Measurements of temperatures and OH-concentrations in a lean methane-air flame using high-resolution laser-absorption spectroscopy

Line profile measurements of selected spectral lines in the 1-0 band of the A²Σ⁺-X²π system of OH near 2830 Å, using a tunable, frequency-doubled dye laser, have been made to determine simultaneously the translational temperature and hydroxyl concentration in a laminar, flat methane-air flame. The rotational temperature was determined from the ratio of two line-absorption coefficients. The rotational degree of freedom was found to be in equilibrium with the translational degree of freedom. Values deduced for the collision broadening parameter in the 1-0 band depend on OH-concentration, ground state rotational quantum number and, possibly, on the vibrational quantum number.     

Theoretical analysis of the multi-rotational line TEA CO2 laser

A theoretical model for the multiline TEA CO₂ laser has been developed which takes into account the overlap of the P(20) line of (00⁰1) (10⁰0) regular band transition with the R(23) line of (01¹1) (11¹0) hot band transition. The model is used for the study of the influence of different parameters like laser gas temperature, gas mixture and pump rates on laser intensities of different rotational lines. This study explains the experimental results of the high power multiline TEA CO₂ laser very well.     

Broadband photoluminescence from pulsed laser deposited Er2O3 films

Photoluminescence (PL) with the bandwidth of 45 nm (1523-1568 nm at the level of 3 dB) was observed in amorphous Er₂O₃ films grown on to the quartz substrate by pulsed laser ablation of erbium oxide stoichiometric target. Optical transmission spectrum has been fitted to Swanepoel formula to determine the dispersion of refractive index and to extract resonance absorption peaks at 980 and 1535 nm. The maximum gain coefficient of 800 dB/cm at 1535 nm was estimated using McCumber theory and experimental spectrum of the resonance absorption. In 5.7 mm-long waveguide amplifier a theory predicts the spectral gain of 20 dB with 1.4 dB peak-to-peak flatness in the bandwidth of 31 nm (1532-1563 nm) when 73% of Er³⁺ ions are excited from the ground state to the ⁴I_13/2 laser level. Strong broadband PL at room temperature and inherently flat spectral gain promise Er₂O₃ films for ultra-short high-gain optical waveguide amplifiers and integrated light circuits.     

Continuous-wave laser oscillation at 1.06 µm in silicon ion-implanted Nd:YVO<Subscript>4</Subscript> planar waveguide

This work, for the first time to our knowledge, reports continuous-wave laser oscillation at 1.06 μm in Nd:YVO₄ planar waveguide formed by 3.0 MeV Si⁺ ion implantation at a dose of 1 × 10¹⁵ ions/cm² at room temperature. The effective refractive indices of the waveguide propagation modes were measured by using a prism-coupling method after the annealing at 240°C for 60 min in air. The performance of the waveguide laser has been studied in terms of the threshold pump power and slope efficiency. The laser outputs show a very high stability operating in cw regime at room temperature.     

UV laser desorption of nitric oxide from semiconducting C<Subscript>60</Subscript>/Cu(111)

The desorption of NO from a well-characterized, epitaxially grown semiconducting C₆₀ surface is reported. Two different channels are identified in the laser desorption. Both channels yield a comparably high desorption cross section of σ₁=7.0×10^-17 cm² and σ₂=5.5×10^-17 cm² for the first and second channel, respectively. The laser desorbed NO molecules are detected with rovibrational state selectivity by (1+1) REMPI in the -bands. In the first channel the desorbing molecules are highly excited with an average kinetic energy of 〈E_kin〉=174 meV. The rotational population distribution can be fitted by a rotational temperature of T_rot=800 K. A rotational–translational coupling is observed, with velocities ranging from 1000 m/s for low to 1300 m/s for high rotational states. The vibrationally excited population is estimated to be less than 1% of the ground state. The second channel yields less excited molecules and an almost Boltzmann distributed rotational population with a temperature of T_rot=280 K. The apparent velocity distribution derived from the pump-probe delay yields molecules much too slow to be explained by even a thermal desorption. This desorption is probably caused by a long-lived electronic excitation in the substrate for which a lifetime of τ≈160 μs is estimated. PACS 42.62.Fi; 34.50.Dy; 68.49.Df; 68.43.Tj; 79.20.La     

Molecular motion in supercooled glycerol

Quasi-elastic Rayleigh scattering of 14·4 keV photons has been measured on supercooled liquid glycerol at -30°C and 0°C by employing the Mössbauer effect. Total scattered intensity, quasi-elastically scattered intensity I _q and energy width of I _q(k, ω) have been determined for k=0·6 to 4·2 Å^-1. The molecular motion is modelled as: random-walk diffusional motions for the centre-of-mass translation and for the orientation of independent rigid molecules, plus fast-bounded translational jitter (vibration). The model parameters are evaluated. The temperature dependence of the translational diffusion constant corresponds to an activation energy of 12 kcal/mol. Comparison is made especially with N.M.R. results for rotational motion. The effect of orientational jitter (libration) is considered and its possible influence on nuclear magnetic relaxation is pointed out.     

