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新试剂5-氟偶氮胂Ⅰ荧光法测定铝的研究 总被引:2,自引:0,他引:2
本文报道了新试剂5-氟偶氮胂Ⅰ(5-FAsA-Ⅰ)的合成方法,研究了荧光光度法测定铝的反应条件。Al(Ⅲ)与试剂在pH5.60HAc-NaAc缓冲介质中形成1+1红色配合物并呈现荧光,λex/λem=348.6/391.4nm,线性范围为0~0.2μg/mL,检测限为3.0ng/mL。用于分析茶叶样品中的铝,结果满意。 相似文献
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7—[(4—甲基2—胂酸基苯)偶氮]—8—羟基喹啉—5—磺酸荧光光度法测定氟 总被引:1,自引:0,他引:1
本文介绍了7-[(4-甲基-2-胂酸基苯)偶氮]-8-羟基喹啉-5-磺酸的合成方法以及性能,详细研究了氟对该试剂与铝形成的荧光的熄灭作用,建立了荧光法测定微量氟的新方法。应用于水样和牙膏中的氟的测定,效果良好。 相似文献
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新荧光试剂DHB—8Q5S与铝的配合反应及分析应用研究 总被引:6,自引:0,他引:6
研究了新合成的试剂7-8-羟基喹啉-5磺酸荧光光度法测定铝的反应条件,铝与试剂在PH5.00-5.75的乙酸/乙酸钠缓冲溶液中形成1+1型配合物并呈现荧光,其最大激发波长/发射波长λex/λem=522/570,检测下限为3×10^-8μg/mL考察了共存离子的干扰,并用于样品分析,结果满意。 相似文献
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9-(3,5-二溴)水杨基荧光酮-溴化十六烷基三甲铵荧光光度法测定微量铝 总被引:4,自引:0,他引:4
研究了9-(3,5-二溴)水杨基荧光酮与铝(Ⅲ)的反应条件。在PH5.5的(CH2)6N4-HCL缓冲溶液中,AI(Ⅲ)与试睡成络合物使试剂的荧光猝灭。建立了铝-9-(3,5-二溴),水杨基荧光酮体系测定痕量铝的荧光光度法。荧光强度与铝的含量在0~1.4μg/mL范围内呈线性关系。本法已用于合金风标样中铝的测定。 相似文献
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新试剂7—(2,4—二羟基—5—羧基苯偶氮)—8—羟基喹啉—5—磺酸与铝的荧?… 总被引:3,自引:2,他引:1
研究了新试剂7-(2,4-二羟基-5-羧基苯偶氮)-8-羟基喹啉-5-磺酸形成的络合物的荧光性能。在pH4.62的NaAc-HAc体系中形成1:1型强荧光配合物,其λex=510nm,λem=572nm,铝含量在0-0.08mg/L范围内与荧光强度呈线性关系,方法检出限为1.04×10^-10mol/L。 相似文献
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新试剂3,5—二溴—4—偶氮8—羟基喹啉苯基荧光酮光度法测定微量铝 总被引:9,自引:0,他引:9
在溴化十六烷基三甲胺(CTMAB)存在下,PH6,0的HAc-NaAc缓冲介质中,铝与新试剂3,5-二溴-4-偶氮8-羟基喹啉苯基荧光酮形成红色三元胶束配合物,最大吸收波长位于564nm,表观摩尔吸光系数ε为1.35×10^5.mol^-1.cm^-1,铝浓度在0~5μg/25mL范围内符合比耳定律,拟定的方法用于铝铁黄铜中微量铝的测定,结果满意。 相似文献
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Helio G. Bonacorso Carson W. WiethanChaiene R. Belo Maiara C. MoraesMarcos A.P. Martins Nilo Zanatta 《Tetrahedron letters》2014
The results of allylation reactions employing allylaluminum reagents are described for 5-substituted (2,6-difluorobenzyl)-4-trifluoro(chloro)acetyl-1H-1,2,3-triazoles (1), in which the 5-substituents are H, Me, and Ph. The allylating reagents were generated in situ by the catalytic insertion of aluminum into allyl and crotyl bromides (2), in order to furnish a new series of twelve trihalomethyl triazolyl homoallylic alcohols (3) at yields of up to 94%. The excellent reactivity of these organoallyl reagents is highlighted as an economical alternative to the indium-mediated reactions to produce homoallylic alcohols, which are important building blocks in organic synthesis. 相似文献
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Paramagnetic properties of nanopowders obtained by electric explosion of copper, aluminum, cobalt, and platinum conductors have been studied. The possibility of using ESR and model reaction of isopropylbenzene for testing the electric-explosion powders as chemical reagents is discussed. 相似文献
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Sahel Fatma Sebih Fatiha Bellahouel Salima Bengueddach Abdelkader Hamacha Rachida 《Research on Chemical Intermediates》2020,46(1):133-148
Research on Chemical Intermediates - Low-cost Al-MCM-41 and Al-SBA-15 mesoporous materials are successfully synthesized from bentonite as silicon and aluminum sources instead of laboratory reagents... 相似文献
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Katsuyuki Kunii Kazuhiro Narahara Shoji Yamanaka 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6-7):1437-1440
Microwave heating enhanced the crystallization of aluminophosphate gels, and AlPO 4 -H1 was successfully obtained without using organic template reagents in a short reaction time. The use of amorphous aluminum hydroxide as an aluminum source and the addition of hydrochloric acid were found to be essentially important to obtain AlPO 4 -H1 as a single phase. Nitrogen and water adsorption properties were studied by measuring the adsorption isotherms. 相似文献
