Long-path measurements of ultrasonic attenuation and velocity for very dilute slurries and liquids and detection of contaminates

The objective was to use multiple paths through the slurry to determine the lowest concentration that provided accurate attenuation measurements and to measure the velocity of sound through an effective long path. Ultrasonic attenuation measurements were obtained for slurries of silica (10 microm diameter) in water for concentrations of 0.1%, 0.25%, 0.5%, 0.75% and 1% silica by weight. Attenuation measurements for concentrations less than 0.1% may prove useful for process control to detect contaminants. A long path is obtained due to multiple reflections occurring within the stainless steel (SS) vessel used; broad-band transducers are affixed on the outside of the thick-walled vessel. The signal in the receive transducer permits the measurement of the attenuation and also the velocity by measuring the time-of-flight. The FFT of the appropriate signal for each echo was obtained and compared with that for water to yield the attenuation as a function of frequency. The attenuation measurements are self-calibrating because they are not affected by changes in the pulser voltage. The data show the feasibility for measuring a concentration of 0.025 wt% silica, which is equivalent to 0.25 g of silica in 1 l of water. Therefore, such measurements can prove useful for detecting contaminants in liquid. The velocity of sound measurements for solutions of hydrogen peroxide in water were obtained and accurate to about 0.3m/s, or 0.02% uncertainty.     

Using ultrasonic attenuation to monitor slurry mixing in real time

Staff at Pacific Northwest National Laboratory have developed and applied a simple ultrasonic attenuation measurement to measure slurry concentration in real time during suspension of solids settled in a large tank. This paper presents a simple single frequency ultrasonic measurement technique that demonstrates the ability of ultrasonic sensors to measure slurry concentration. Sensor calibration data show that in this attenuation regime ultrasonic signal attenuation is proportional to the applied frequency and to the slurry volume fraction. Real-time measurements of ultrasonic signal attenuation were used to track the process of slurry mixing using single sensors and sensor arrays. Results from two experiments show the use of real-time measurements of ultrasonic signal attenuation to track the process of slurry mixing in situ and to track the ability to maintain a well-mixed steady state condition. Comparison of concentration means of the ultrasonic measurements with concentration means obtained from discrete extractive measurements show that the distributions overlap and cannot be statistically distinguished. The real-time ultrasonic sensor can be used as a primary measurement method or to reduce reliance upon extractive methods to measure slurry density and solids concentration.     

Ultrasonic sensor to measure the density of a liquid or slurry during pipeline transport

This paper describes the design and testing of a computer-controlled sensor for the real-time measurement of the density of a liquid or slurry. It is to be deployed at the US Department of Energy's Hanford Site in Richland, WA, to monitor slurry properties during radioactive waste transfers. To demonstrate the sensor performance, tests were carried out using non-radioactive waste simulants and the results will be presented. The sensor is mounted flush with the pipeline wall in a nominal 5-cm (2-in.) pipe spool piece. The design pressure is 2.8 MPa (400 psi). The probe wedge in contact with the slurry was selected to operate up to pH 14, and the probe components were radiation tested at exposures of 1 x 10(6) R. The sensor is applicable for process control of all types of liquids or slurries in pipelines or in vessels.     

Complete ultrasonic transducer characterization and its use for models and measurements

Transmitting and receiving properties of ultrasonic piezoelectric crystal transducers that directly affect the measured output voltage in an ultrasonic measurement system are described. These transducer properties are the transducer's electrical impedance and sensitivity, the transducer's radiation impedance, and the transducer's effective parameters (effective radius and focal length). It is shown that all these properties can be obtained with a series of calibration measurements, most of them purely electrical in nature. This series of measurements is described, including a newly developed method that makes the determination of the transducer sensitivity simpler than with previous methods. It is demonstrated that by combining these transducer properties with knowledge of the electrical properties of the pulser/receiver and cabling and the acoustic/elastic processes present in an ultrasonic measurement system, it is possible to accurately simulate the output voltage of the system.     

Measurement of viscosity and shear wave velocity of a liquid or slurry for on-line process control

