Self-diffusion in simple models: Systems with long-range jumps

We review some exact results for the motion of a tagged particle in simple models. Then, we study the density dependence of the self-diffusion coefficientD _N() in lattice systems with simple symmetric exclusion in which the particles can jump, with equal rates, to a set ofN neighboring sites. We obtain positive upper and lower bounds onF _N()=N{(1–)–[D_N()/D_N(0)]}/[(1–)]x for [0, 1]. Computer simulations for the square, triangular, and one-dimensional lattices suggest thatF _N becomes effectively independent ofN forN20.     

The role of the distribution of nucleons in finite nuclei

The total energy of many-nucleon system is expressed as a functional E[ _p(r), _n(r)] of the proton and neutron densities _p(r) and _n(r), respectively. The distribution(r) of nucleons in the nucleus, which is essential to determine the energy functional, is chosen. The energy density formalism is applied to finite nuclei, and then the binding energies per nucleon together with the mean square radii, for some medium and heavy nuclei, are obtained. Finally the achieved results are compared with the corresponding experimental values.     

On the relative entropy

ForA any subset of () (the bounded operators on a Hilbert space) containing the unit, and and restrictions of states on () toA, ent _A (|)—the entropy of relative to given the information inA—is defined and given an axiomatic characterisation. It is compared with ent _A ^A (|)—the relative entropy introduced by Umegaki and generalised by various authors—which is defined only forA an algebra. It is proved that ent and ent ^S agree on pairs of normal states on an injective von Neumann algebra. It is also proved that ent always has all the most important properties known for ent ^S : monotonicity, concavity,w* upper semicontinuity, etc.     

Growth of correlation in the Hopfield model

Introducing a finite correlation ₀ between any two learned patterns (others remaining uncorrelated), we observe in a numerical simulation that the Hopfield model stores these two patterns with correlation _f such that _f0 for any loading capacity. The patterns are memorized perfectly (with _f= ₀) up to -0.05 for finite correlations ₀ not exceeding a value _c(), where _c() decreases continuously to zero at -0.05.     

Spatial structure in diffusion-limited two-particle reactions

We analyze the limiting behavior of the densities _A(t) and _B(t), and the random spatial structure(r) = ( _A(t)., _B(t)), for the diffusion-controlled chemical reaction A+Binert. For equal initial densities _B(0) = _b(0) there is a change in behavior fromd 4, where _A(t) = _B(t) C/t^d/4, tod 4, where _A(t) = _b(t) C/t ast ; the termC depends on the initial densities and changes withd. There is a corresponding change in the spatial structure. Ind < 4, the particle types separate with only one type present locally, and , after suitable rescaling, tends to a random Gaussian process. Ind >4, both particle types are, after large times, present locally in concentrations not depending on type or location. Ind=4, both particle types are present locally, but with random concentrations, and the process tends to a limit.     

Metastable states in the van der Waals-Maxwell theory

A slight modification of the recent Penrose and Lebowitz treatment of thermodynamic metastable states is presented. For the case of periodic boundary conditions, this modification allows the condition of metastability to be extended to all the metastable states in the van der Waals-Maxwell theory of the liquid-vapor phase transition, that is, for all states satisfyingf ₀()+1/2 ²>f(, 0+) andf₀()+x>0 wheref(, 0+) is the (stable) Helmholtz free energy density of the generalized van der Waals-Maxwell theory andf ₀() is the Helmholtz free energy density of a reference system with no long-range interaction, is a mean field-type term arising from a long-range Kac interaction, is the overall mean particle density, andx is any positive number. For the case of rigid-wall boundary conditions, a more restrictive condition is placed onx.     

Hydrogenated and irradiatedA15 Nb3Sn layers — Preparation,Rutherford scattering analysis,resistivity and superconductivity

Niobium films on sapphire were reacted in tin-vapour to Nb₃Sn with resistance ratiosR(297 K)/R(18.3 K) up to 6 and resistively measured superconducting transition temperaturesT _c up to 17.93 K. The composition Nb_3+z Sn_1–z H _x of electrolytically hydrogenated samples was determined depth dependent by Rutherford backscattering of 30 MeV³²S and simultaneous detection of recoiled protons. Considerable concentration gradients in the thin layers (0.27 m) were detected. The increase of resistivity with hydrogen content and the change in the temperature dependence of is analyzed. A correlation betweenT _c and ₀= is found: An increase of T _c =0.2 K at ₀25cm andx0.03 is followed by a drastic decrease toT _c <1.1 K at ₀80cm andx1. TheT _c vs. ₀ andT _c vs. (T) characteristic correlations are different from universal irradiation or preparation induced correlations. The discrepancies can be interpreted by a stiffening of phonon modes and a band-shifting caused by the hydrogen.     

