Determination of traces of elements in solutions by the method of flame atomic-ionization spectroscopy

Multistage effective excitation circuits for a sodium atom in a propane-butane-air flame are studied experimentally. Consideration is given to the effectiveness of the excitation and ionization of an Au atom following the collision scheme

Krein formula with compensated singularities for the ND-mapping and the generalized Kirchhoff condition at the Neumann Schrödinger junction

The Neumann Schrödinger operator \(\mathcal{L}\) is considered on a thin 2D star-shaped junction, composed of a vertex domain Ω_int and a few semi-infinite straight leads ω _m , m = 1, 2, ..., M, of width δ, δ ? diam Ω_int, attached to Ω_int at Γ ? ?Ω_int. The potential of the Schrödinger operator l ^ω on the leads vanishes, hence there are only a finite number of eigenvalues of the Neumann Schrödinger operator L _int on Ω_int embedded into the open spectral branches of l ^ω with oscillating solutions χ _±(x, p) = \(e^{ \pm iK_ + x} e_m \) of l ^ω χ _± = p ² χ _±. The exponent of the open channels in the wires is

$K_ + (\lambda ) = p\sum\limits_{m = 1}^M {e^m } \rangle \langle e^m = \sqrt \lambda P_ + $

, with constant e _m , on a relatively small essential spectral interval Δ ? [0, π ² δ ^?2). The scattering matrix of the junction is represented on Δ in terms of the ND mapping

$\mathcal{N} = \frac{{\partial P_ + \Psi }}{{\partial x}}(0,\lambda )\left| {_\Gamma \to P_ + \Psi _ + (0,\lambda )} \right|_\Gamma $

as

$S(\lambda ) = (ip\mathcal{N} + I_ + )^{ - 1} (ip\mathcal{N} - I_ + ), I_ + = \sum\limits_{m = 1}^M {e^m } \rangle \langle e^m = P_ + $

. We derive an approximate formula for \(\mathcal{N}\) in terms of the Neumann-to-Dirichlet mapping \(\mathcal{N}_{\operatorname{int} } \) of L _int and the exponent K _? of the closed channels of l ^ω . If there is only one simple eigenvalue λ ₀ ∈ Δ, L _intφ0 = λ _0φ0 then, for a thin junction, \(\mathcal{N} \approx |\vec \phi _0 |^2 P_0 (\lambda _0 - \lambda )^{ - 1} \) with

$\vec \phi _0 = P_ + \phi _0 = (\delta ^{ - 1} \int_{\Gamma _1 } {\phi _0 (\gamma )} d\gamma ,\delta ^{ - 1} \int_{\Gamma _2 } {\phi _0 (\gamma )} d\gamma , \ldots \delta ^{ - 1} \int_{\Gamma _M } {\phi _0 (\gamma )} d\gamma )$

and \(P_0 = \vec \phi _0 \rangle |\vec \phi _0 |^{ - 2} \langle \vec \phi _0 \),

$S(\lambda ) \approx \frac{{ip|\vec \phi _0 |^2 P_0 (\lambda _0 - \lambda )^{ - 1} - I_ + }}{{ip|\vec \phi _0 |^2 P_0 (\lambda _0 - \lambda )^{ - 1} + I_ + }} = :S_{appr} (\lambda )$

. The related boundary condition for the components P ₊Ψ(0) and P ₊Ψ′(0) of the scattering Ansatz in the open channel \(P_ + \Psi (0) = (\bar \Psi _1 ,\bar \Psi _2 , \ldots ,\bar \Psi _M ), P_ + \Psi '(0) = (\bar \Psi '_1 , \bar \Psi '_2 , \ldots , \bar \Psi '_M )\) includes the weighted continuity (1) of the scattering Ansatz Ψ at the vertex and the weighted balance of the currents (2), where

