Ablation depth control with 40 nm resolution on ITO thin films using a square,flat top beam shaped femtosecond NIR laser

We reported on the ablation depth control with a resolution of 40 nm on indium tin oxide (ITO) thin film using a square beam shaped femtosecond (190 fs) laser (λ_p=1030 nm). A slit is used to make the square, flat top beam shaped from the Gaussian spatial profile of the femtosecond laser. An ablation depth of 40 nm was obtained using the single pulse irradiation at a peak intensity of 2.8 TW/cm². The morphologies of the ablated area were characterized using an optical microscope, atomic force microscope (AFM), and energy dispersive X-ray spectroscopy (EDS). Ablations with square and rectangular types with various sizes were demonstrated on ITO thin film using slits with varying x–y axes. The stereo structure of the ablation with the depth resolution of approximately 40 nm was also fabricated successfully using the irradiation of single pulses with different shaped sizes of femtosecond laser.     

Manganite heterojunction photodetectors for femtosecond pulse laser measurements

We report a sensitive photodetector, based on a manganite junction La_2/3Ca_1/3MnO₃/Si, for femtosecond (fs) pulse laser energy per pulse and average power measurements. The La_2/3Ca_1/3MnO₃/Si photodetector exhibits D^? (normalized detectivity) greater than 5.229×10⁹ cm Hz^1/2 W^?1. The open-circuit photovoltage and short-circuit photocurrent responsivities reach ～268 V/mJ and ～275 A/mJ for single pulse irradiation, respectively, and the open-circuit photovoltage responsivity reaches ～1.7 V/W for average power illumination. The experimental results make the manganite junction a promising fs laser measurement detector and reference standard for calibrating fs lasers.     

Femtosecond single-mode diode-pumped Cr:LiSAF laser mode-locked with single-walled carbon nanotubes

A low threshold Cr:LiSAF laser pumped with an inexpensive single-mode laser diode emitting 120 mW was passively mode-locked with a novel ultrafast saturable absorber mirror based on single-walled carbon nanotubes (SWCNT-SAM). Pulses as short as 122 fs were achieved, tunable across 14 nm. A second pump diode coupled in polarization allowed to shorten the pulse duration to 106 fs, with up to 24-mW output power.     

Wavelength tunable,high energy femtosecond laser pulses directly generated from large-mode-area photonic crystal fiber

Wavelength tunable high energy ultrashort laser pulses are generated from a large-mode-area photonic crystal fiber in anomalous dispersion (AD) regime. A simplified laser cavity design with one fine polished facet of the fiber as a cavity mirror is used. The intra-cavity dispersion compensation is achieved by a grating pair, the spatial dispersed light from which also have optical spectrum filtering effects combined with the limited aperture of the fiber core. The laser system is able to generate ultrashort pulses ranging from 494 fs (with 56 nJ pulse energy) to 1.24 ps (with 49 nJ pulse energy) at 55 MHz repetition rate. The filtering mechanism benefits the generation of high energy pulses with narrowing pulse duration in AD regime. An undulation in frequency and time domain is also observed with the increase of the pump power. Furthermore, this laser system is directly used as seed for supercontinuum generation.     

Optimal ablation of fluorine-doped tin oxide (FTO) thin film layers adopting a simple pulsed Nd:YAG laser with TEM00 mode

In material processing, a laser system with optimal laser parameters has been considered to be significant. Especially, the laser ablation technology is thought to be very important for fabricating a dye-sensitized solar cell (DSSC) module with good quality. Moreover, the TEM₀₀ mode laser beam is the most dominant factor to decide the incident photon to current conversion efficiency (IPCE) characteristics. In order to get the TEM₀₀ mode, a pin-hole is inserted within a simple pulsed Nd:YAG laser resonator. And the spatial field distribution is measured by using three pin-hole diameters of 1.6, 2.0 and 4.0 mm, respectively. At that moment, each case has the same laser beam energy by adjusting the discharge voltage and pulse per second (pps). From those results, it is known that the pin-hole size of 1.6 mm has the perfect TEM₀₀ mode. In addition, at the charging voltage of 1000 V, 10 pps, the feeding speed of 6.08 mm/s and the overlapping rate (OL) of 62%, the scanning electron microscope (SEM) photograph of fluorine-doped tin oxide (FTO) thin film layers shows the best ablation trace.     

