated that the corresponding
relationship was in accord with that estimated by the Rayleigh model. 相似文献
16.
Huanfu Zhou Hong Wang Minghui Zhang Xi Yao 《Applied Physics A: Materials Science & Processing》2009,95(2):513-516
A new Li2O–Nb2O5–TiO2 (LNT) ceramic with the Li2O:Nb2O5:TiO2 mole ratio of 5.5:1:7 was prepared by solid state reaction route. The phase and structure of the ceramic were characterized
by X-ray diffraction and scanning electron microscopy (SEM). The microwave dielectric properties of the ceramics were studied
using a network analyzer. The microwave dielectric ceramic has low sintering temperature (∼1075°C) and good microwave dielectric
properties of ε
r=42, Q×f=16900 GHz (5.75 GHz), and τ
f
=63.7 ppm/°C. The addition of B2O3 can effectively lower the sintering temperature from 1075 to 875°C and does not induce degradation of the microwave dielectric
properties. Obviously, the LNT ceramics can be applied to microwave low temperature-cofired ceramics (LTCC) devices. 相似文献
17.
Li1
.2V3O8 and Cu-doped Li1.2V3O8 were prepared at a temperature as low as 300 °C by a sol-gel method. The structure, morphology, and electrochemical performance of the as-prepared samples were characterized
by means of X-ray diffraction, scanning electron microscopy, electrochemical impedance spectroscopy, and the galvanostatic
discharge–charge techniques. It is found that the Cu-doped Li1.2V3O8 sample exhibits less capacity loss during repeated cycling than the undoped one. The Cu-doped Li1.2V3O8 sample demonstrates the first discharge capacity of 275.9 mAh/g in the range of 3.8–1.7 V at a current rate of 30 mA/g and
remains at a stable discharge capacity of 264 mAh/g within 30 cycles. Furthermore, the possible role that copper plays in
enhancing the cycleability of Li1.2V3O8 has also been elucidated. 相似文献
18.
Jyh-Liang Wang Yi-Sheng Lai Bi-Shiou Chiou Chen-Chia Chou Trent Gwo-Yann Lee Huai-Yuan Tseng Chueh-Kuei Jan Huang-Chung Cheng 《Applied Physics A: Materials Science & Processing》2008,90(1):129-134
Pulsed laser deposition (PLD) of (Pb,Sr)TiO3 (PSrT) film on Pt/SiO2/Si at low substrate temperatures (Ts), ranging from 300–450 °C, has been investigated. As Ts increases, the films reveal coarsening clusters, improved crystallization of the perovskite phase, distinct capacitance–electric
field (C–E) hysteretic loops and a larger dielectric constant. The 350 °C-deposited film shows strong (100) preferred orientation
and optimum dielectric properties with the dielectric constant of ∼620. The current density increases as the measurement temperature
and the electric field increase. Moreover, PSrT films exhibit a strong negative temperature coefficient of resistance (NTCR)
behavior at temperatures ranging from 100 to 390 °C.
PACS 81.15.Fg; 77.22.Ch; 68.60.Dv 相似文献
19.
I. S. Edelman E. A. Petrakovskaja D. A. Petrov S. M. Zharkov R. I. Khaibullin V. I. Nuzhdin A. L. Stepanov 《Applied magnetic resonance》2011,40(3):363-375
Fused silica plates have been implanted with 40 keV Co+ or Ni+ ions to high doses in the range of (0.25–1.0) × 1017 ions/cm2, and magnetic properties of the implanted samples have been studied with ferromagnetic resonance (FMR) technique supplemented
by transmission electron microscopy, electron diffraction and energy dispersive X-ray spectroscopy. The high-dose implantation
with 3d-ions results in the formation of cobalt and nickel metal nanoparticles in the irradiated subsurface layer of the SiO2 matrix. Co and Ni nanocrystals with hexagonal close packing and face-centered cubic structures have a spherical shape and
the sizes of 4–5 nm (for cobalt) and 6–14 nm (for nickel) in diameter. Room-temperature FMR signals from ensembles of Co and
Ni nanoparticles implanted in the SiO2 matrix exhibit an out-of-plane uniaxial magnetic anisotropy that is typical for thin magnetic films. The dose and temperature
dependences of FMR spectra have been analyzed using the Kittel formalism, and the effective magnetization and g-factor values have been obtained for Co- and Ni-implanted samples. Nonsymmetric FMR line shapes have been fitted by a sum
of two symmetrical curves. The dependences of the magnetic parameters of each curve on the implantation dose and temperature
are presented. 相似文献
20.
We report on the effect of oxygen partial pressure and vacuum annealing on structural and optical properties of pulsed laser-deposited
nanocrystalline WO3 thin films. XRD results show the hexagonal phase of deposited WO3 thin films. The crystallite size was observed to increase with increase in oxygen partial pressure. Vacuum annealing changed
the transparent as-deposited WO3 thin film to deep shade of blue color which increases the optical absorption of the film. The origin of this blue color could
be due to the presence of oxygen vacancies associated with tungsten ions in lower oxidation states. In addition, the effects
of VO2 content on structural, electrochemical, and optical properties of (WO3)1−x
(VO2)
x
nanocomposite thin films have also been systematically investigated. Cyclic voltammogram exhibits a modification with the
appearance of an extra cathodic peak for VO2–WO3 thin film electrode with higher VO2 content (x ≥ 0.2). Increase of VO2 content in (WO3)1−x
(VO2)
x
films leads to red shift in optical band gap. 相似文献