$\frac{{\bar \Psi _m }}{{\bar \phi _0^m }} = \frac{{\delta \sum\nolimits_{t = 1}^M { \bar \Psi _t \bar \phi _0^t } }}{{|\vec \phi _0 |^2 }} = \frac{{\bar \Psi _r }}{{\bar \phi _0^r }} = :\bar \Psi (0)/\bar \phi (0), 1 \leqslant m,r \leqslant M$

(1)

,

$\sum\limits_{m = 1}^M {\bar \Psi '_m } \bar \phi _0^m + \delta ^{ - 1} (\lambda - \lambda _0 )\bar \Psi /\bar \phi (0) = 0$

(1)

. Conditions (1) and (2) constitute the generalized Kirchhoff boundary condition at the vertex for the Schrödinger operator on a thin junction and remain valid for the corresponding 1D model. We compare this with the previous result by Kuchment and Zeng obtained by the variational technique for the Neumann Laplacian on a shrinking quantum network.

     

Optical double resonance and zero field level crossing spectroscopy applied to the 5p 3 6s 5 S 2 level in the Te-I spectrum

As a first application of optical double resonance and zero field level crossing spectroscopy to the elements of the sixth group in the periodic table of the atoms, the 5p ³6s ⁵ S ₂ level in the Te-I spectrum was investigated using natural tellurium in a high temperature quartz cell. For the electronic Landé-factor and the natural radiative lifetime the following values were obtained: $$g_J \left( {5p^3 6s^5 S_2 } \right) = - 1.9657\left( {12} \right),\tau \left( {5p^3 6s^5 S_2 } \right) = 71.8\left( {2.2} \right)ns.$$      

An expansion of Hartree-Fock and correlation energies,relativistic corrections and the dipole matrix element in the powers of of 1/Z

Feynman diagrammatic technique was used for the calculation of Hartree-Fock and correlation energies, relativistic corrections, dipole matrix element. The whole energy of atomic system was defined as a polen-electron Green function. Breit operator was used for the calculation of relativistic corrections. The Feynman diagrammatic technique was developed for 〈H_B>. Analytical expressions for the contributions from diagrams were received. The calculations were carried out for the terms of such configurations as 1s² 2sⁿ¹ 2pⁿ² (2 ≧n₁≧ 0, 6≧ n₂ ≧ 0). Numerical results are presented for the energies of the terms in the form $$E = E_0 Z^2 + \Delta {\rm E}_2 + \frac{1}{Z}\Delta {\rm E}_3 + \frac{{\alpha ^2 }}{4}(E_0^r + \Delta {\rm E}_1^r Z^3 )$$ and for fine structure of the terms in the form $$\begin{gathered} \left\langle {1s^2 2s^{n_1 } 2p^{n_2 } LSJ|H_B |1s^2 2s^{n_1 \prime } 2p^{n_2 \prime } L\prime S\prime J} \right\rangle = \hfill \\ = ( - 1)^{\alpha + S\prime + J} \left\{ {\begin{array}{*{20}c} {L S J} \\ {S\prime L\prime 1} \\ \end{array} } \right\}\frac{{\alpha ^2 }}{4}(Z - A)^3 [E^{(0)} (Z - B) + \varepsilon _{co} ] + \hfill \\ + ( - 1)^{L + S\prime + J} \left\{ {\begin{array}{*{20}c} {L S J} \\ {S\prime L\prime 2} \\ \end{array} } \right\}\frac{{\alpha ^2 }}{4}(Z - A)^3 \varepsilon _{cc} . \hfill \\ \end{gathered} $$ Dipole matrix elements are necessary for calculations of oscillator strengths and transition probabilities. For dipole matrix elements two members of expansion by 1/Z have been obtained. Numerical results were presented in the form P(a,a′) = a/Z(1+τ/Z).     