Rotational and vibrational temperatures of electronically excited BiN radicals in a chemiluminescent flame

Rotational and vibrational temperatures of electronically excited BiN radicals in a low-pressure Bi_x+N/N₂*/N₂+Ar chemiluminescent flame have been deduced from high-resolution Fourier-transform emission spectra. Bands of three electronic transitions, a³Σ⁺(a₁1)→X¹Σ⁺(X0⁺), b⁵Σ⁺(b₁0⁺)→X¹Σ⁺(X0⁺), and b⁵Σ⁺(b₁0⁺)→a ³Σ⁺(a₁1), were analysed to determine the optical temperatures in the a³Σ⁺(a₁1) and b⁵Σ⁺(b₁0⁺) states. The rotational temperatures characterising the rotational populations in the a₁1, v=0 and 1 states were determined from the a₁→X, 0-2, 0-3, 0-4, 1-1, and 1-2 bands. The b₁→X, 0-8 and 0-11 bands, and the b₁→a₁, 0-0 bands served to determine the rotational temperature of the radicals in the b₁0⁺, v=0 state. The temperatures derived from the various bands and transitions were well consistent and the mean rotational temperature was determined to be 353±18 K, which is close to the translational temperature of the gas.Vibrational temperatures of the radicals in the a₁1 and b₁0⁺ states were derived from band intensities of the a₁→X and from the b₁→X as well as b₁→a₁ systems, respectively. The Franck-Condon factors needed were calculated with RKR potentials deduced from literature values of the rotational and vibrational constants in the three states involved. The a₁1 vibrational temperature (336±21 K) was close to the rotational temperature, while the b₁0⁺ vibrational temperature (438±36 K) differed, likely due to the previously observed perturbation of the b₁0⁺ state.     

A waveguide reactor for IR multiphoton dissociation and its application to13C laser isotope separation

A waveguide reactor for infrared multiphoton dissociation reactions has been presented and applied to laser isotope separation of¹³C. The reactor is a sealed vessel containing a hollow waveguide for a CO₂ laser, and the laser beam is condensed in the waveguide. The waveguide is a pipe of total-reflection glass or metal-coated glass with a funnelled inlet; it is 50 cm long with a 3 mm inner diameter. The isotope separation of¹³C has been made by multiphoton dissociation of CHF₂Cl using a TEA CO₂ laser. The result has shown that the waveguide reactor increases the dissociation yield by four to ten times as much as that without the waveguide at the pulse rate of up to 150 Hz, while the separation factor remains on the same level. It is also found that an optical breakdown which is induced at the wall surface plays a significant role to reduce the isotope selectivity.This work is for a partial fulfilment of B.S. degree of Osaka Electric Communication University     

用于准相位匹配的LD泵浦Nd:YAG946nm连续激光光源

本文为泵浦质子交换准相位匹配波导器LiNbO₃提供了激光光源,用808nm半导体激光器泵浦Nd:YAG晶体,在室温下获得946nm激光连续输出大于120mW,斜率效率9.8%,并且在国内首次实现了LD泵浦Nd:YAG/KNbO₃473nm蓝色激光器的连续运转,报道了初步的实验结果并对此进行了详细的分析,提出了改进方案.     

Well-confined Yb:GdVO4 laser waveguide formed by MeV C ion implantation

The planar waveguide in x-cut Yb:GdVO₄ crystal has been fabricated by 6.0 MeV carbon ion implantation with the fluence of 1 × 10¹⁴ ions/cm² at room temperature. The modes of the waveguide were measured by the prism-coupling method with the wavelength of 633 nm and 1539 nm, respectively. An enhanced ordinary refractive index region was formed with a width of about 4.0 μm beneath the sample surface to act as a waveguide structure. By performing a modal analysis on the observed transverse magnetic polarized modes, it was found that all the transverse magnetic polarized modes can be well-confined inside the waveguide. Strong Yb-related photoluminescence in Yb:GdVO₄ waveguide has been observed at room temperature, which reveals that it exhibits possible applications for integrated active photonic devices.     