An on-line sensor to measure the density of a liquid or slurry, based on longitudinal wave reflection at the solid-fluid interface, has been developed by the staff at Pacific Northwest National Laboratory. The objective of this research is to employ shear wave reflection at the solid-fluid interface to provide an on-line measurement of viscosity as well. Both measurements are of great interest for process control in many industries. Shear wave reflection measurements were conducted for a variety of liquids. By analyzing multiple reflections within the solid (only 0.63 cm thick-similar to pipe wall thickness) we increased the sensitivity of the measurement. At the sixth echo, sensitivity was increased sufficiently and this echo was used for fluid interrogation. Shear wave propagation of ultrasound in liquids is dependent upon the viscosity and the shear modulus. The data are analyzed using the theory for light liquids (such as water and sugar water solutions) and also using the theory for highly viscous liquids (such as silicone oils). The results show that, for light liquids, the shear wave reflection measurements interrogate the viscosity. However, for highly viscous liquids, it is the shear wave modulus that dominates the shear wave reflection. Since the density is known, the shear wave velocity in the liquid can be determined from the shear wave modulus. The results show that shear wave velocities in silicone oils are very small and range from 315 to 2389 cm/s. Shear wave reflection measurements are perhaps the only way that shear wave velocity in liquids can be determined, because the shear waves in liquids are highly attenuated. These results show that, depending on the fluid characteristics, either the viscosity or the shear wave velocity can be used for process control. There are several novel features of this sensor: (1) The sensor can be mounted as part of the wall of a pipeline or tank or submerged in a tank. (2) The sensor is very compact and can be located within the process stream. (3) The sensor can interrogate and characterize very attenuative liquids or slurries because the sensor operation depends upon reflection at the interface between the solid and the fluid, rather than on transmission through a liquid. (4) The sensor performance is not affected by fluid flow rate, entrained air, or vibration.     

基于声压-质点速度声强探头的材料吸声系数的测量

通过由一个声压换能器和一个质点速度换能器所构成的传感器(p-u声强探头)同时测量材料表面附近的声压和质点振动速度,可直接得到其声学阻抗,进而得到材料的反射因子、吸声系数。本文利用一个p-u探头声强测量系统,在半消声室内测量了三聚氰胺泡沫的吸声系数,分析了声源高度和入射角度、材料样本尺寸和厚度对吸声系数测量的影响,并和阻抗管中测量得到的法向吸声系数进行了对比。最后分析了声阻抗率的幅值和相位误差对吸声系数的影响,推导了它们的误差传递公式。     

Measurement of the viscosity-density product using multiple reflections of ultrasonic shear horizontal waves

We have developed an on-line computer-controlled sensor, based on ultrasound reflection measurements, to determine the product of the viscosity and density of a liquid or slurry for Newtonian fluids and the shear impedance of the liquid for non-Newtonian fluids. A 14 MHz shear wave transducer is bonded to one side of a 45-90 degrees fused silica wedge and the base is in contract with the liquid. Twenty-eight echoes were observed due to the multiple reflections of an ultrasonic shear horizontal (SH) wave within the wedge. The fast Fourier transform of each echo was obtained for a liquid and for water, which serves as the calibration fluid, and the reflection coefficient at the solid-liquid interface was obtained. Data were obtained for 11 sugar water solutions ranging in concentration from 10% to 66% by weight. The viscosity values are shown to be in good agreement with those obtained independently using a laboratory viscometer. The data acquisition time is 14s and this can be reduced by judicious selection of the echoes for determining the reflection coefficient. The measurement of the density results in a determination of the viscosity for Newtonian fluids or the shear wave velocity for non-Newtonian fluids. The sensor can be deployed for process control in a pipeline, with the base of the wedge as part of the pipeline wall, or immersed in a tank.     

On-Line Particle Size Analysis Using Ultrasonic Velocity Spectrometry

A new method is described for the determination of particle size distribution of slurries based on ultrasonic velocity spectrometry combined with gamma-ray transmission. This method shares the advantages of ultrasonic attenuation spectroscopy of being capable of analyzing highly concentrated samples without dilution. However the ultrasonic velocity method is better suited to fine particles of diameter from about 0.1 to 30 μm, a greater volume of slurry is analysed and therefore sampling errors are reduced, and precise theoretical models are readily available to permit the accurate determination of size distribution by inversion of ultrasonic velocity measurements. The method can also be used to accurately determine particle size cut points by linear correlation. Using either inversion or correlation methods, the accuracy of particle size information from ultrasonic velocity spectroscopy is significantly enhanced by the independent measurement of solids loading by gamma-ray transmission. In addition, larger sizes can be measured by combining the ultrasonic velocity method with ultrasonic attenuation measurements. The method has been tested in the laboratory on a wide variety of mineral and paint slurries. The method determined the size distribution of single component silica and alumina samples in water in agreement with laser diffraction measurements and the method successfully distinguished well and poorly dispersed TiO₂ suspensions. For composite samples the method discriminated separate TiO₂ and CaCO₃, components and determined their proportions to within 0.25% volume. In addition the method, in combination with ultrasonic attenuation measurements, determined the size fractions of iron ore slurries below 10 and 30 μm to within 1.3% and 1.0% relative respectively, when compared with laser diffraction measurement of particle size. The CSIRO is presently designing an industrial gauge which will be manufactured and installed in an industrial slurry stream in 1997.     

