共查询到20条相似文献,搜索用时 109 毫秒
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聚乙烯二茂铁修饰电极测定抗坏血酸 总被引:1,自引:1,他引:0
化学修饰电极是近几年来活跃于电化学及电分析化学领域的一个新的研究课题,成功地应用于表面配位化学、光电转化、表面催化反应及痕量元素检测等方面。具有电活性的聚乙烯二茂铁修饰电极对抗坏血酸的氧化有催化作用。 相似文献
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功能聚吡咯膜修饰电极的制备及其应用 总被引:2,自引:0,他引:2
本文对功能聚吡咯膜修饰电极的制备及其在电化学催化、电化学释放、分子器件、电变色效应、生物传感器以及电化学分析等方面的应用进行了综述,引参考文献五十篇。 相似文献
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B. ?ljuki? I. Stojkovi? N. Cvijeti?anin G. ?iri?-Marjanovi? 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2011,85(13):2406-2409
Manganese dioxide modified carbonized nanostructured polyaniline (MnO2/Carb-nanoPANI) was prepared via a novel hydrothermal procedure. The synthesized material was characterized using XRD, SEM
and TG-DTA analysis. Furthermore, MnO2/Carb-nanoPANI was examined as electrode material for potential application in the field of electroanalysis. It showed a high
electrocatalytic activity for the sensing of hydrogen peroxide in an aqueous media. 相似文献
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Modified electrodes have been popularly used in electroanalysis. Chemically stripping analysis (CSA) with modified electrodes, however, was few in past years⑴.In this paper, we present a new method for determination of copper, chemically stripping analysis with glutathione modified graphite paste electrode (GMGPE). 相似文献
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《Electroanalysis》2005,17(3):263-268
In this paper it is shown that the charge transfer kinetics of the oxidation of sodium dithionite at a gold electrode in alkaline solution can be increased by modifying this electrode with cobalt(II)tetrasulfonated phthalocyanine, sodium salt (CoTSPc) or 5,10,15,20‐tetrakis‐(4‐sulfonatophenyl)porphyrin cobalt(II), tetrasodium salt (CoTSPor). Electrodeposition of these catalysts is discussed as well as the oxidation of sodium dithionite at these immobilized catalysts. Despite an observed acceleration in the charge transfer kinetics, sodium dithionite is still oxidized irreversibly. However, the improvement in kinetics has beneficial consequences in the field of electroanalysis of sodium dithionite. Comparison of the oxidation at bare gold and modified gold electrodes showed that with improved charge transfer kinetics at the modified electrodes a higher sensitivity and selectivity and a much lower detection limit is obtained. 相似文献
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Haniyeh Fayazfar Abdollah Afshar Abolghasem Dolati 《Applied biochemistry and biotechnology》2014,173(6):1511-1528
Carbon nanotube/nanoparticle hybrid materials have been proven to exhibit high electrocatalytic activity suggesting broad potential applications in the field of electroanalysis. For the first time, modification of Ta electrode with aligned multi-walled carbon nanotubes/Au nanoparticles introduced for the sensitive determination of the antibiotic drug, cefazolin (CFZ). The electrochemical response characteristics of the modified electrode toward CFZ were investigated by means of cyclic and linear sweep voltammetry. The modified electrode showed an efficient catalytic activity for the reduction of CFZ, leading to a remarkable decrease in reduction overpotential and a significant increase of peak current. Under optimum conditions, the highly sensitive modified electrode showed a wide linear range from 50 pM to 50 μM with a sufficiently low detection limit of 1?±?0.01 pM (S/N?=?3). The results indicated that the prepared electrode presents suitable characteristics in terms of sensitivity (458.2?±?2.6 μAcm?2/μM), accuracy, repeatability (RSD of 1.8 %), reproducibility (RSD of 2.9 %), stability (14 days), and good catalytic activity in physiological conditions. The method was successfully applied for accurate determination of trace amounts of CFZ in pharmaceutical and clinical preparations without the necessity for samples pretreatment or any time-consuming extraction or evaporation steps prior to the analysis. 相似文献
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《Electrochemistry communications》2000,2(4):226-229
Monomolecular level modification of electrode surfaces through a self-assembly approach is, of late, gaining importance in view of its many functional applications in areas such as molecular electronics, molecular recognition, electron transfer studies and electroanalysis. Self-assembled monolayer (SAM) modification of a gold electrode with 2-mercaptobenzimidazole (MBI) has been achieved. On this modified electrode, anodic stripping voltammetric determination of mercury at ppm/sub-ppm level concentrations has been successfully attempted. Pre-concentration, prior to stripping, has been effected through a non-electrolytic process involving chemical interactions between MBI and Hg(II). The results are described and discussed with a plausible scheme. 相似文献