A new efficient far-infrared optically pumped laser gas: CH3 18OH

The¹²CH₃ ¹⁸OH molecule has been investigated for new far-infrared laser lines by optically pumping it with a cw waveguide CO₂ laser. The larger tunability (318 MHz) with respect to a conventional CO₂ laser permits the pumping of many¹²CH₃ ¹⁸OH lines. As a consequence 100 new laser lines have been discovered, ranging from 34.6 m to 653.2 m in wavelength. The infrared spectrum of¹²CH₃ ¹⁸OH has been observed and all the fundamental vibration energies measured.     

The H2S Spectrum around 0.7 μm

The overtone spectrum of H₂S has been recorded by intracavity laser spectroscopy in the 14100–14400 cm⁻¹spectral region. The rovibrational analysis was performed allowing one to assign not only lines involving the pair of interacting states {(402), (303)} ({(60⁺, 0), (60⁻, 0)} in local mode notation), but also lines involving the interacting states {(322), (223)} ({50⁺, 2), (50⁻, 2)} in local mode notation). Indeed, apart from the strong H₂₂interactions that link the rotational levels of the states (60^±, 0) on the one hand, and the rotational levels of the states (50⁺, 2) on the other hand, we observe that the rotational levels of the two pairs of states interact strongly through anharmonic and Coriolis-type resonances. These resonances transfer intensity to lines involving the (50⁺, 2) pair of states. Altogether 80 rotational upper-state levels have been observed and reproduced satisfactorily using an Hamiltonian matrix that takes explicitly into account the various interactions and assumes the same vibrational energy and rotational constants for the two components of the local mode pairs. The following band centers have been obtained: ν₀(60⁺, 0) = 14291.122 cm⁻¹and ν₀(50^±, 2) = 14284.705 cm⁻¹. Finally a local mode-type behavior is evidenced by the values of the Hamiltonian constants, and refined vibrational local mode parameters are obtained.     

Pressure broadening by argon in the hyperfine resolved P(10) and P(70) (17,1) transitions of I2 XΣ(0g)→BΠ(0u) using sub-Doppler laser saturation spectroscopy

The dependence of pressure broadening upon hyperfine component in the P(10) and P(70) lines of the (17,1) band of the I₂ X¹Σ(0_g⁺)→B³Π(0_u⁺) has been studied using laser saturation spectroscopy. By limiting absorption to the zero velocity group, Doppler broadening is removed, lineshapes with widths (FWHM) <9 MHz are detectable, and collision-induced broadening is measured at pressures of 0.2-1.2 Torr. The rates for broadening by argon are 8.3±0.3 and 10.7±0.4 MHz/Torr for the P(70) and P(10) lines, respectively. No significant variation in broadening rates is observed for the 15 hyperfine components of these even rotational lines. The effects of velocity cross-relaxation introduce a broad baseline into the spectra, which is strongly dependent on rotational state, pressure, and laser modulation frequency. The observed broadening rates correlate well with prior measurements and the polarizability of the collision partner.     

Laser operation of the new stoichiometric crystal KYb(WO4)2

We demonstrate for the first time laser operation with the monoclinic stoichiometric crystal KYb(WO₄)₂ (hereafter KYbW). Lasing on the ² F _5/2 ?² F _7/2 transition of Yb³⁺ at room temperature has been achieved near 1074 nm with >41% slope efficiency (>26% maximum conversion efficiency) using a 0.5-mm-thick plate of KYbW. This new laser material holds great promise for diode-pumped high-power lasers, thin-disk and waveguide designs as well as for ultrashort (ps/fs) pulse laser systems. Received: 10 October 2001 / Revised version: 19 November 2001 / Published online: 17 January 2002     

The absorption of ethylene in the 10-μm region

The ν₇, ν₁₀, and ν₄ interacting band system has been studied from three complementary sources: classical, diode laser, and waveguide laser spectra. In addition to the two first-order Coriolis interaction terms associated with ζ_7.10^a and ζ_4.10^b, we were obliged to introduce the corresponding second-order terms to obtain a statistical agreement between calculated and experimental data. High-quality vibrational and rotational data are presented for the two infrared active fundamentals, ν₇ and ν₁₀, and the rotational constants for the inactive ν₄ fundamental are determined for the first time. We also present the list of all the infrared transitions starting from the vibrational ground state of ethylene and being in quasi coincidence with CO₂ or N₂O laser lines.     

