Σ3 twin boundaries and texture in FCC solid solutions and alloys with <Emphasis Type="Italic">L</Emphasis>1<Subscript>2</Subscript> superstructure

Crystallographic textures in solid solutions (Cu–Al, Cu–Mn) with face-centered cubic lattice, and in alloys (Ni₃Mn, Pd₃Fe) with L1₂ superstructure, are investigated by means of scanning electron microscopy with back-scattered electron diffraction. It is found that an increase in the portion of S3 twin boundaries in a special type of boundary spectrum is accompanied by a strengthening of texture.     

Cellular dislocation substructures in polycrystals of FCC solid solutions based on copper: Holt’s relation and the size effect

The cellular dislocation substructures (CDSes) of Cu-Mn polycrystalline solid solutions upon plastic deformation is studied by means of TEM. It is determined that Holt??s relation holds for alloys with different grain sizes, solid solution concentrations, and deformation temperatures. The dependence of Holt??s coefficient C on the main polycrystalline parameters and deformation conditions is studied. Regularities of the fraction of closed cell boundaries and disoriented boundaries in CDS that emerge upon deformation are determined.     

Defect structure near grain boundaries in deformed polycrystalline Cu–Al alloys

The evolution of defect structure upon the deformation of Cu–Al polycrystalline solid solutions with grain sizes of 10, 100, and 200 μm is studied by means of transmission diffraction electron microscopy. Alloys are deformed by tension at a rate of 10^?2 s^?1 at room temperature. Different parameters that characterize defect structure are measured. Patterns of changes in them are revealed upon moving away from grain boundaries. Analysis of the results testifies to the presence of a reinforced zone near the grain boundaries.     

Transformations in the Grain Boundary Ensemble of M1 Copper Subjected to Equal-Channel Angular Pressing during Recrystallization Annealing

The grain structure of M1 copper subjected to equal-channel angular pressing (ECAP) and subsequent annealing at 593K for 1 h is studied by means of transmission electron microscopy and scanning electron microscopy with the diffraction of backscattered electrons. An increase in grain size and the formation of special boundaries (Σ3 twins both coherent and incoherent) are observed, along with the migration of high-energy Σ3 twins and common grain boundaries, the splitting of Σ9 special boundaries into Σ3 twins, and the splitting of common grain boundaries into Σ9 and Σ3 special boundaries. The local transformation of common grain boundaries into special boundaries also occurs. Particles of the Cu₂O phase are present on the migrating Σ3 twins and common grain boundaries.     

Influence of the degree of long-range atomic order on parameters of the solid solution and the granular structure of the Pd3Fe alloy with superstructure L12

It has been established using X-ray structural analysis and scanning electron microscopy that the lattice parameter and total root-mean-square (rms) atomic displacements increase in the Pd₃Fe polycrystal-line alloy during the A1 → L1₂ phase transition and with an increase in the degree of long-range atomic order, while the microdistortions of the crystal lattice and the fraction of the Σ3 twin boundaries in the spectrum of special boundaries decrease; the latter leads to strengthening the texture.     

Peculiarities of the interaction of polycrystalline aluminum with aqueous solutions of gallium

We study the effect of gallium-containing aqueous solutions on polycrystalline aluminum. The procedure for kinetic studies of the selected system is described. It is found that in the reaction of polycrystalline aluminum with gallium-containing aqueous solutions, gallium penetrates along the aluminum grain boundaries, which, upon the application of external stress, leads to failure of the sample. It is found that gallium can penetrate along the aluminum grain boundaries both in the liquid and solid state; the rates of penetration of gallium in the liquid and solid states are determined.     

Grain boundary behavior in metallic solid solutions as deduced from diffusion and segregation experiments

Grain boundary diffusion and segregation experiments have been carried out in the same metallic solid solutions by means of radio-isotopes and Auger techniques. It was shown that the mass transport parameters could only be understood by assuming the formation of “2D phases” in “segregated grain boundaries” where the main bonds between atoms were identical to those which limit the bulk solid solubility of the solutes.     

Electron backscatter diffraction study of changes in the grain structure of Ni3Fe ordering alloy upon an A1 → L12 phase transition

The rearrangement of the grain structure of Ni₃Fe alloy upon an A1 → L1₂ phase transition is studied via transmission electron microscopy in combination with the electron backscatter diffraction. It is established that the formation of fresh grain boundaries of general and special types occurs, with the proportion of special-type grain boundaries in the grain boundary ensemble growing. The spectrum of the special grain boundaries changes, due to an increase of the proportion of grain boundaries Σ3 and Σ9. This strengthens the texture of the long-range ordered alloy.     