On Strong Superadditivity of the Entanglement of Formation

We employ a basic formalism from convex analysis to show a simple relation between the entanglement of formation E_F and the conjugate function E^* of the entanglement function E()=S(Tr_A). We then consider the conjectured strong superadditivity of the entanglement of formation E_F()E_F(_I)+E_F(_II), where _I and _II are the reductions of to the different Hilbert space copies, and prove that it is equivalent with subadditivity of E^*. Furthermore, we show that strong superadditivity would follow from multiplicativity of the maximal channel output purity for quantum filtering operations, when purity is measured by Schatten p-norms for p tending to 1.     

Hall effect in heterogeneous Fe-Ni vacuum condensates

The temperature dependence of the electric conductivity and the Hall and Nernst-Ettinghausen effects of amorphous and microcrystalline Fe-Ni films obtained by ion-plasma sputtering, with a content of technological impurities of about 3 at. %, was studied for the first time. The relationship R_a(T) a²(T), was found between the anomalous Hall constant R_a and . R_a was found to be more sensitive to peculiarities of the complex transformation amorphous, microheterogeneous-crystalline state.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 29–33, September, 1990.     

Sum rules for the one-component plasma with additional short-range forces

It is proved that, in the one-component plasma, with interactions including a non-Coulombic short-range part, the density derivative of the correlation functions _n (r ₁,,r _n) can be simply expressed as an integral of _n+1(r ₁,,r _n+1). This result is applied to prove the relation between the fourth moment of ₂ and the compressibility.     

Anisotropy of the low temperature resistivity of hexagonal single crystalline spin glass systems

The impurity contribution to the resistivity in zero field (T) of dilute hexagonal single crystals of ZnMn, CdMn and MgMn has been studied in the mK range on samples cut parallel () and perpendicular () to thec-axis, using a SQUID technique for the measurements. Typical spin glass behavior is found in (T) as well as (T) for all alloys, with Kondo like logarithmic increases at higher temperatures and maxima atT _m at lower temperatures, indicating the influence of impurity interactions. The differences in the corresponding isotropic resistivity _poly(T) between the three systems can qualitatively be understood within the framework of a theoretical model by Larsen, describing (T) as a function of universal quantitiesT/T _K and _RKKY/T _K , where _RKKY is the RKKY-interaction strength andT _K the Kondo temperature. With respect to the two lattice directions studied, the behavior of (T and (T is anisotropic in the Kondo regime as well as in the range where ordering becomes important. While the anisotropy in the Kondo slope can be understood by an anisotropic unitarity limit, the understanding of the anisotropy in region where impurity interactions are important remains problematic.Dedicated to Prof. Dr. S. Methfessel on the occasion of his 60th birthday     

Analytical properties of mean two-particle density matrix

The analytical properties of the mean two-particle density matrixZ(t)=d R ₁ d R ₂ <_c(R ₁:R ₂;t)(R ₁,R ₂;t)> in the right-hand halfplane of the complex variable t is considered; herec,v(R₁,R ₂; t) are single-particle density matrices. It is proven that, in the case of a Gaussian field, the function Z(t) is analytical in the region Ret > 0. It is shown that the frequency dependence of the light-absorption coefficient in disordered semiconductors is determined by the asymptote of the function Z(t) as t.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 46–50, June, 1987.     

Relative change of the electron density at the Cu nucleus in Cu-Ag alloys

The decay constant of⁶⁴Cu in Cu–Ag solid solutions has been measured at various Cu concentrations. Deduced values of the relative changes of electron densities (0)/(0) at the Cu nucleus are given. The observed concentration dependence of (0)/(0) is discussed in terms of a volume effect and charge transfer from Cu to Ag.     

Theory of percolation in fluids of long molecules

We use the reference interaction site model (RISM) integral equation theory to study the percolation behavior of fluids composed of long molecules. We examine the roles of hard core size and of length-to-width ratio on the percolation threshold. The critical density _c is a nonmonotonic function of these parameters exhibiting competition of different effects. Comparisons with Monte Carlo calculations of others are reasonably good. For critical exponents, the theory yields =2=2 for molecules of any noninfinite lengthL. WhenL is very large, the theory yields _cL ^–2. These predictions compare favorably with observations of the conductivity for random assemblies of conductive fibers. The threshold region where asymptotic scaling holds requires the correlation length (/ _c ) ^–v to be much larger thanL. Evidently, the range of densities in this region diminishes asL increases, requiring that density deviations from _c be no larger thanL ^–2. Otherwise, crossover behavior will be observed.     

