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1.
On semipolar epitaxial ZnO grown by chemical vapor deposition consists of two distinct orientations as evidenced by transmission electron microscopy and X‐ray diffraction. The initially grown ZnO on GaN follows the GaN lattice with the epitaxial relationship of // and The other oriented ZnO domains then grow on faceted with and with good coherency with the ‐oriented grains. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)  相似文献   

2.
By high‐throughput screening Fe–Sn–Cr, (Fe,Cr)3Sn2 (Fe53.5Cr6.5Sn40) with high potential as new hard magnetic compound is discovered. To produce the compound in large amounts a special procedure is needed. By quantitative microscopy and magnetometry promising intrinsic properties, Js ~ 0.9 T, K1 ~ 1.7 MJ/m3, TC ~ 612 K, are found with K1 increasing with temperature.

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3.
We reported the characteristics of p‐type tin‐oxide (SnO) thin film transistors (TFTs) upon illumination with visible light. Our p‐type TFT device using the SnO film as the active channel layer exhibits high sensitivity toward the blue‐light with a high light/dark read current ratio (Ilight/Idark) of 8.2 × 103 at a very low driven voltage of <3 V. Since sensing of blue‐light radiation is very critical to our eyes, the proposed p‐type SnO TFTs with high sensitivity toward the blue‐light show great potential for future blue‐light detection applications.

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4.
We report the synthesis of single‐phase Bi3O2S3 sample and confirm the occurrence of bulk superconductivity with transition temperature at 5.8 K. The Bi3O2S3 superconductor is categorized as typical type‐II superconductor based on the results of both temperature and magnetic field dependences of magnetization. Hall coefficient measurements give evidence of a multiband character, with a dominant conduction mainly by electron‐like charge carriers. The charge carrier density is about 1.45 × 1019 cm–3, suggesting that the system has very low charge carrier density.

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5.
The α‐PbO2‐type TiO2 is synthesized under high‐pressure and high‐temperature environment and it shows higher photocatalytic activity as compared to rutile and anatase under UV irradiation. The reduction in α‐PbO2‐type TiO2 induces visible‐light photocatalytic activity. These results indicate that α‐PbO2‐type TiO2 is an important candidate material for use in a photocatalytic matrix.

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6.
Ralf Hofmann 《Annalen der Physik》2015,527(3-4):254-264
Presuming that CMB photons are described by the deconfining phase of an SU(2) Yang‐Mills theory with the critical temperature for the deconfining‐preconfining phase transition matching the present CMB temperature K (SU(2)CMB), we investigate how CMB temperature T connects with the cosmological scale factor a in a Friedmann‐Lemaître‐Robertson‐Walker Universe. Owing to a violation of conformal scaling at late times, the tension between the (instantaneous) redshift of reionisation from CMB observation () and quasar spectra () is repealed. Also, we find that the redshift of CMB decoupling moves from to which questions ΛCDM cosmology at high redshifts. Adapting this model to the conventional physics of three flavours of massless cosmic neutrinos, we demonstrate inconsistency with the value Neff ~ 3.36 extracted from Planck data. Interactions between cosmic neutrinos and the CMB implies a common temperature T of (no longer separately conserved) CMB and neutrino fluids. Neff ~ 3.36 then entails a universal, temperature induced cosmic neutrino mass with . Our above results on zre and zdec, derived from SU(2)CMB alone, are essentially unaffected when including such a neutrino sector.

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7.
Metal–insulator–metal capacitors (MIMCAP) with stoichiometric SrTiO3 dielectric were deposited stacking two strontium titanate (STO) layers, followed by intermixing the grain determining Sr‐rich STO seed layer, with the Ti‐rich STO top layer. The resulted stoichiometric SrTiO3 would have a structure with less defects as demonstrated by internal photoemission experiments. Consequently, the leakage current density is lower compared to Sr‐rich STO which allow further equivalent oxide thickness downscaling.

Schematic of MIMCAP with stoichiometric STO dielectric formed from bottom Sr‐rich STO and top Ti‐rich STO after intermixing during crystallization anneal.  相似文献   


8.
Polymers such as benzocyclobutene are commonly used as embedding materials for semiconductor nanostructures. During the curing process of the polymer up to 250 °C, a significant impact of strain can be induced on the embedded semiconductor material due to different thermal expansion coefficients. This strain has been revealed by X‐ray diffraction in free‐standing GaAs nanowires grown on a silicon substrate, embedded in a polymer matrix. It will be shown that this strain is released during the X‐ray irradiation if additionally an external static electric field is applied.