Special interaction between quasiperiodic grain boundaries and lattice dislocations in crystalline solids

A theoretical model is suggested which describes phason imperfections (specific excitations) in a quasiperiodic grain boundary in a polycrystalline solid as dilatation flexes. In the framework of the model, an elastic stress field of the quasiperiodic grain boundary is calculated as a stress field created by an ensemble of dilatation flexes (phason imperfections) located in the boundary. It is shown that there is a special elastic interaction between crystal lattice defects and quasiperiodic grain boundaries comprising phason imperfections. The strengthening effect in plastically deformed polycrystalline solids is quantitatively described which is related to the special elastic interaction between lattice dislocations and quasiperiodic grain boundaries. Received: 29 October 1996 / Revised: 22 August 1997 / Accepted: 13 November 1997     

Correlation among grain boundary character,carbide precipitation and deformation in Alloy 690

The correlation among grain boundary character, carbide precipitation and deformation in the grain boundary engineering (GBE) treated Alloy 690 samples with and without pre-deformation aged at 715^oC for 15?h was analysed by scanning electron microscopy and electron backscatter diffraction. The fraction of low Σ coincidence site lattice (CSL) grain boundary was enhanced by GBE treatment. The fraction of Σ3 grain boundary decreased, and most of Σ9 and Σ27 grain boundaries disappeared in the deformed GBE samples. After aging treatment, bigger carbide precipitated at coherent Σ3 grain boundary, however, most of plate-like carbide precipitated at incoherent Σ3 grain boundary disappeared in the pre-deformed GBE samples. The larger carbide precipitated on the random grain boundary in the 5% pre-deformed sample, while smaller carbide can be observed in the 15% pre-deformed sample. During the in situ tensile test of the aged GBE samples, grain boundary carbide migrated with the grain boundary migration. The slip bands go across Σ3 grain boundary directly, but cannot go across other grain boundaries. The high density of carbide plate precipitated near incoherent Σ3 and Σ9 grain boundaries can resist the evolution of slip bands. Compared to the Σ3 and Σ9 grain boundaries, Σ27 and random grain boundaries are more easily to form microcrack during deformation. The initiation of grain boundary microcrack not only related to the character of grain boundary but also related to the character of nearby grain boundaries. The phase interface of carbide and matrix is another region to initiate the microcrack.     

The effect of antiphase domains on the energy spectra of special boundaries in alloys with the <Emphasis Type="Italic">L</Emphasis>1<Subscript>2</Subscript> superstructure

The special grain boundaries in ordering alloys with the L1₂ superstructure have been investigated by optical metallography and transmission diffraction electron microscopy. The relative energy of the boundaries Σ3 and Σ9 in Ni₃Fe alloy with a short-range order is determined. The energy of these boundaries in an alloy with long-range order is estimated. The energy of twin grain boundaries increases at the phase transitions A1 → L1₂ due to the formation of antiphase grain boundaries in those boundaries. The spectra of special boundaries over Σ and their distributions, depending on the relative energy, change as well. The average relative energy of special grain boundaries in alloys with the L1₂ superstructure increases with increasing the energy of antiphase boundaries.     

Diffusion and segregation along grain boundary at the electrolyte-anode interface in IT-SOFC

The atomic level chemical and microstructural features of grain boundaries in gadolinium-doped ceria (GDC) electrolyte thin film supported by Ni-GDC cermet anode were characterized by high resolution transmission electron microscope (HR-TEM) and scanning TEM (STEM). It was found that metallic Ni can diffuse from the anode into the thin film electrolyte along grain boundaries. In addition, Ce and Gd can also diffuse and segregate at grain boundaries between Ni grains in the anode substrate. HR-TEM observations revealed that Ni diffusion and segregation at grain boundaries between GDC grains enhanced the inhomogeneity and led to microstructural changes at grain boundary regions, i.e. the formation of superstructure. The observations also indicated that enhanced inhomogeneity at grain boundaries might play a significant role in the conductivity of GDC electrolyte film in solid oxide fuel cells.     

Periodic domain structures obtained by growth of LiNbO<Subscript>3</Subscript> crystals doped with gadolinium

The growth of a periodic domain structure in LiNbO₃ crystals doped with gadolinium (Gd, 0.44 wt %) was investigated by special electron beam surface charging in a scanning electron microscope and on a atomic force microscope. Ferroelectric domain boundaries with “tail-to-tail” and “head-to-head” P _s orientations were comparatively analyzed. The domain boundaries had different forms and differed by their physical properties. Micron-size surface crystal regions close to the “tail-to-tail” boundaries were charged slower by electron irradiation and had modified elastic properties. This region was detected by using the lateral force mode of atomic force microscopy. The observed morphology and property features were supposed to be due to different concentration gradients of the Gd impurity and different width of its distribution close to the domain boundaries of different types.     