FEM calculation of an acoustic field in a sonochemical reactor

The spatial distribution of the acoustic amplitude in a sonochemical reactor has been numerically calculated using the finite element method (FEM). In the FEM program, the acoustic field in a sonochemical reactor is coupled with the vibration of the reactor's wall. The present calculations have revealed that the thin (thick) glass or stainless steel wall is nearly a free (rigid) boundary and that the glass wall is freer than the stainless steel wall. The influence of the attenuation coefficient of ultrasound on the acoustic field has also been studied in order to see the effect of bubbles on the acoustic field. As the attenuation coefficient increases, the vibration amplitude of the reactor's wall becomes smaller and the acoustic emission from the vibrating wall becomes weaker. The qualitative feature of the spatial pattern of sonochemiluminescence from an aqueous luminol solution has been reproduced by the calculation when the attenuation coefficient is in the range of 0.5-5m(-1). When the attenuation coefficient is less than about 0.05 m(-1), the standing wave pattern of an acoustic field in the liquid is very complex due to the acoustic emission from the vibrating wall. The present calculations have also revealed that some stripes of pressure antinodes have also been disconnected when the radius of the transducer is much smaller than the side length of the vibrating plate. The dependence of the acoustic field on the liquid height is also discussed.     

Inversion for acoustic impedance of a wall by using artificial neural network

A new approach for measuring acoustic impedance is developed by using artificial neural network (ANN) algorithm. Instead of using impedance tube, a rectangular room or a box is simulated with known boundary conditions at some boundaries and an unknown acoustic impedance at one side of the wall. A training data basis for the ANN algorithm is evaluated by similar source method which was developed earlier by Too and Su [Too G-PJ, Su T-K. Estimation of scattering sound field via nearfield measurement by source methods. Appl Acoust. 1999;58:261-81 (SCI) (EI)] for the estimation of interior and exterior sound field. The training data basis is constructed by evaluating of acoustic pressure at a field point with various acoustic impedance conditions at one side of the wall. Then, the inversion for unknown acoustic impedance of a wall is performed by measuring several field data and substituting these data into ANN algorithm. The simulation result indicates that the prediction of acoustic impedance is very accurate with error percentage under 1%. In addition, one field point measurement in the present approach for acoustic impedance provides more straightforward and easier evaluation than that in the two point measurement of impedance tube.     

Experimental estimation of the transmission loss contributions of a sound package placed in a double wall structure

The objective of this paper is to propose a practical impedance tube method to optimize the sound transmission loss of double wall structure by concentrating on the sound package placed inside the structure. In a previous work, the authors derived an expression that breakdown the transmission loss of a double wall structure containing a sound absorbing blanket separated from the panels by air layers in terms of three main contributions; (i) sound transmission loss of the panels, (ii) sound transmission loss of the blanket and (iii) sound absorption due to multiple reflections inside the cavity. The sound transmission loss contributions of the blanket can thus be estimated from three acoustic measurements using impedance tube techniques: two reflection coefficients at the front face and the rear face of the blanket placed in specific positions characteristic of its position inside the double wall structure and its sound transmission coefficient. The method is first validated in the case of a double wall structure filled with a 2 in. foam material. Next, it is applied to investigate (i) the effect of frame compression of a 2 in. fibre glass in an aeronautic-type double wall structure and (ii) the effect of double porosity with or without porous inclusions in a building-type double wall structure.     

Correction for transducer influence on sound velocity measurements by the pulse echo method

The accuracy of sound velocity measurements calculated by the pulse echo method is influenced markedly by the transducer used. This influence is the result of multiple internal reflections within the transducer and is dependent both on transducer thickness and the impedance mismatch between transducer and sample. Corrections for this effect have been computed for a wide range of sample acoustic impedances and the results were confirmed by experiment. These corrections improve sound velocity measurements, particularly on low impedance materials.     

Using a multi-layered transducer model to estimate the properties of paraffin wax deposited on steel

When using ultrasound for detecting low impedance materials on the surface of high impedance materials, a major challenge is the contrast difference between the strong reverberations from the high impedance material and the weak echoes received from the low impedance material. The purpose of this work is to present the theoretical and experimental validation of an ultrasonic methodology for estimating the acoustical properties of paraffin wax on the surface of steel. The method is based on modeling and inversion of the complete electro-acoustic channel from the transmitted voltage over the active piezoelectric element, to the received voltage resulting from the acoustic reverberations in the multilayered structure. In the current work, two conceptually different models of the same multi-layer transducer structure attached to steel is developed and compared with measurements. A method is then suggested for suppressing the strong reverberations in steel, hence isolating the wax signals. This contrast enhancement method is fitted to the model of the structure, facilitating parameter inversion from the wax layer. The results show that the models agree well with measurements and that up to three parameters (travel time, impedance and attenuation) can be inverted from the wax simultaneously. Hence, given one of the three parameters, density, sound speed or thickness, the other two can be estimated in addition to the attenuation.     