A study of isotopically selective photoionization of ytterbium atoms for laser isotope separation

Atomic-vapor laser isotope separation (AVLIS) is studied experimentally and theoretically for ytterbium vapors. The optimum ionization scheme and the process dynamics are determined. The photoionization scheme uses the transitions $$6^1 S_0 \mathop \to \limits^{555.648nm} 6^3 P_1 \mathop \to \limits^{581.067nm} (7/2,3/2)_2 \mathop \to \limits^{582.79nm} (52353cm^{ - 1} ).$$ For a numerical study of photoionization dynamics, the mathematical model of the AVLIS process is used, which is based on the density matrix formalism and Maxwell's equations. Selective photoionization of the¹⁶⁸Yb isotope is simulated numerically. The yield and selectivity of the process are determined. It is shown that the length of the photoionization region is limited because the laser radiation is absorbed by atoms of¹⁷¹Yb and¹⁷³Yb isotopes. The advantage of the laser method over the method using an electromagnetic separator is demonstrated.     

Parity-violating neutron spin rotation in hydrogen and deuterium

We calculate the (parity-violating) spin-rotation angle of a polarized neutron beam through hydrogen and deuterium targets, using pionless effective field theory up to next-to-leading order. Our result is part of a program to obtain the five leading independent low-energy parameters that characterize hadronic parity violation from few-body observables in one systematic and consistent framework. The two spin-rotation angles provide independent constraints on these parameters. Our result for np spin rotation is $\frac{1} {\rho }\frac{{d\varphi _{PV}^{np} }} {{dl}} = \left[ {4.5 \pm 0.5} \right] rad MeV^{ - \frac{1} {2}} \left( {2g^{\left( {^3 S_1 - ^3 P_1 } \right)} + g^{\left( {^3 S_1 - ^3 P_1 } \right)} } \right) - \left[ {18.5 \pm 1.9} \right] rad MeV^{ - \frac{1} {2}} \left( {g_{\left( {\Delta {\rm I} = 0} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} - 2g_{\left( {\Delta {\rm I} = 2} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} } \right)$\frac{1} {\rho }\frac{{d\varphi _{PV}^{np} }} {{dl}} = \left[ {4.5 \pm 0.5} \right] rad MeV^{ - \frac{1} {2}} \left( {2g^{\left( {^3 S_1 - ^3 P_1 } \right)} + g^{\left( {^3 S_1 - ^3 P_1 } \right)} } \right) - \left[ {18.5 \pm 1.9} \right] rad MeV^{ - \frac{1} {2}} \left( {g_{\left( {\Delta {\rm I} = 0} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} - 2g_{\left( {\Delta {\rm I} = 2} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} } \right), while for nd spin rotation we obtain $\frac{1} {\rho }\frac{{d\varphi _{PV}^{nd} }} {{dl}} = \left[ {8.0 \pm 0.8} \right] rad MeV^{ - \frac{1} {2}} g^{\left( {^3 S_1 - ^1 P_1 } \right)} + \left[ {17.0 \pm 1.7} \right] rad MeV^{ - \frac{1} {2}} g^{\left( {^3 S_1 - ^3 P_1 } \right)} + \left[ {2.3 \pm 0.5} \right] rad MeV^{ - \frac{1} {2}} \left( {3g_{\left( {\Delta {\rm I} = 0} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} - 2g_{\left( {\Delta {\rm I} = 1} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} } \right)$\frac{1} {\rho }\frac{{d\varphi _{PV}^{nd} }} {{dl}} = \left[ {8.0 \pm 0.8} \right] rad MeV^{ - \frac{1} {2}} g^{\left( {^3 S_1 - ^1 P_1 } \right)} + \left[ {17.0 \pm 1.7} \right] rad MeV^{ - \frac{1} {2}} g^{\left( {^3 S_1 - ^3 P_1 } \right)} + \left[ {2.3 \pm 0.5} \right] rad MeV^{ - \frac{1} {2}} \left( {3g_{\left( {\Delta {\rm I} = 0} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} - 2g_{\left( {\Delta {\rm I} = 1} \right)}^{\left( {^1 S_0 - ^3 P_0 } \right)} } \right), where the g ^(X-Y), in units of $MeV^{ - \frac{3} {2}}$MeV^{ - \frac{3} {2}}, are the presently unknown parameters in the leading-order parity-violating Lagrangian. Using naıve dimensional analysis to estimate the typical size of the couplings, we expect the signal for standard target densities to be $\left| {\frac{{d\varphi _{PV} }} {{dl}}} \right| \approx \left[ {10^{ - 7} \ldots 10^{ - 6} } \right]\frac{{rad}} {m}$\left| {\frac{{d\varphi _{PV} }} {{dl}}} \right| \approx \left[ {10^{ - 7} \ldots 10^{ - 6} } \right]\frac{{rad}} {m} for both hydrogen and deuterium targets. We find no indication that the nd observable is enhanced compared to the np one. All results are properly renormalized. An estimate of the numerical and systematic uncertainties of our calculations indicates excellent convergence. An appendix contains the relevant partial-wave projectors of the three-nucleon system.     

