Experimental proof on two-cone axisymmetric-folded combination CO2 laser

The experimental proof of the light output on the two-cone axisymmetric-folded combination (ASFC) CO₂ laser has been performed. The output power from the centre discharge tube is 26.7 W, and that of one couple of folded discharge tubes is 40.5 W. Seventeen beams can be obtained from the device, which are from the folded cavities with axes placed in the inner and outer cones, respectively. Therefore, the ASFC CO₂ laser with more discharge tubes can be fabricated and much higher output power can be obtained.     

The influence of misaligned holophote of the axisymmetric-fold-combination CO2 laser on phase locking

Under the condition of ideal phase locking, output beams with excellent coherence from improved axisymmetric-fold-combination (ASFC) CO₂ laser can be obtained. Unfortunately, misalignments are inevitable. The influence of the misalignment of holophote of fold cavity on phase locking is analyzed, and the light intensity distributions are given by numerical simulation. The conclusion is demonstrated that the method of phase locking of the CO₂ laser is fully feasible under the conditions of the ideal and the misaligned. The results have shown that the effect of phase locking is still excellent when the misalignment angle is in the range of tolerance.     

Optimization of gas pressures ratio in a fast-axial-flow CO2 laser with genetic algorithm

In this paper, the laser output power of a fast-axial flow CO₂ laser was optimized with gas pressures ratio of CO₂:N₂:He using a genetic algorithm technique. The power of laser was increased from 500 W (un-optimized case) to 2200 W (simulated case), also experimentally the power has achieved the value of 700 W (optimized case).     

High-power eye-safe KTA-OPO driven by YVO4/Nd:YVO4 composite laser

We present a high-power 1.53 μm laser based on intracavity KTA-OPO driven by diode-end-pumped acousto-optical Q-switched YVO₄/Nd:YVO₄ composite. The composite crystal was utilized for reducing the thermal effect, and the mode mismatch compensating OPO cavity was designed for efficient OPO conversion. The output power of eye-safe laser at 1535 nm was up to 4.4 W with the pump power of 27 W, corresponding to a diode-to-signal conversion efficiency of 16.3%. To our knowledge, this is the highest output power in diode-end-pumped circumstances. In the experiment, the strong yellow light generated by Raman conversion and frequency doubling in the KTA crystal was observed.     

High pulse repetition frequency RF excited waveguide CO2 laser with mechanical Q-switching

In this paper, a mechanical Q-switching is used in radio frequency (RF) excited waveguide CO₂ laser to obtain high pulse repetition frequency (PRF) laser. The Q-switching system includes two confocal ZnSe lenses and a high speed mechanical chopper, which is inserted into the cavity. The peak power is up to 730 W and the pulse width 200 ns at the highest PRF 20 kHz. The laser also has the advantages of compact, small-volume, and low-cost.     

An eye-safe KTiAsO4 intracavity optical parametric oscillator driven by a diode pumped composite Nd:YAG/Cr4+:YAG laser

A mini eye-safe KTiAsO₄ intracavity optical parametric oscillator (IOPO) employing the shared cavity configuration and driven by a diode-end-pumped composite Nd:YAG/Cr⁴⁺:YAG laser is demonstrated in this paper. Under an incident laser diode power of 11 W, a maximum average output power of 424 mW at 1534 nm was obtained. The corresponding signal pulse width and repetition rate were 1.2 ns and 16.7 kHz, respectively. The fluctuation of the average signal output power over long-term operation was found to be ±3.0%. A theoretical model for the compact IOPO was also presented in this paper.     

Simulation and optimization of deep violet InGaN double quantum well laser

The performance characteristics of a deep violet InGaN double quantum well laser diode (LD) such as threshold current (I_th), external differential quantum efficiency (DQE) and output power have been investigated using the Integrated System Engineering Technical Computer Aided Design (ISE-TCAD) software. As well as its operating parameters such as internal quantum efficiency (η_i), internal loss (α_i) and transparency threshold current density (J₀) have been studied. Since, we are interested to investigate the mentioned characteristics and parameters independent of well and barrier thickness, therefore to reach a desired output wavelength, the indium mole fraction of wells and barriers has been varied consequently. The indium mole fractions of well and barrier layers have been considered 0.08 and 0.0, respectively. Some important parameters such as Al mole fraction of the electronic blocking layer (EBL) and cavity length which affect performance characteristics were also investigated. The optimum values of the Al mole fraction and cavity length in this study are 0.15 and 400 μm, respectively. The lowest threshold current, the highest DQE and output power which obtained at the emission wavelength of 391.5 nm are 43.199 mA, 44.99% and 10.334 mW, respectively.     