Neutrino exploration of the earth

We show how the neutrinos produced by a multi-TeV proton synchotron may be used for purposes of geological research. Project GENIUS (geological exploration by neutrino-induced underground sound) is designed to search for deposits of oil and gas at large distances from the accelerator. It depends upon the coherent sound signal produced at depth by millions of neutrino interactions along the underground neutrino beam. Surface measurements of the acoustic pulse provide a remote underground probe. Project GEMINI (geological exploration with muons induced by neutrino interactions) is designed to search for distant deposits of high-Z ores. It depends upon the surface measurement of neutrino-induced muons which were produced in the last few kilometers of the neutrinos' underground voyage. Project GEOSCAN is a flux-independent procedure to determine the vertical density profile of the Earth, and especially its core. It depends upon the angle and energy dependence of the attenuation as the neutrino beam traverses the whole Earth.     

Application of the equivalent surface source method to the acoustics of duct systems with non-uniform wall impedance

The paper outlines the application of the equivalent surface source method to the analysis of the acoustic field in a partially lined duct with arbitrarily non-uniform wall impedance. Lined sections of the duct wall are represented by unsteady mass source singularities, the strengths of which are determined by solving integral equations. The method is applicable to lined walls of impedance which is non-uniform in the streamwise and/or circumferential direction. Numerical examples are given to show the effects of various design parameters on sound attenuation. Some advantageous features of circumferentially non-uniform wall impedance are demonstrated.     

超声波多次回波反射法测量油料密度技术研究*

该文通过同时测量油料的声阻抗和声速来测量油料的密度。通过对超声波在不锈钢壁内的多次反射回波信号作快速傅里叶变换,取各次回波信号中心频率下的幅值在对数坐标系下作数据拟合,由拟合曲线斜率并结合多次反射理论求得油料的声阻抗;测量由聚苯乙烯壁面反射回来的二次回波信号计算油料的声速。实验中将温度控制在20?C,测量了8种油料的声阻抗和声速,进而求出8种油料的密度。实验结果表明8种油料密度测量结果的最大误差为1.2%。该方法适合油料密度在线、快速、准确测量。     

Point source equalised by inverse filtering for measuring ground impedance

A point source for measuring ground impedance which complies with the omnidirectionality requirements of the ANSI S1.18 standard is presented. The source consists of a small aperture connected to a conventional loudspeaker through a cone. Whilst this source radiates with deviations lesser than ±1 dB within ±45°, its frequency response exhibits strong peaks arising from resonances of air inside the cone. To equalise these resonances, inverse filtering is applied. Inverse filters pre-emphasise the electrical signal driving the sound source so that zero-phase (or minimum-phase) cosine-magnitude signals are radiated. Equalisation by inverse filtering has two main advantages in the ground impedance measurement. On the one hand, flattening the frequency response avoids large fluctuations of the excess attenuation curve, which can make difficult its inversion to ground impedance data. On the other hand, inverse filtering shorten the time response of the sound source, this in turn making easier the positioning of a time window to separate ground reflection from reflections/diffractions coming from nearby objects usually present in the acoustic scenario.     

Effect of the spectrum of a high-intensity sound source on the sound-absorbing properties of a resonance-type acoustic lining

Experimental results are presented on the effect of both the sound pressure level and the type of spectrum of a sound source on the impedance of an acoustic lining. The spectra under study include those of white noise, a narrow-band signal, and a signal with a preset waveform. It is found that, to obtain reliable data on the impedance of an acoustic lining from the results of interferometric measurements, the total sound pressure level of white noise or the maximal sound pressure level of a pure tone (at every oscillation frequency) needs to be identical to the total sound pressure level of the actual source at the site of acoustic lining on the channel wall.     

In-line concentration measurement in complex liquids using ultrasonic sensors

Recently there has been increased demand for chemical sensors measuring in-line the concentration of selected substances in complex liquids in order to guarantee a high product quality in the process industry. At present there is a great interest in acoustic sensor systems for concentration measurements. This article presents a new ultrasonic sensor system consisting of a miniaturized multi-sensor arrangement for the comprehensive acoustic characterization of liquid mixtures. The sensor system measures sound velocity, impedance coefficient, attenuation coefficient and temperature.     

重塑砂质含气沉积物的声响应特性与模型预测分析

海洋沉积物中气泡的存在对沉积物的声学特性有显著影响.为实现在实验室内对不同初始应力条件下含气沉积物的声学特性测量,研制了一套可用于土工三轴仪的双探针声学测量系统,基于CT扫描试验获得重塑含气砂样品中气泡群的尺寸分布,确定其共振频率范围.试验结果表明:细砂沉积物声速随气体含量的增加呈指数型降低,衰减系数随气体含量的增加呈...