Domain and Range of the Modified Wave Operator for Schrödinger Equations with a Critical Nonlinearity

We study the final problem for the nonlinear Schrödinger equation

$i{\partial }_{t}u+\frac{1}{2}\Delta u=\lambda|u|^{\frac{2}{n}}u,\quad (t,x)\in {\mathbf{R}}\times \mathbf{R}^{n},$

where\(\lambda \in{\bf R},n=1,2,3\). If the final data\(u_{+}\in {\bf H}^{0,\alpha }=\left\{ \phi \in {\bf L}^{2}:\left( 1+\left\vert x\right\vert \right) ^{\alpha }\phi \in {\bf L}^{2}\right\} \) with\(\frac{ n}{2} < \alpha < \min \left( n,2,1+\frac{2}{n}\right) \) and the norm\(\Vert \widehat{u_{+}}\Vert _{{\bf L}^{\infty }}\) is sufficiently small, then we prove the existence of the wave operator in L ². We also construct the modified scattering operator from H ^0,α to H ^0,δ with\(\frac{n}{2} < \delta < \alpha\).

     

Collisional damping of transverse waves in a plasma

The effect of collisions on transverse waves in a homogeneous, field free plasma is investigated by means of Gross-Krook collision model. The dispersion relation is calculated by assuming the collision frequency to be small andKλ _D ?1. The damping rate ω _I is obtained as $$\omega _I = \frac{{\nu _{ei} }}{2}\frac{{\omega _p^2 }}{{\omega _0^2 }}\left[ {1 + \frac{{3K^2 \lambda _D^2 \omega _p^2 }}{{\omega _0^2 }} - \frac{{K^2 \lambda _D^2 \omega _p^4 }}{{\omega _0^4 }}} \right] + \frac{{\nu _{ee} }}{2}\frac{{\omega _p^2 }}{{\omega _0^2 }}\left( {\frac{{K^2 \lambda _D^2 \omega _p^2 }}{{\omega _0^2 }}} \right)$$ where ω ₀ ² =c ² K ²+ω ₂ ^p , andv _ei andv _ee are electron-ion and electron-electron collision frequency respectively.     

Problèmes mathématiques de l'équation de Boltzmann relativiste

This work deals with relativistic Boltzmann equation and more particulary with integral operator of complete equation and integral operator of linearized equation. These operators depend on the differential cross sectionh(〈p, q〉, cos θ) which is a fonction of energy 〈p, q〉 and of the deviation angle θ. The only hypothesis is thath is a symetric function of cosθ. The second part deals essentially with linearized equation in Special Relativity. We take for the distribution function: $$F\left( {x,p} \right) = a e^{ - \frac{{\lambda p}}{2}} \left( {e^{ - \frac{{\lambda p}}{2}} + \varepsilon f\left( {x,p} \right)} \right)$$ wherea is a constant, λ a constant vector and ? a small constant so that ?² can be neglected. We obtain the equation: $$\frac{{p^\alpha }}{{p^0 }}\frac{{\partial f}}{{\partial x^\alpha }} = - K\left( p \right) \cdot f + G\left( f \right)$$ whereK(p) is a positive function andG an Hilbert-Schmidt operator. Then we resolve the Cauchy's problem by taking the Fourier's transformation off, and in the last part by investigating properties of the resolvent of ?K+G we establish that asx ⁰→+∞ the solution of this problem has for limit the equilibrium distributiona e ^?λp .     