Compact resonantly intra-cavity pumped tunable Ho:Sc2SiO5 laser

A compact intra-cavity pumped low threshold continuous-wave Ho:Sc₂SiO₅ laser is reported. The characteristics of output wavelength tuning are investigated by use a intra-cavity briefringent (BF) filter. A wavelength tunable range of 140 nm from 2020 to 2160 nm is achieved. For the free-running mode, the laser slope efficiency is 24.8%, when the output central wavelength is 2110 nm. The laser threshold is about 820 mW of incident pump power. With the BF filter, a maximum output power of 870 mW is obtained at the incident pump power of 5 W, corresponding to a slope efficiency of 20.3%. The characteristics of output wavelength verse the crystal temperature are also investigated.     

Wall paper single-walled carbon nanotubes absorber for passively mode-locked Nd: GdVO4 laser

A novel and low-cost wall paper single-walled carbon nanotubes (SWCNTs) absorber was fabricated by high viscosity of polyvinyl alcohol (PVA) aqueous solution and vertical evaporation technique. Sandwich structure wall paper SWCNT (SSWA-SWCNT) absorber was constructed by a piece of wall paper SWCNT absorber, a piece of round quartz and an output coupler mirror. We exploited it to realize mode locking operation in a diode-pumped Nd: GdVO₄ laser. A pulse duration of 9.6 ps was produced with an average power of 870 mW. The stable mode locking operation was obtained when the average power is less than 300 mW.     

High-power sixth-harmonic generation of an Nd:YAG laser with KBe2BO3F2 prism-coupled devices

High-power sixth harmonic generation from an Nd:YAG laser (10 ns, 10 kHz) has been achieved with a KBe₂BO₃F₂ (KBBF) prism-coupled device (PCD) containing a 1.95 mm thick KBBF crystal. The highest output power reached 120.5 mW at 177.3 nm, and the highest conversion efficiency from 354.7 to 177.3 nm was 1.82%. Moreover, stable sixth harmonic output with an average power of 22.2 mW was produced by another KBBF-PCD, in which the thickness of the KBBF crystal was 1.51 mm. The highest and stable sixth harmonic output powers are improved by about three and six times compared with the previously published results, respectively.     

Pulsed Nd:YAG passive Q-switched laser using Cr4+:YAG crystal

In this paper, we report the experimental results of a pulsed flash lamp Nd:YAG laser at wavelength of 1064 nm and Q-switched by Cr⁴⁺:YAG solid state saturable absorber. We have obtained the output energy (E) and pulse- width (τ_p) of this laser for various initial transmissions of this saturable absorber. Furthermore, the effect of reflectivity of the output coupler (R), diameter of the rod (d), and optical length of the cavity (l) on this laser output data have been investigated. We have used the corner cube as a back mirror, which shows high laser stability and better brightness. We have obtained pulse-width 15 ns with 31 mJ output energy. We have also analyzed this laser theoretically and analytically, which agrees well with our corresponding experimental results.     

Damage/ablation morphology of laser conditioned sapphire under 1064 nm laser irradiation

The damage/ablation morphologies and laser induced damage threshold (LIDT) of three different sapphire samples: original, 1064 nm laser conditioned and 10.6 μm CO₂ laser polished substrates are investigated with ns pulses laser irradiation. The results indicate that the damage resistance capability cannot be enhanced by 1064 nm laser conditioning or CO₂ laser polishing. The damage/ablation morphology of 1064 nm-laser conditioned samples is same as that of the original sapphire. But it is different from the damage/ablation morphology of the CO₂ laser polished sapphire. The “gentle and strong” ablation phases are observed in this work and several phenomena are observed in the two ablation phases. Ripple is observed in the “gentle” ablation processes, while convex spots and raised rims are observed in the “strong” ablation processes. Meanwhile, stripe damage and pin-points are observed in the CO₂ laser conditioned sapphire after ns laser irradiation. The formation mechanisms of the phenomena are also discussed for the explanation of related damage/ablation morphology. The results may be helpful for the damage/ablation investigation of sapphire in high power laser systems.     

Diode-pumped Nd:YAG ceramic laser at 946 nm passively Q-switched with a Cr4+:YAG saturable absorber

We demonstrate a diode-pumped Nd:YAG ceramic laser with emission at 946 nm that is passively Q-switched by single-crystal Cr⁴⁺:YAG saturable absorber. An average output power of 1.7 W is measured under 18.4 W of incident power using an output mirror with transmission T=4%. The corresponding optical-to-optical efficiency is 9.2%. The laser runs at a pulse repetition rate of 120 kHz and delivers pulses with energy of 14 μJ and duration of 80 ns, which corresponds to a peak power of 175 W.     