Absorption,luminescence, and electron paramagnetic resonance of molybdenum ions in CdWO4

A single crystal of cadmium tungstate (CdWO₄) containing approximately 200 ppm of molybdenum was grown by the Czochralski method and then characterized in a series of optical absorption, photoluminescence (PL), photoluminescence excitation (PLE), and electron paramagnetic resonance (EPR) experiments. The Mo⁶⁺ ions substitute for W⁶⁺ ions and serve as recombination sites for electrons and holes when the crystal is exposed to ionizing radiation. A charge-transfer absorption band for the Mo⁶⁺ ions was observed near 320 nm at 10 K. The PL experiments, performed at low temperature with 325 nm excitation, showed a Mo-associated emission peaking near 680 nm. A direct correlation of the 680 nm emission and the 320 nm absorption band was established by the PLE data. When these doped CdWO₄ crystals are exposed at low temperature either to light that is near or above the band gap or to X-rays, the Mo⁶⁺ ions can trap an electron and form stable Mo⁵⁺ ions. The EPR spectrum of the Mo⁵⁺ ions was observed at temperatures near 15 K, and a complete set of parameters describing the g matrix was obtained from an angular dependence study.     

Surface treatment of CFRP composites using femtosecond laser radiation

In the present work, we investigate the surface treatment of carbon fiber-reinforced polymer (CFRP) composites by laser ablation with femtosecond laser radiation. For this purpose, unidirectional carbon fiber-reinforced epoxy matrix composites were treated with femtosecond laser pulses of 1024 nm wavelength and 550 fs duration. Laser tracks were inscribed on the material surface using pulse energies and scanning speeds in the range 0.1–0.5 mJ and 0.1–5 mm/s, respectively. The morphology of the laser treated surfaces was investigated by field emission scanning electron microscopy. We show that, by using the appropriate processing parameters, a selective removal of the epoxy resin can be achieved, leaving the carbon fibers exposed. In addition, sub-micron laser induced periodic surface structures (LIPSS) are created on the carbon fibers surface, which may be potentially beneficial for the improvement of the fiber to matrix adhesion in adhesive bonds between CFRP parts.     

Design and construction of Q-switched Nd:YAG laser system for LIBS measurements

A passive, Q-switched pulsed, Nd:YAG laser system was designed and built, which can provide a potential compact robust laser source for portable laser induced breakdown spectroscopy systems.The developed laser system operates at 1064 nm. Each laser shot contains a train of pulses having maximum total output energy of 170 mJ. The number of pulses varies from 1–6 pulses in each laser shot depending on the pump energy. The pulse width of each pulse ranges from 20 to 30 ns. The total duration of the output pulse train is within 300 μs. The multi-pulse nature of the laser shots was employed to enhance the LIBS signal. To validate the system, LIBS measurements and analysis were performed on ancient ceramic samples collected from Al-Fustat excavation in Old Cairo. The samples belong to different Islamic periods in Egypt history. The results obtained are highly indicative that useful information can be provided to archeologists for use in restoring and repairing of precious archeological objects.     

Soft-X-ray lasing in nickel-like barium at 9.2 nm using the grazing-incidence scheme

We report on the experimental demonstration of saturated X-ray lasing on the 4 d → 4p, J = 0–1 line of nickel-like barium (Ba, Z = 56) at a wavelength of 9.2 nm, using a main pulse energy of 9 J in a 1.5-ps duration pulse from a Nd:glass chirped-pulse amplification laser. Gain saturation was achieved by applying a triple-pulse scheme in which a weak (few-percent) prepulse, preceding the main pulse by 2.4 ns, is followed by a second, relatively intense (16%) prepulse ~ 50 ps before the main pulse. For handling convenience, compound targets of BaF₂ were used, either in the form of windows or coated onto glass slides.     

An anti-reflective 1D rectangle grating on GaAs solar cell using one-step femtosecond laser fabrication

We report the fabrication of the anti-reflective micro/nano-structure on absorbing layer of GaAs solar cell surface using an efficient approach based on one-step femtosecond laser irradiation. Morphology of the microstructures and reflectance of the cell irradiated are characterized with SEM and spectrometer to analyze the influence of laser processing parameters on the change of microstructures induced and the reflectance. It has been found that the rectangle grating micro/nano-structure with a period of 700 nm and width of 600 nm is obtained neatly with laser pulse energy of 30.5 μJ(pulse duration is 130 fs, center wavelength is 800 nm, scanning speed is 2.2 mm/s and spot diameter is 22 µm). Reflectance has been suppressed to 23.6% with rectangle structure from 33% of planar cell. In addition, simulation using a finite-difference-time domain(FDTD) method results show that the rectangle grating micro/nano-structure can effectively suppress the reflection within large wavelength ranges.     