Low cost fabrication of SiO2 optical waveguides by laser direct writing on Ti-doped Sol-Gel films

A commercial direct laser writing (DLW) system operating at 1070 nm was used to fabricate SiO₂ optical waveguides on silicon wafers. A Ti-doped SiO₂ Sol-Gel film was deposited on the SiO₂/Si substrate by the dip-coating technique, based on which SiO₂ optical waveguides were patterned by DLW using a Ytterbium fiber laser and followed by chemical etching. The effects of laser parameters and the preheated temperature of Sol-Gel films on the dimensions of optical waveguides were studied systematically. The differences of etching rate between laser irradiated and non-irradiated areas in Sol-Gel films preheated at various temperatures are characterized by measuring the thickness of the films. Results demonstrate that the available laser power density range for laser densification and the width of the patterned optical waveguides are influenced strongly by the preheated temperature of the Sol-Gel films. The width of the optimized optical waveguide in this work is 25 μm. The minimum propagation loss of the fabricated optical waveguides is 1.7 dB cm⁻¹ at the wavelength of 1550 nm.     

Intracavity laser absorption spectroscopy of AuO: Identification of the bΠ3/2-XΠ3/2 transition

The visible electronic spectrum of AuO has been recorded at rotational resolution using intracavity laser absorption spectroscopy. Five vibrational bands have been analyzed and assigned as the (0, 0), (1, 0), (2, 0), (3, 0), and (4, 0) bands of the b⁴Π_3/2-X²Π_3/2 transition of AuO. The molecular parameters for the newly identified b⁴Π_3/2 state are presented.     

Laser-induced Alignment and Coulomb Explosion of CO2

实验研究了CO₂分子在飞秒强激光脉冲作用下的动力学过程,包括分子取向,隧穿电离和库仑爆炸,激光强度从1×10¹³W/cm²变化到6×10¹⁴W/cm². 当激光强度小于分子的电离阈值时,CO₂分子的非绝热转动激发形成一个相干转动波包,波包演化导致分子沿激光电场方向取向. 激光脉冲结束后,分子取向可以周期性地再现,利用另一束激光可以对取向结构进一步进行修饰. 当激光强度大于分子     

Efficient blue upconversion emission due to confined radiative energy transfer in Tm-Nd co-doped Ta2O5 waveguides under infrared-laser excitation

Intense blue upconversion emission at 480 nm has been obtained at room temperature in Tm³⁺-Nd³⁺ co-doped Ta₂O₅ channel waveguides fabricated on a Si substrate, when the sample is excited with an infrared laser at 793 nm. The upconversion mechanism is based on the radiative relaxation of the Nd³⁺ ions (⁴F_3/2 → ⁴I_11/2) at about 1064 nm followed by the absorption of the emitted photons by Tm³⁺ ions in the ³H₄ excited state. A coefficient of energy transfer rate as high as 3 × 10⁻¹⁶ cm³/s has been deduced using a rate equation analysis, which is the highest reported for Tm-Nd co-doped systems. The confinement of the 1064 nm emitted radiation in the waveguide structure is the main reason of the high energy transfer probability between Nd³⁺ and Tm³⁺ ions.     

Two Dimensional Rotational Temperature Measurement by Multiline Laser Induced Fluorescence of Nitric Oxide in Combustion Flame

Two-dimensional rotational temperature measurement was performed in a stable combustion flame of premixed butane and oxygen using multiline laser induced fluorescence (LIF) of nitric oxide molecules. Multiple rotational absorption lines of A²∑⁺Π;X²II(0,0) Q₁ and Q₂ lines were excited by laser light around 226 nm, and the LIF signal was observed by an image-intensified digital camera. Temperature was determined through least squares fitting correlation between LIF intensity and excitation rotational quantum number for the Boltzmann distribution function. The measured LIF intensity was approximated by the Boltzmann distribution with good accuracy, and the temperature obtained was between 500 K and 1800 K for the test flame. The measuring error of the temperature was evaluated and found to be 80 K, which corresponded to 8% of the measured fluorescence intensity. The two-line LIF scheme was evaluated by different pairs of excitation lines (Q₁(31.5)/Q₁(16.5) and Q₁(18.5)/Q₁(16.5)) for comparison with the multiline LIF approach. Temperature which was obtained by two-line LIF scheme corresponded well with multiline LIF results for Q₁(31.5)/Q₁(16.5) excitation. However, for Q₁(18.5)/Q₁(16.5) excitation, the obtained temperature did not agree with the multiline LIF result because the population of rotational states J=18.5 and J=16.5 is similar at high temperatures. We found that two-line LIF temperature measurement was reliable when excitation lines were suitably selected.