Intracavity laser absorption spectroscopy of AuO: Identification of the bΠ3/2-XΠ3/2 transition |
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Authors: | Sadasivan Shaji James J O’Brien Leah C O’Brien |
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Institution: | a Department of Chemistry and Biochemistry and the Center for Molecular Electronics, University of Missouri—St. Louis, St. Louis, MO 63121, USA b Department of Chemistry, Southern Illinois University Edwardsville, Edwardsville, IL 62026-1652, USA |
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Abstract: | The visible electronic spectrum of AuO has been recorded at rotational resolution using intracavity laser absorption spectroscopy. Five vibrational bands have been analyzed and assigned as the (0, 0), (1, 0), (2, 0), (3, 0), and (4, 0) bands of the b4Π3/2-X2Π3/2 transition of AuO. The molecular parameters for the newly identified b4Π3/2 state are presented. |
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Keywords: | Gold oxide Electronic spectroscopy Intracavity laser absorption spectroscopy ILS |
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