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O. V. Kikhtyanin A. V. Toktarev A. B. Ayupov N. N. Boldyreva G. V. Echevskii 《Russian Chemical Bulletin》2012,61(10):1867-1876
Microporous aluminophosphates and silicoaluminophosphates were obtained by hydrothermal synthesis with a number of symmetrical di-n-alkylamines as templates. The influence of the reagents and chemical composition of the starting reaction gel on the phase composition of the products obtained was studied. Pure ATO-type crystals were formed when the organic component was abundant in the reaction mixture and aluminum isopropoxide served as an aluminum source. Various physicochemical investigations revealed that the properties of the products obtained depend on the amine nature. 相似文献
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Carlo F. Morelli Arianna Fornili Lavinia Durì Paolo Manitto 《Tetrahedron letters》2005,46(11):1837-1840
The Cl2AlH-mediated ring-opening of 2-substituted cis-4-methyl-5-trifluoromethyl-1,3-dioxolanes was found to occur with regioselective cleavage of the O1-C2 bond by attack of the aluminum hydride from the direction anti to the departing oxygen. This stereochemical outcome, which appears to be unprecedented in the reductive cleavage of chiral acetals by aluminum reagents, is interpreted on the basis of theoretical calculations. 相似文献
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有机铝杂环化合物作为金属杂环化合物中的重要一员,在有机合成中表现出一些独特的性质。有机铝杂环化合物主要包括铝杂环戊二烯、铝杂环戊烯,以及铝杂环戊烷。本文介绍近年来有机铝杂环化合物的合成方法学、反应化学及其在有机合成中的应用研究进展。 相似文献
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The reactions of AlMe(2)Y (Y = Me or Cl) with new ligands 2-(1,3,5-dithiazinan-5-yl)ethanol (1), 2-(1,3,5-dithiazinan-5-yl)-1-methylethanol (2), and 2-(1,3,5-dithiazinan-5-yl)-1-phenylethanol (3) are described. The ligands are coordinated to aluminum atoms by nitrogen and oxygen atoms, with a nitrogen based spiranic structure. Equimolar reactions gave dimeric structures bearing pentacoordinated aluminum atoms O-(AlMeY)-2-(1,3,5-dithiazinan-5-yl)ethanolates (4-7) as well as monometallic compounds with tetracoordinated aluminum atoms O-(AlMeY)-2-(1,3,5-dithiazinan-5-yl)ethanolates (8-9). Reactions with 2 equiv of the aluminum reagents afforded tetracoordinated dialuminum complexes O-(AlMeY)-O-(AlMe(2)Y)-2-(1,3,5-dithiazinan-5-yl)ethanolate (10-18). The structures of the new compounds were determined by NMR ((1)H,(13)C, and (27)Al) and complemented by X-ray diffraction of compounds 4, 10, and 16-18. Relevant intermolecular interactions C-H...S, C-H...Cl, and C-H...pi found in the crystalline network are reported. 相似文献
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E. E. Grinberg Yu. I. Levin I. E. Strel’nikova A. E. Amelina 《Russian Journal of Applied Chemistry》2014,87(5):567-571
Possibility of deep purification of lower aluminum alcoholates used to synthesize aluminum oxide by the sol-gel method and pyrolytic technique is analyzed. The influence exerted by the purity of the starting reagents, moisture content, and catalyst on the nature of the process and the purity of the product being obtained was examined. 相似文献
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Renaud Millet 《Tetrahedron letters》2009,50(26):3474-1750
The desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand is described. The corresponding homoallylic alcohols are obtained in high yield, diastereoselectivity, and enantiomeric excess. Furthermore the first anti enantioselective desymmetrization with aromatic nucleophiles is reported. 相似文献