Hierarchy of Poisson brackets for elements of a scattering matrix

The infinite family of Poisson brackets between the elements of a scattering matrix is calculated for the linear matrix spectral problem.     

Weakly Non-Ergodic Statistical Physics

For weakly non ergodic systems, the probability density function of a time average observable is where is the value of the observable when the system is in state j=1,…L. p _j ^eq is the probability that a member of an ensemble of systems occupies state j in equilibrium. For a particle undergoing a fractional diffusion process in a binding force field, with thermal detailed balance conditions, p _j ^eq is Boltzmann’s canonical probability. Within the unbiased sub-diffusive continuous time random walk model, the exponent 0<α<1 is the anomalous diffusion exponent 〈x ²〉∼t ^α found for free boundary conditions. When α→1 ergodic statistical mechanics is recovered . We briefly discuss possible physical applications in single particle experiments.     

Interaction of sodium fullerene derivatives with trimethylchlorosilane

Soluble dimer compounds of the general formula [C₆₀(Me ₃Si)_n]₂ (where n = 3, 5, 7, or 9 and M _e = CH₃) and a soluble monomer compound, C₆₀(Me ₃Si)₁₂, are synthesized by the reaction of the compound C₆₀Na_n(THF)_x (where n = 4, 6, 8, 10, or 12 and THF = tetrahydrofuran) with trimethylchlorosilane Me ₃SiCl. The compounds synthesized are identified using IR and NMR spectroscopy and mass spectrometry. An irreversible endothermic effect exhibited by the [C₆₀(Me ₃Si)₇]₂ compound in the temperature range 448–570 K is revealed by dynamic adiabatic calorimetry. From analyzing the experimental results, it becomes possible for the first time to demonstrate the structural flexibility of the fullerene in the following sequence of reactions: $\begin{array}{*{20}c} {C_{60} \xrightarrow[{ - 12C_{10} H_8 }]{{ + 12NaC_{10} H_8 }}C_{60} Na_{12} \xrightarrow[{ - 12NaCl}]{{ + excess Me_3 SiCl}}C_{60} (Me_3 Si)_{12} \xrightarrow[{ - 12Me_3 SiCl}]{{ + HCl(gas)}}[C_{60} H_n ]\xrightarrow[{ - 1/2nH_2 }]{{hv}}C_{60} } \\ {C_{60} \xrightarrow[{ - 8C_{10} H_8 }]{{ + 8NaC_{10} H_8 }}C_{60} Na_8 \xrightarrow[{ - 8NaCl}]{{ + excess Me_3 SiCl}}[C_{60} (Me_3 Si)_7 ]_2 \xrightarrow{{573K}}\begin{array}{*{20}c} {products of the} \\ {transformation of + } \\ {Me_3 Si groups} \\ \end{array} C_{60^ - } } \\ \end{array} $      

Laser-diode-excited Blue Upconversion in Tm3+/Yb3+-codoped TeO2-Ga2O3-R2O (R=Li, Na, K) Glasses

This paper reports on intense blue upconversion in Tm³⁺/Yb³⁺ codoped TeO₂-Ga₂O₃-R₂O(R=Li, Na, K) glasses upon excitation with commercial available laser diode (LD). Effects of alkali ions on the Raman spectra, thermal stability and spectroscopic properties of the tellurite-gallium glasses have also been investigated. Energy transfer and the involved upconversion mechanisms have been discussed. Intense blue upconversion emission centered at 476 nm along with a weak red emission at 650 nm has been observed upon excitation of 977 nm LD, assigned to the transitions of , and and/or of Tm³⁺, respectively. The blue upconversion intensity has a cubelike dependence on incident pump laser power, indicating a three-photon process. However, a quadratic dependence of the 476 nm upconversion intensity on the incident pump laser power has been observed when samples under excitation of 808 nm LD due to a two-photon absorption process. Enhanced upconversion luminescence have been observed with replacing K⁺ for Na⁺ and Li⁺.     