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A conducting polymer modified electrode based on the incorporation of 4,5-dihydroxy-3-(p-sulfophenylazo)-2,7-naphthalene disulfonic acid, SPADNS, as an anionic complexing ligand into polypyrrole film during electropolymerization was prepared. The electroanalysis of copper(II) in this modified electrode was achieved by medium exchange and differential pulse voltammetry. Copper ions were accumulated from ammonia buffer on the electrode surface by the formation of a chemical complex at open circuit. The resulting electrode with complexed Cu(2+) was then transferred to an acetate buffer and subjected to anodic stripping voltammetry. The analytical performance was evaluated and, finally, linear calibration graphs were obtained in the concentration range of 2 - 250 ng ml(-1) for Cu(II). The detection limit was found to be 1.1 ng ml(-1) and RSD was obtained at 3.1 and 1.9% for two different concentrations. Many coexisting metal ions had little or no effect on the determination of copper. The developed method was applied to Cu(II) determination in natural water and human hair samples. Also, the rapid and convenient regeneration of electrode allows the use of a single modified electrode in multiple analyses. 相似文献
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Electroanalytical Applications of Microporous Zeolites and Mesoporous (Organo)Silicas: Recent Trends
Alain Walcarius 《Electroanalysis》2008,20(7):711-738
Microporous zeolites and ordered mesoporous (organo)silicas have been widely used as electrode modifiers because of their attractive properties (ion exchange and size selectivity of zeolites, well ordered nanoreactors containing a high number of widely accessible active centers in mesoporous (organo)silicas). These properties have been intelligently combined to selected redox processes to improve the response of the resulting modified electrodes or to design novel electrochemical detection schemes. This up‐to‐date review provides the recent advances made in the electroanalytical applications of zeolite modified electrodes and discusses the interest of ordered mesoporous (organo)silica materials in electroanalysis. 相似文献
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Functionalized Carbon Nanoparticles,Blacks and Soots as Electron‐Transfer Building Blocks and Conduits 下载免费PDF全文
Dr. Katherine Lawrence Charlotte L. Baker Prof. Tony D. James Dr. Steven D. Bull Dr. Ruth Lawrence Dr. John M. Mitchels Prof. Marcin Opallo Prof. Omotayo A. Arotiba Prof. Kenneth I. Ozoemena Prof. Frank Marken 《化学:亚洲杂志》2014,9(5):1226-1241
Functionalized carbon nanoparticles (or blacks) have promise as novel active high‐surface‐area electrode materials, as conduits for electrons to enzymes or connections through lipid films, or as nano‐building blocks in electroanalysis. With previous applications of bare nanoblacks and composites mainly in electrochemical charge storage and as substrates in fuel cell devices, the full range of benefits of bare and functionalized carbon nanoparticles in assemblies and composite (bio)electrodes is still emerging. Carbon nanoparticles are readily surface‐modified, functionalized, embedded, or assembled into nanostructures, employed in bioelectrochemical systems, and incorporated into novel electrochemical sensing devices. This focus review summarizes aspects of a rapidly growing field and some of the recent developments in carbon nanoparticle functionalization with potential applications in (bio)electrochemical, photoelectrochemical, and electroanalytical processes. 相似文献
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Dr. Süleyman Koçak 《Electroanalysis》2021,33(2):375-382
A new electrochemical sensor based on Poly(Isoleucine) modified glassy carbon electrode decorated with platinum nanoparticles (Pt/Poly(Isoleucine)/GCE) was developed for sensitive individual and simultaneous determination of hydroquinone (HQ) and catechol (CC). Scanning electron microscopy (SEM), Electrochemical impedance spectroscopy (EIS), Cyclic voltammetry (CV) and Differential pulse voltammetry (DPV) were performed in order to characterize the Pt/Poly(Isoleucine)/GCE nanocomposite. For simultaneous determination of HQ and CC, Pt/Poly(Isoleucine)/GCE showed wide linear range between the 0.01–100.0 μM. The detection limits were 0.006 μM for HQ and 0.005 μM for CC. The Pt/Poly(Isoleucine)/GC electrode exhibited good sensitivity and reliability in the simultaneous electroanalysis of two isomers in PBS of pH 7.5. The modified electrode was used to detect the isomers in naturel samples. 相似文献