Relaxation dynamics of electronic excitations in CaWO4 and CdWO4 crystals studied by femtosecond interferometry technique

The relaxation of electronic excitations in CdWO₄ and CaWO₄ crystals was studied using the method of time-resolved interferometry with 100-fs temporal resolution at temperatures 15–295 K. The electronic system was excited in the one-photon and two-photon regime within the excitonic band in CaWO₄ and in the electron-hole continuum in CdWO₄. Immediate trapping of charge carriers was detected under pumping in the excitonic band of CaWO₄. This result is in agreement with decay kinetics measurements with nanosecond time resolution under direct creation of excitons by 100-fs laser pulses. Fast relaxation of charge carriers followed by formation of excitons was observed in CdWO₄. The comparison with previous work allows suggesting the formation of bulk excitons and surface-perturbed excitons in the multi-photon and one-photon regime. The corresponding models of self-trapped exciton creation in tungstate crystals are discussed.     

Fundamental and harmonic mode-locking in erbium-doped fiber laser based on graphene saturable absorber

Graphene-based passively mode-locked erbium doped fiber laser is presented. Multilayer graphene was obtained by mechanical exfoliation of pure graphitic block and deposited on the fiber ferrule. The mode-locking performance was investigated under various laser pumping conditions. The laser could operate at fundamental repetition rate of 16.34 MHz with 844 fs pulse duration and 30 mW average output power. Also harmonic-mode locking of the laser is demonstrated. 294 and 800 MHz repetition rates were obtained (corresponding to the 18th and 49th harmonic of the fundamental repetition frequency, respectively) with nearly transform-limited pulses.     

Diode-pumped actively Q-switched Nd:GGG laser operating at 938 nm

The stimulated emission cross-section of Nd:GGG crystal in 938 nm transition was measured by the amplifier approach. It is 2.3×10^?20 cm². A quasi-continuous-wave diode pumped, actively Q-switched Nd:GGG laser operating at 938 nm was demonstrated. Pumped by laser diodes with 900 W peak power and 300 μs pulse duration, it generated 168 mJ energy in long pulse mode. The slope efficiency was 36%. Q-switched by a KD?P Pockels cell, 41 mJ output pulse energy was obtained. The pulse duration and peak power were 120 ns and 340 kW, respectively. The optical to optical efficiency was 7%.     

Pulsed laser induced damage in SOI material

Laser-induced damage in silicon-on-insulator (SOI) material is investigated with 1064 nm laser pulses. As the laser pulse duration is increased from 190 ps to 1.14 s, the damage threshold of SOI material decreases from 1.3×10¹⁰ to 7.7×10³ W/cm² in laser flux. It is found that the damage threshold varies inversely as the pulse duration for a short irradiation time, and is independent of pulse duration for a long irradiation time. The time dependence is in good agreement with a thermal model which well describes the thermal-induced damage in a semi-finite material irradiated by a Gaussian laser beam. The values of absorption coefficient and thermal conductivity under laser irradiation are calculated as 1.1×10³ cm^?1 and 0.18 Wcm^?1 K^?1, respectively, by fitting the model to the experimental results. These results on material damage can be used to predict the damage thresholds of SOI-based devices.     

Behaviour of scintillators under XUV free electron laser radiation

Free electron lasers (FEL) are new generation accelerator-based short wavelength light sources providing high pulse intensity and femtosecond pulse duration, which enable investigation of interaction of elementary excitations in solids under extreme conditions. Using the FLASH facility of HASYLAB at DESY (Hamburg, Germany), we investigated the response of different materials with scintillating properties based on intrinsic emissions to the 25.6 and 13.8 nm FEL radiation by means of time-resolved luminescence spectroscopy. FLASH delivered single pulses of 25 fs duration having energy per pulse up to 30 μJ resulting in power densities of ～10¹² W/cm² on crystals. As a function of excitation density we observed the shortening of lifetime and non-exponential behaviour of emission decays in CaWO₄, while the emission spectra recorded are comparable to those obtained at conventional excitation sources.     