Prospects of technicolor-signatures in hadronic collisions

Within the context of the Dimopoulos' one family model, we consider possible technicolor signatures in hadronic reactions at high energies. For the single-production of light color-singlet states (P ⁰,P ³,P ^±) in \(p\bar p\) annihilation, we find the Compton-scattering processgc→P ⁰ c most promising. In case of PGB-pair-production, the reaction in \(p\bar p \to P^ + P^ - \) via the subprocess \(q\bar q\xrightarrow{{\gamma ,Z^0 }}P^ + P^ - \) , as well as the production of heavy color-triplets (P ₃) via \(p\bar p \to P_3 \bar P_3 \) via \(q\bar q\) andgg-fusion at Tevatron-energies, appear to be best suited for detecting these objects.     

A measurement of the branching ratio∑ +→pγ/∑ +→pπ 0⋆

In an experiment performed in the CERN SPS hyperon beam we have obtained a value for the branching ratio $${{\Sigma ^ + \to p\gamma } \mathord{\left/ {\vphantom {{\Sigma ^ + \to p\gamma } {\Sigma ^ + \to p\pi }}} \right. \kern-\nulldelimiterspace} {\Sigma ^ + \to p\pi }}^0 of\left( {2.46_{ - 0.35}^{ + 0.30} } \right) \times 10^{ - 3} ,$$ corresponding to a branching ratio $${{\Sigma ^ + \to p\gamma } \mathord{\left/ {\vphantom {{\Sigma ^ + \to p\gamma } {\Sigma ^ + \to all}}} \right. \kern-\nulldelimiterspace} {\Sigma ^ + \to all}}of\left( {1.27_{ - 0.18}^{ + 0.16} } \right) \times 10^{ - 3} .$$ This result is discussed in the context of present understanding of hyperon radiative decays.     

Hyperfine structure and isotope shift study in singly ionized lead

Hyperfine structure and isotope shifts in five optical transitions: 424.5 nm ( – ), 537.2 nm ( – ), 554.5 nm ( – ), 560.9 nm ( – ) and 666.0 nm ( – ) of Pb  II have been measured. As a light source the discharge tube was used. The hyperfine structure measurements were performed using metallic isotope ²⁰⁷Pb. For isotope shifts measurements natural lead was used. The high resolution spectral apparatus consisted of a silver coated Fabry-Perot etalon and a grating spectrograph combined with a CCD camera used as a detector. In the analysis of the spectra a computer simulation technique was used. The hyperfine structure observations yielded the splitting constants A for seven levels of Pb II. The isotope shift studies enabled to separate the mass and the field shifts and to determine values of changes of the mean square nuclear charge radii.     

Noncommutative products of Euclidean spaces

We present natural families of coordinate algebras on noncommutative products of Euclidean spaces \({\mathbb {R}}^{N_1} \times _{\mathcal {R}} {\mathbb {R}}^{N_2}\). These coordinate algebras are quadratic ones associated with an \(\mathcal {R}\)-matrix which is involutive and satisfies the Yang–Baxter equations. As a consequence, they enjoy a list of nice properties, being regular of finite global dimension. Notably, we have eight-dimensional noncommutative euclidean spaces \({\mathbb {R}}^{4} \times _{\mathcal {R}} {\mathbb {R}}^{4}\). Among these, particularly well behaved ones have deformation parameter \(\mathbf{u} \in {\mathbb {S}}^2\). Quotients include seven spheres \({\mathbb {S}}^{7}_\mathbf{u}\) as well as noncommutative quaternionic tori \({\mathbb {T}}^{{\mathbb {H}}}_\mathbf{u} = {\mathbb {S}}^3 \times _\mathbf{u} {\mathbb {S}}^3\). There is invariance for an action of \({{\mathrm{SU}}}(2) \times {{\mathrm{SU}}}(2)\) on the torus \({\mathbb {T}}^{{\mathbb {H}}}_\mathbf{u}\) in parallel with the action of \(\mathrm{U}(1) \times \mathrm{U}(1)\) on a ‘complex’ noncommutative torus \({\mathbb {T}}^2_\theta \) which allows one to construct quaternionic toric noncommutative manifolds. Additional classes of solutions are disjoint from the classical case.     