RF behavior of triple-frequency high power fusion gyrotron

The RF behavior of high power, triple frequency (170-, 127.5-, and 85 GHz) gyrotron for fusion application is presented in this paper. The operating mode selection is discussed in detail for each corresponding frequencies and TE_34,10, TE_25,8 and TE_17,5 modes are selected as the operating mode for 170 GHz, 127.5 GHz and 85 GHz operation of the device, respectively. The interaction cavity geometry and beam parameters are finalized by the cold cavity analysis and beam-wave interaction simulations. Considering the beam parameters and the beam launching positions in cavity (beam radius), the design of Magnetically Tunable MIG (MT-MIG) is also presented. Results of MT-MIG confirm the beam launching with desired beam parameters at the beam radius corresponding to the selected operating modes for all three frequencies. The CVD diamond window is also designed for RF power transmission. The beam-wave interaction simulations confirm more than 1 MW power at all three frequencies (170-, 127.5-, and 85 GHz).     

Behavior of CO2/water flow in porous media for CO2 geological storage

A clear understanding of two-phase fluid flow properties in porous media is of importance to CO₂ geological storage. The study visually measured the immiscible and miscible displacement of water by CO₂ using MRI (magnetic resonance imaging), and investigated the factor influencing the displacement process in porous media which were filled with quartz glass beads. For immiscible displacement at slow flow rates, the MR signal intensity of images increased because of CO₂ dissolution; before the dissolution phenomenon became inconspicuous at flow rate of 0.8 mL min^− 1. For miscible displacement, the MR signal intensity decreased gradually independent of flow rates, because supercritical CO₂ and water became miscible in the beginning of CO₂ injection. CO₂ channeling or fingering phenomena were more obviously observed with lower permeable porous media. Capillary force decreases with increasing particle size, which would increase permeability and allow CO₂ and water to invade into small pore spaces more easily. The study also showed CO₂ flow patterns were dominated by dimensionless capillary number, changing from capillary finger to stable flow. The relative permeability curve was calculated using Brooks-Corey model, while the results showed the relative permeability of CO₂ slightly decreases with the increase of capillary number.     

Cascaded continuous-wave singly resonant optical parametric oscillator pumped by a single-frequency fiber laser

We present a cascaded continuous-wave singly resonant optical parametric oscillator (SRO) delivering idler output in mid-IR and terahertz frequency range. The SRO was pumped by an ytterbium-doped fiber laser with 27 W linear polarization pump powers, and based on periodically poled MgO:LiNbO₃ crystal (PPMgLN) in two-mirror linear cavity. The PPMgLN is 50 mm long with 29.5 μm period. The idler power output at 3811 nm was obtained 2.6 W. The additional spectral components that have been attributed to cascaded optical parametric processes are described at increasing pump levels. Besides the initial signal component at about 1476.8 nm, further generated wavelengths with frequency shifts about 47 cm^?1, 94 cm^?1 and 104 cm^?1 were observed. It was speculated that the idler waves lie in the terahertz (THz) domain from the observed results.     

Ultrasound-induced emulsification of subcritical carbon dioxide/water with and without surfactant as a strategy for enhanced mass transport

Pulsed ultrasound was used to disperse a biphasic mixture of CO₂/H₂O in a 1 dm³ high-pressure reactor at 30 °C/80 bar. A view cell positioned in-line with the sonic vessel allowed observation of a turbid emulsion which lasted approximately 30 min after ceasing sonication. Within the ultrasound reactor, simultaneous CO₂-continuous and H₂O-continuous environments were identified. The hydrolysis of benzoyl chloride was employed to show that at similar power intensities, comparable initial rates (1.6 ± 0.3 × 10^–3 s^–1 at 95 W cm^–2) were obtained with those reported for a 87 cm³ reactor (1.8 ± 0.2 × 10^–3 s^–1 at 105 W cm^–2), demonstrating the conservation of the physical effects of ultrasound in high-pressure systems (emulsification induced by the action of acoustic forces near an interface). A comparison of benzoyl chloride hydrolysis rates and benzaldehyde mass transport relative to the non-sonicated, ‘silent’ cases confirmed that the application of ultrasound achieved reaction rates which were over 200 times faster, by reducing the mass transport resistance between CO₂ and H₂O. The versatility of the system was further demonstrated by ultrasound-induced hydrolysis in the presence of the polysorbate surfactant, Tween, which formed a more uniform CO₂/H₂O emulsion that significantly increased benzoyl chloride hydrolysis rates. Finally, pulse rate was employed as a means of slowing down the rate of hydrolysis, further illustrating how ultrasound can be used as a valuable tool for controlling reactions in CO₂/H₂O solvent mixtures.     