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9.
A Cu‐based organic–inorganic perovskite framework exhibits high‐temperature ferroelectricity with strong magnetoelectric effects. Both electric field control of magnetization and magnetic field control of polarization are realized. Theoretical calculations suggest that a new mechanism of hybrid improper ferroelectricity arising from the Jahn–Teller distortions of magnetic metal ions and tilting of the organic cations are responsible for the peculiar multiferroic behaviors.

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10.
Epitaxial thin films of ferromagnetic La0.7Sr0.3MnO3 (LSMO) and charge‐ordered, antiferromagnetic Y0.5Ca0.5MnO3 (YCMO) were deposited on SrTiO3 (100) substrates by pulsed laser deposition (PLD). The heterostructure undergoes tetragonal distortion due to strong biaxial tensile strain imposed by the substrate. The LSMO–YCMO bilayers exhibit significant exchange bias (EB) across the interface even in a very small remnant magnetic field (~5 Oe) present in the superconductor magnet. The unidirectional exchange anisotropy at the interface can be switched by reversing the polarity of the remnant magnetic field.

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11.
Lead‐free and more air‐stable perovskite Cs2SnI6 absorber with a direct bandgap of 1.48 eV is synthesized via a modified solution process. Different nanostructured ZnO nanorod arrays as electron transport layers and hole blocking layers are grown by controlling the seed layer and used to fabricate mesoscopic perovskite solar cells with Cs2SnI6 as light absorber layer. The influences of ZnO seed layers and nanorod morphology on the device photovoltaic performance were also investigated. With careful control of ZnO nanorod length and pore size to ensure high loading of the Cs2SnI6 absorber, we achieved power conversion efficiency of near 1%.

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12.
A single particle obeys the Dirac equation in spatial dimensions and is bound by an attractive central monotone potential that vanishes at infinity. In one dimension, the potential is even, and monotone for The asymptotic behavior of the wave functions near the origin and at infinity are discussed. Nodal theorems are proven for the cases and , which specify the relationship between the numbers of nodes n1 and n2 in the upper and lower components of the Dirac spinor. For , whereas for if and if where and This work generalizes the classic results of Rose and Newton in 1951 for the case Specific examples are presented with graphs, including Dirac spinor orbits   相似文献   

13.
Layered growth of molybdenum disulphide (MoS2) was successfully achieved by pulsed laser deposition (PLD) method on c ‐plane sapphire substrate. Growth of monolayer to a few monolayer MoS2, dependent on the pulsed number of excimer laser in PLD is demonstrated, indicating the promising controllability of layer growth. Among the samples with various pulse number deposition, the frequency difference (A1g–E12g) in Raman analysis of the 70 pulse sample is estimated as 20.11 cm–1, suggesting a monolayer MoS2 was obtained. Two‐dimensional (2D) layer growth of MoS2 is confirmed by the streaky reflection high energy electron diffraction (RHEED) patterns during growth and the cross‐sectional view of transmission electron microscopy (TEM). The in‐plane relationship, (0006) sapphire//(0002)MoS2and sapphire//MoS2 is determined. The results imply that PLD is suitable for layered MoS2 growth. Additionally, the oxide states of Mo 3d core level spectra of PLD grown MoS2, analysed by X‐ray photoelectron spectroscopy (XPS), can be effectively reduced by adopting a post sulfurization process. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)  相似文献   

14.
Iron nanowires with a square cross section are grown by pulsed electrodeposition within a newly developed nanochannel template that allows for easy characterization. Measurements of the magnetoresistance as a function of magnetic field and temperature are performed within a large parameter window allowing for the investigation of the magnonic contribution to the magnetoresistance of electrodeposited iron nanowires. Values for the temperature dependent magnon stiffness D (T) are extracted: D (T) = D0(1 – d1T2) = 365(1 – 4.4 × 10–6 · T2 · K–2) meV Å2.