330 MHz,sub 50 fs Yb: Fiber ring laser

We demonstrate 330 MHz repetition rate operation in a ring cavity Yb:fiber laser with an innovative wavelength-division-multiplexing collimator to raise the repetition rate. The spectral bandwidth of the pulse is 30 nm and the dechirped pulse width is 48 fs. The output power is 70 mW with 600 mW, 975 nm pump laser diode.     

Efficient femtosecond Yb:YAG laser pumped by a single-mode laser diode

Single-mode diodes enable a particularly simple, compact and effective pumping of solid-state laser devices for many specialized applications. We investigated a single-mode, 300-mW laser diode for pumping at 935 nm a Yb:YAG laser passively mode-locked by a semiconductor saturable absorber. Relatively short pulse generation (156 fs), tunable across 1033–1059 nm has been demonstrated. An optical-to-optical efficiency of about 28% has been obtained with 320 fs long pulses. Therefore, contrarily to what previously believed, compact diode-pumped ultrafast Yb:YAG oscillators can reliably and efficiently deliver pulses in the range of ≈ 100–200 fs with few tens of mW, which are very appealing for bio-diagnostics and amplifier seeding applications.     

Effect of laser incident energy on the structural,morphological and optical properties of Cu2ZnSnS4 (CZTS) thin films

The polycrystalline Cu₂ZnSnS₄ (CZTS) thin films have been prepared by pulsed laser deposition (PLD) method at room temperature. The laser incident energy was varied from 1.0 at the interval of 0.5–3.0 J/cm². The effect of laser incident energy on the structural, morphological and optical properties of CZTS thin films was studied by means of X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and optical absorption. The studies reveal that an improvement in the structural, morphological and optical properties of CZTS thin films with increasing laser incident energy up to 2.5 J/cm². However, when the laser incident energy was further increased to 3.0 J/cm², leads to degrade the structural, morphological and optical properties of the CZTS thin films.     

Removal of four kinds of volatile organic compounds mixture in air using silent discharge reactor driven by bipolar pulsed power

A silent discharge reactor initiated by bipolar pulsed power substituting the traditional ac power was used to remove the volatile organic compounds (VOC_s) mixture of acetone, benzene, tetrachloroethylene and m-xylene. The results indicated that the silent discharge driven by bipolar pulsed power could effectively input pulsed energy, produce strong instant discharge and energetic particles, and thus enhance the removal efficiency of the mixed VOC_s. The order of the removal efficiency of mixed VOC_s followed as acetone < benzene < tetrachloroethylene < m-xylene no matter what power supply was used. Comparing with single-compound, the removal efficiency of m-xylene only fell a little but those of the other three components fell a lot in the process of the mixed VOC_s treatment. In addition, controlling the status of electrical discharge plasma by changing the discharge parameters (such as capacitance of the pulse capacitor and pulse repetitive rate) was found to be an efficient way to enhance the removal efficiency of the mixed VOC_s. In this system, the Cp = 2 nF was the optimal capacitance for the bipolar power supply combined with the silent discharge reactor that had the best energy conversion efficiency for removal of mixed VOC_s. A higher pulse repetitive rate and longer residence time could also increase the removal efficiency of mixed VOC_s.     

High speed ultra short pulse fiber ring laser using photonic crystal fiber nonlinear optical loop mirror

A scheme to generate high speed optical pulse train with ultra short pulse width is proposed and experimentally studied. Two-step compression is used in the scheme: 20 GHz and 40 GHz pulse trains generated from a rational harmonic actively mode-locked fiber ring laser is compressed to a full width at half-maximum (FWHM) of ~ 1.5 ps using adiabatic soliton compression with dispersion shifted fibers (DSF). The pulse trains then undergo a pedestal removal process by transmission through a cascaded two photonic crystal fiber (PCF)-nonlinear optical loop mirrors (NOLM) realized using a double-ring structure. The shortest output pulse width obtained was ~ 610 fs for 20 GHz pulse train and ~ 570 fs for 40 GHz pulse train. The signal to noise ratio of the RF spectrum of the output pulse train is larger than 30 dB. Theoretical simulation of the NOLM transmission is conducted using split-step Fourier method. The results show that two cascaded NOLMs can improve the compression result compared to that for a single NOLM transmission.