Ultrasound assisted co-precipitation of nanostructured CuO–ZnO–Al2O3 over HZSM-5: Effect of precursor and irradiation power on nanocatalyst properties and catalytic performance for direct syngas to DME

Nanostructured CuO–ZnO–Al₂O₃/HZSM-5 was synthesized from nitrate and acetate precursors using ultrasound assisted co-precipitation method under different irradiation powers. The CuO–ZnO–Al₂O₃/HZSM-5 nanocatalysts were characterized using XRD, FESEM, BET, FTIR and EDX Dot-mapping analyses. The results indicated precursor type and irradiation power have significant influences on phase structure, morphology, surface area and functional groups. It was observed that the acetate formulated CuO–ZnO–Al₂O₃/HZSM-5 nanocatalyst have smaller CuO crystals with better dispersion and stronger interaction between components in comparison to nitrate based nanocatalysts. Ultrasound assisted co-precipitation synthesis method resulted in nanocatalyst with more uniform morphology compared to conventional method and increasing irradiation power yields smaller particles with better dispersion and higher surface area. Additionally the crystallinity of CuO is lower at high irradiation powers leading to stronger interaction between metal oxides. The nanocatalysts performance were tested at 200–300 °C, 10–40 bar and space velocity of 18,000–36,000 cm³/g h with the inlet gas composition of H₂/CO = 2/1 in a stainless steel autoclave reactor. The acetate based nanocatalysts irradiated with higher levels of power exhibited better reactivity in terms of CO conversion and DME yield. While there is an optimal temperature for CO conversion and DME yield in direct synthesis of DME, CO conversion and DME yield both increase with the pressure increase. Furthermore ultrasound assisted co-precipitation method yields more stable CuO–ZnO–Al₂O₃/HZSM-5 nanocatalyst while conventional precipitated nanocatalyst lost their activity ca. 18% and 58% in terms of CO conversion and DME yield respectively in 24 h time on stream test.     

Ultrasound coupled with supercritical carbon dioxide for exfoliation of graphene: Simulation and experiment

Ultrasound coupled with supercritical CO₂ has become an important method for exfoliation of graphene, but behind which a peeling mechanism is unclear. In this work, CFD simulation and experiment were both investigated to elucidate the mechanism and the effects of the process parameters on the exfoliation yield. The experiments and the CFD simulation were conducted under pressure ranging from 8 MPa to 16 MPa, the ultrasonic power ranging from 12 W to 240 W and the frequency of 20 kHz. The numerical analysis of fluid flow patterns and pressure distributions revealed that the fluid shear stress and the periodical pressure fluctuation generated by ultrasound were primary factors in exfoliating graphene. The distribution of the fluid shear stress decided the effective exfoliation area, which, in turn, affected the yield. The effective area increased from 5.339 cm³ to 8.074 cm³ with increasing ultrasonic power from 12 W to 240 W, corresponding to the yield increasing from 5.2% to 21.5%. The pressure fluctuation would cause the expansion of the interlayers of graphite. The degree of the expansion increased with the increase of the operating pressure but decreased beyond 12 MPa. Thus, the maximum yield was obtained at 12 MPa. The cavitation might be generated by ultrasound in supercritical CO₂. But it is too weak to exfoliate graphite into graphene. These results provide a strategy in optimizing and scaling up the ultrasound-assisted supercritical CO₂ technique for producing graphene.     

Ultrafast laser performance of Yb3 +: Sc2SiO5 crystal with a single-walled carbon nanotube absorber

Single-walled carbon nanotube (SWCNT) absorber fabricated by vertical evaporation is used in passively mode-locked Yb^3 +:Sc₂SiO₅ (Yb:SSO) ultrafast laser for the first time. The performance of Yb:SSO ultrafast laser with pulse width as short as 880 fs is studied and the average output power is 712 mW. To our knowledge, this is the highest output power of femtosecond lasers with SWCNT-SAs reported. In addition, we firstly demonstrate a passively mode-locked picosecond Yb:SSO laser without inserting any dispersion compensation device. The pulses width is as short as 5.4 ps and the output power is 940 mW.