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15.
Shannon entropy for the position and momentum eigenstates of an asymmetric trigonometric Rosen–Morse potential for the ground and first excited states is evaluated. The position and momentum information entropies and are calculated numerically. Also, it is found that is obtained analytically and increases with the potential depth and width. Some interesting features of the information entropy densities and are demonstrated graphically. The Bialynicki‐Birula–Mycielski inequality is also tested and found to hold good.  相似文献   

16.
Trends between the Hammett's σp and related normal , inductive σI, resonance σR, negative and positive polar conjugation and Taft's σp° substituent constants and the distance, δN? H NMR chemical shift, oxidation potential (Ep/2°x, measured in this study by cyclic voltammetry (CV)) and thermodynamic parameters (pK, ΔG0, ΔH0 and ΔS0) of the dissociation process of unsubstituted 3‐(phenylhydrazo)pentane‐2,4‐dione (HL1) and its para‐substituted chloro (HL2), carboxy (HL3), fluoro (HL4) and nitro (HL5) derivatives were recognized. The best fits were found for σp and/or in the cases of , δN? H and Ep/2°x, showing the importance of resonance and conjugation effects in such properties, whereas for the above thermodynamic properties the inductive effects (σI) are dominant. HL2 exists in the hydrazo form in DMSO solution and in the solid state and contains an intramolecular H‐bond with the distance of 2.588(3) Å. It was also established that the dissociation process of HL1–5 is non‐spontaneous, endothermic and entropically unfavourable, and that the increase in the inductive effect (σI) of para‐substitutents (? H < ? Cl < ? COOH < ? F < ? NO2) leads to the corresponding growth of the distance and decrease of the pK and of the changes of Gibbs free energy, of enthalpy and of entropy for the HL1–5 acid dissociation process. The electrochemical behaviour of HL1–5 was interpreted using theoretical calculations at the DFT/HF hybrid level, namely in terms of HOMO and LUMO compositions, and of reactivities induced by anodic and cathodic electron‐transfers. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

17.
A single spin‐1/2 particle obeys the Dirac equation in spatial dimension and is bound by an attractive central monotone potential which vanishes at infinity (in one dimension the potential is even). This work refines the relativistic comparison theorems which were derived by Hall 1 . The new theorems allow the graphs of the two comparison potentials and to crossover in a controlled way and still imply the spectral ordering for the eigenvalues at the bottom of each angular momentum subspace. More specifically in a simplest case we have: in dimension , if , then ; and in dimensions, if , where and , then .

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18.
This work demonstrates the formation of Ag fractals on top of a Ag:TiO2 thin film. The dendrite‐type objects emerged from a homogeneous and highly transparent Ag:TiO2 nanocomposite, via the mechanism of diffusion‐limited‐aggregation of Ag atoms, during heat‐treatment at 500 °C. A porous TiO2 matrix was also formed during this process, opening a wide range of possible applications, namely in sensing‐based ones, together with surface enhanced spectroscopies. Furthermore, fractals incorporate a wide range of shapes and spatial scales, inducing a potentially interesting optical response, over the whole visible range, presumably related with localized surface plasmon modes with very broad spectral distribution.

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19.
The excitons in the orthorhombic phase of the perovskite CH3NH3PbI3 are studied using the effective mass approximation. The electron–hole interaction is screened by a distance‐dependent dielectric function, as described by the Haken potential or the Pollmann–Büttner potential. The energy spectrum and the eigenfunctions are calculated for both cases. The results show that the Pollmann–Büttner model, using the corresponding parameters obtained from ab initio calculations, provides better agreement with the experimental results.

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20.
Pentacene thin‐film transistor with high‐κ TaLaO as gate dielectric has been fabricated and shows a carrier mobility of 0.73 cm2/V s, much higher than that based on pure La2O3 (0.43 cm2/V s) due to the smoother surface of the TaLaO film and thus larger pentacene islands grown on it in the initial stage. Moreover, among various times for fluorine‐plasma treatment on the TaLaO gate dielectric, 100 seconds result in the highest carrier mobility of 1.12 cm2/V s due to (1) smoothest oxide surface achieved by fluorine passivation of oxide traps, as measured by AFM and supported by smallest sub‐threshold swing and lowest low‐frequency noise; (2) the largest pentacene grains grown on the smoothest oxide surface, as demonstrated by AFM.

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