双动边界一维空腔中的能量密度

利用广义Moore方程的数值解，计算了具有做简谐振动的双边界一维空腔中的能量密度. 能量密度的性质与运动边界的振幅、频率和相差密切相关.取某些特殊的参数值时，能量密度呈现出波包结构. 关键词： 双动边界 广义Moore方程 能量密度     

Effect of the wetting of grain boundaries on the formation of a solid solution in the Al-Zn system

Phase transitions in the bulk and at grain boundaries in the (Al-20 wt % Zn) alloy have been studied by means of differential scanning calorimetry and transmission electron microscopy. Polycrystals with a high specific area of grain boundaries have been obtained using severe plastic deformation (high-pressure torsion). It has been shown that the Zn-based solid phase completely wets the grain boundaries in aluminum at a temperature of 200°C. The position of the grain boundary solvus line (solubility line), which is above the bulk solvus by 40?C45 K, has been determined.     

An Eulerian method for multi-component problems in non-linear elasticity with sliding interfaces

This paper is devoted to developing a multi-material numerical scheme for non-linear elastic solids, with emphasis on the inclusion of interfacial boundary conditions. In particular for colliding solid objects it is desirable to allow large deformations and relative slide, whilst employing fixed grids and maintaining sharp interfaces. Existing schemes utilising interface tracking methods such as volume-of-fluid typically introduce erroneous transport of tangential momentum across material boundaries. Aside from combatting these difficulties one can also make improvements in a numerical scheme for multiple compressible solids by utilising governing models that facilitate application of high-order shock capturing methods developed for hydrodynamics. A numerical scheme that simultaneously allows for sliding boundaries and utilises such high-order shock capturing methods has not yet been demonstrated. A scheme is proposed here that directly addresses these challenges by extending a ghost cell method for gas-dynamics to solid mechanics, by using a first-order model for elastic materials in conservative form. Interface interactions are captured using the solution of a multi-material Riemann problem which is derived in detail. Several different boundary conditions are considered including solid/solid and solid/vacuum contact problems. Interfaces are tracked using level-set functions. The underlying single material numerical method includes a characteristic based Riemann solver and high-order WENO reconstruction. Numerical solutions of example multi-material problems are provided in comparison to exact solutions for the one-dimensional augmented system, and for a two-dimensional friction experiment.     

Direct evidence for Ge preferential growth at steps and out-of-phase boundaries of (7 × 7) domains on Si(111) in solid phase epitaxy

Ge solid phase epitaxy on a Si(111) surface has been directly observed by secondary electron surface microscopy which is based on scanning electron microscopy. Ge island formation initially occurs at steps and out-of-phase boundaries of (7 × 7) domains. These results confirm the origin of previously reported mesh patterns of Ge islands grown on Si(111).     

Electronic and thermoelectric properties of Mg_2Ge_xSn-_(1-x)(x=0.25,0.50,0.75) solid solutions by first-principles calculations

The electronic structure and thermoelectric(TE) properties of Mg_2Ge_xSn_(1-x)(x = 0.25, 0.50, 0.75) solid solutions are investigated by first-principles calculations and semi-classical Boltzmann theory. The special quasi-random structure(SQS) is used to model the solid solutions, which can produce reasonable band gaps with respect to experimental results.The n-type solid solutions have an excellent thermoelectric performance with maximum zT values exceeding 2.0, where the combination of low lattice thermal conductivity and high power factor(PF) plays an important role. These values are higher than those of pure Mg_2Sn and Mg_2Ge. The p-type solid solutions are inferior to the n-type ones, mainly due to the much lower PF. The maximum zT value of 0.62 is predicted for p-type Mg_2Ge_(0.25)Sn_(0.75) at 800K. The results suggest that the n-type Mg_2Ge_xSn_(1-x) solid solutions are promising mid-temperature TE materials.     

Dependence of grain boundary character distribution on the initial grain size of 304 austenitic stainless steel

Abstract

In order to study the dependence of the grain boundary character distributions (GBCD) on the grain size, annealing treatment was carried out on 304 austenitic stainless steel with different initial grain sizes. The evolution of the GBCD was analysed by electron backscatter diffraction. The experimental results showed that abnormal grain growth (AGG) occurred when grain size was small. With a smaller initial grain size, the number density of abnormally large grains and the fraction of low-Σ CSL boundaries increased but the size of abnormally large grains decreased and the random boundaries presented a continuous network. With a larger initial grain size, the fraction of low-Σ CSL boundaries also increased as well as the size of abnormally large grains but the number density of abnormally large grains decreased and the connectivity of random boundary network was disrupted by low-Σ CSL boundaries, especially Σ3ⁿ (n = 1, 2, 3) boundaries. However, with a very large initial grain size, normal grain growth (NGG) occurred, which had no effect on the fraction of low-Σ CSL boundaries and the connectivity of random boundary network.