On Blow-up Profile of Ground States of Boson Stars with External Potential

We study minimizers of the pseudo-relativistic Hartree functional \({\mathcal {E}}_{a}(u):=\Vert (-\varDelta +m^{2})^{1/4}u\Vert _{L^{2}}^{2}+\int _{{\mathbb {R}}^{3}}V(x)|u(x)|^{2}\mathrm{d}x-\frac{a}{2}\int _{{\mathbb {R}}^{3}}(\left| \cdot \right| ^{-1}\star |u|^{2})(x)|u(x)|^{2}\mathrm{d}x\) under the mass constraint \(\int _{{\mathbb {R}}^3}|u(x)|^2\mathrm{d}x=1\). Here \(m>0\) is the mass of particles and \(V\ge 0\) is an external potential. We prove that minimizers exist if and only if a satisfies \(0\le a<a^{*}\), and there is no minimizer if \(a\ge a^*\), where \(a^*\) is called the Chandrasekhar limit. When a approaches \(a^*\) from below, the blow-up behavior of minimizers is derived under some general external potentials V. Here we consider three cases of V: trapping potential, i.e. \(V\in L_{\mathrm{loc}}^{\infty }({\mathbb {R}}^3)\) satisfies \(\lim _{|x|\rightarrow \infty }V(x)=\infty \); periodic potential, i.e. \(V\in C({\mathbb {R}}^3)\) satisfies \(V(x+z)=V(x)\) for all \(z\in \mathbb {Z}^3\); and ring-shaped potential, e.g. \( V(x)=||x|-1|^p\) for some \(p>0\).     

Weak and electromagnetic corrections to sin2 θ w in deep inelastic neutrino-nucleon scattering

The weak and electromagnetic corrections to deep inelastic neutrino scattering experiments are calculated. The results are used to determineθ _w from the ratios $$R_v = \frac{{\sigma _{nc} }}{{\sigma _{cc} }} and D_ - = \frac{{\sigma _{nc} - \bar \sigma _{nc} }}{{\sigma _{cc} - \bar \sigma _{nc} }}$$ It is found that the effect of the weak corrections is less than 1% and that electromagnetic corrections decrease the angle by about 3%.     

Theoretical study of collision and collision-free radiative lifetimes of {{\text{S}}_2}\left( {{{\text{B}}^3}\Sigma_{\text{u}}^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right)

We calculate multireference configuration-interaction wavefunctions and the potential-energy curves for the $ {B^3}\Sigma_u^{-} $ and $ {X^3}\Sigma_g^{-} $ states of the collision-free S₂ molecule and the T-shape collision complex S₂?CHe using cc-pVQZ basis sets. We obtain the transition dipole moments of the $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \to {X^3}\Sigma_g^{-} } \right) $ and the Franck?CCondon factors between the vibrational levels of this two states. We evaluate the radiative lifetimes of $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right) $ levels of the collision complex and the collision-free molecule and compare them with the experiments. The collision provides little change in the radiative lifetimes of $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right) $ according to the previous calculations. We obtain excellent agreement between the theoretical results and the experiments. The data calculated are very useful in the study of the microwave-driven high-pressure sulfur lamp and an S₂ laser pumped by a transverse fast discharge.