Behavior of the electrical resistivity at phase transitions in binary alloys

The excess resistivity of binary alloys is calculated in the Born approximation for the scattering of quasifree electrons from the atomic disorder. can be represented as the convolution of the structure functionS(q) and the fourier transform of the effective potential. The critical anomaly of is derived from scaling expressions forS(q), both for alloys which undergo unmixing and for order-disorder transitions. The variation of with concentration and temperature in the vicinity of a critical point is obtained. The time-dependence of the resistivity of alloys after a sudden quench into the two-phase region is also calculated, using computer simulation data forS(q,t), and a maximum of is found for zones with linear dimension of 8–12 lattice spacings. All these results are in fair agreement with the available experiments. As a further possible application, we obtain the critical exponent for the nonlinear relaxation of the resistivity of an alloy close to the order-disorder transition.     

Electron-electron interaction and magnon scattering in the d-electron dominated resistivity of Ni80−xFe x Si8B12 glasses

Our investigation of the electrical resistivity (T) betweenT=0.1 K and 295 K revealed for all Fe-concentrations, 2.4x16, a minimum of betweenT _min=7 K and 15 K. Above the minimum, scattering from structural disorder prevails in the paramagnetic alloy (x=2.4), while in the ferromagnetic glasses (x5.6) coherent magnon scattering appears to dominate. With one exception, (TT _min) increases as down to the lowest temperatures for all investigated Fe-contents (x10.4) in zero magnetic field as well as in applied 6 T. The value of the slopes, 6.3(6) ( cm)^–1 K^–1/2, agrees with the universal scaling behaviour reported recently by Cochrane and Strom-Olsen for systems with strong electron-electron interaction. A large, linear rise of (T<T _min,B=0) observed in the most diluted sample (x=2.4) is tentatively attributed to quantum localization in the non-reentrant spin glass phase. The magnitude of the temperature effects on (T) above as well as belowT _min indicates significantd-band contributions to the conductivity.     

Study ofA+A→0 with probability of reaction and diffusion in one dimension and in fractal substrata

We present Monte Carlo simulations of annihilation reactionA+A0 in one dimensional lattice and in three different fractal substrata. In the model, the particles diffuse independently and when two of them attempt to occupy the same substratum site, they react with a probabilityp. For different kinds of initial distributions and in the short an intermediate time regimes, the results for 0<p1 show that the density ofA particles approximately behaves as (t)=(t=0)f(t/t ₀), with the scaling functionf(x)1 forx1,f(x)x ^–y forx1. The crossover timet ₀, behaves ast _{0 0eff} ^–1y where theeffective initial density _0eff depends on (t=0) and on the kind of initial distribution. For a given substratum of spreading dimensiond _s, the exponenty(d _s/2<y<1) depends only onp and its value increases asp decreases (y1 whenp0). In the very long time regime it is expected thatp(t)t ^–ds/2 independently ofp.     

Determination of the electron density at the Cu nucleus in Cu-Au alloys

The half-life of⁶⁴Cu in Cu–Au solid solutions has been measured as a function of the Cu concentration. Relative changes of electron densities (0)/(0) at the Cu nucleus are deduced. The observed nonlinear concentration dependence of (0)/(0) is discussed in terms of volume and charge transfer effects.     

On the equivalence of boundary conditions

We show that ifb andb are two boundary conditions (b.c.) for general spin systems on ^d such that the difference in the energies of a spin configuration in ^d is uniformly bounded, |H _,b ()–H _,b()|C < , then any infinite-volume Gibbs states and obtained with these b.c. have the same measure-zero sets. This implies that the decompositions of and into extremal Gibbs states are equivalent (mutually absolutely continuous). In particular, if is extremal,=. Application of this observation yields in an easy way (among other things) (a) the uniqueness of the Gibbs states for one-dimensional systems with forces that are not too long-range; (b) the fact that various b.c. that are natural candidates for producing non-translation-invariant Gibbs states cannot lead to such an extremal Gibbs state in two dimensions.Supported in part by NSF Grant PHY 78–15920 and by the Swiss National Foundation For Scientific Research.     

Generalized Stefan-Boltzmann law

Thermodynamics arguments have been employed to derive how the energy density depends on the temperatureT for a fluid whose pressurep obeys the equation of statep = ( –1), where is a constant. Three different methods, among them the one considered by Boltzmann (Carnot cycle), lead to the expression = T/( –1), where is a constant. This result also appears naturally in the framework of general relativity for spacetimes with constant spatial curvature. Some particular cases are vacuum (p = –), cosmic strings (p= –1/3), radiation (p = 1/3), and stiff matter (p = ). It is also shown that such results can be adapted for blackbody radiation inN spatial dimensions.