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1.
本文使用代数方法(AM),研究了N_2分子的X~1∑_g~+、A~3∑_u~+、B~(′3)∑_u~-、a′~1∑_u~-、b′~1∑_u~+、B~3∏_g、c′_4~1∑_u~+等七个电子态的离解能;然后使用新公式计算了这些电子态的离解能,并分别与离解能的实验值进行了分析对比.结果表明:使用新公式得到的分子离解能与离解能的实验值更为接近.对于那些用实验方法还难以获得其离解能的电子态,该式提供了一种获得其离解能的新途径.  相似文献   

2.
本文使用代数方法(AM),研究了N_2分子的X~1∑_g~+、A~3∑_u~+、B~(′3)∑_u~-、a′~1∑_u~-、b′~1∑_u~+、B~3∏_g、c′_4~1∑_u~+等七个电子态的离解能;然后使用新公式计算了这些电子态的离解能,并分别与离解能的实验值进行了分析对比.结果表明:使用新公式得到的分子离解能与离解能的实验值更为接近.对于那些用实验方法还难以获得其离解能的电子态,该式提供了一种获得其离解能的新途径.  相似文献   

3.
本文使用代数方法(AM),研究了N_2分子的X~1∑~+_g、A~3∑~+_u、B~(′3)∑~-_u、a′~1∑~-_u、b′~1∑~+_u、B~3∏_g、c′_4~1∑~+_u等七个电子态的离解能;然后使用新公式计算了这些电子态的离解能,并分别与离解能的实验值进行了分析对比.结果表明:使用新公式得到的分子离解能与离解能的实验值更为接近.对于那些用实验方法还难以获得其离解能的电子态,该式提供了一种获得其离解能的新途径.  相似文献   

4.
本文使用孙卫国等人提出的基于微扰理论的代数方法(AM),研究了碱金属K2分子的五个电子态X1g+、a3u+、Og-、B1u和33g的离解能;然后使用作者最近提出的新公式计算了这些电子态的离解能,并分别与实验值进行了比较.计算结果表明:使用新公式得到的分子离解能与实验值非常吻合.而对那些还没有离解能实验数据的电子态,该公式提供了一种推测其离解能的理论计算方法.  相似文献   

5.
本文使用基于微扰理论的代数方法(AM),研究了双原子离子F2+的X2Ⅱg,CO+的X2∑+,O2+的A2Ⅱu,BeH+的X1∑+四个电子态的离解能,然后使用最近提出的新公式计算了这些电子态的离解能,并分别与离解能的实验值进行了比较.研究结果表明:使用新公式得到的分子离解能与实验值更加接近;同时AM和新公式相结合的理论方法也适用于双原子离子体系.  相似文献   

6.
本文使用孙卫国提出的基于微扰理论的代数方法(AM),研究了双原子离子F2+的X2Πg,CO + 的X2Σ+, O2+的A2Πu ,BeH +的X1Σ+ 四个电子态的离解能,然后使用最近提出的新公式计算了这些电子态的离解能,并分别与离解能的实验值进行了比较.研究结果表明:使用新公式得到的分子离解能与实验值更加接近;同时AM和新公式相结合的理论方法也适用于双原子离子体系。  相似文献   

7.
文章使用孙卫国等人提出的基于微扰理论的代数方法(AM),研究了碱金属K2分子的 、 、 、 、 等五个电子态的离解能;然后使用作者最近提出的新公式计算了这些电子态的离解能,并分别与实验值进行了比较.计算结果表明:使用新公式得到的分子离解能与实验值非常吻合.而对那些还没有离解能实验数据的电子态,该式提供了一种获得其离解能的理论计算方法.  相似文献   

8.
NaRb分子部分电子态的完全振动能谱与离解能的精确研究   总被引:1,自引:1,他引:0  
本文应用孙卫国等最近建立的代数方法(AM)和精确计算双原子分子离解能的新解析表达式研究了NaRb分子的X1∑ ,(1)3∑ 和a3∑ 电子态的完全振动能谱和离解能.得到的完全振动能谱既重复了已知的实验能级,又给出了尚没有实验数据的高振动激发能级的正确数值,获得的各电子态离解能精确地符合实验值.这些结果为需要NaRb分子的精确振动能谱和离解能的科学研究提供了重要的数据.  相似文献   

9.
NiCO分子结构与解析势能函数   总被引:1,自引:1,他引:0       下载免费PDF全文
用密度泛函理论的B3P86方法,对镍原子采用LANL2DZ收缩价基,碳原子和氧原子采用6-311+G~*基组,对NiC、NiO和NiCO体系的结构进行优化,计算表明:NiC分子基态为~1∑~+态,键长为R_e=0.16070 nm,离解能为3.62948 eV.NiO分子基态的平衡核间距为0.16784 nm,其电子态为~3∑~-,离解能为3.45119 eV,拟合得到Murrell-Sorbie势能函数;NiCO分子有两个线性稳定构型,其中一个构型为Ni—C≡O(C_(∞υ)),电子态为~1∑~+,平衡核间距为R_(NiC)=0.16621 nm,R_(co)=0.11519 nm,离解能为12.80476 eV,另一个为Ni—O≡C(C_(∞υ)),电子态是~1∑~+,平衡核间距为R_(co)=0.11470 nm,R_(NiO)=0.17636 nm,离解能为11.24679 eV.由微观过程的可逆性原理分析了分子的可能的离解极限,并用多体展式理论导出基态NiCO分子的势能函数,其等势面图准确地再现了NiCO分子的结构特征和离解能,由此讨论了Ni+CO,NiC+O,NiO+C分子反应的势能面静态特征.  相似文献   

10.
在LeRoy与Bernstein的工作基础上,孙卫国等又建立了精确计算双原子分子离解能的新解析表达式.基于代数方法(AM)可以获得双原子分子的包含最高振动能级在内的所有高阶振动能级的精确数值这一事实,应用新公式研究了7LiD分子C1∑ 电子态的振动能谱和分子离解能,获得了与实验值符合得非常好的理论结果.  相似文献   

11.
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs.  相似文献   

12.
A review of schemes for multiple access in fiber optic networks shows that a hybrid of wavelength and code division multiple access (WCDMA) combines the best features of both. In particular, the hybrid scheme retains the large information carrying capacity of wavelength division multiple access (WDMA) and flexibility of code division multiple access (CDMA). In this paper WDMA, optical CDMA (OCDMA), and WCDMA networks are discussed. In OCDMA networks, concept of incoherent and coherent coding including inverse decoding and matched filter is introduced. The delay performance of both WDMA and WCDMA networks, under the simple suboptimum access protocols based on cyclic search, is computed. It has been shown quantitatively that tuning delay significantly affects the delay performance of both WDMA and WCDMA networks. Futhermore, delay performance of WCDMA networks is always better than the WDMA networks for the same tuning delay, load, and number of users.  相似文献   

13.
A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output.  相似文献   

14.
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation (5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure crystals is analyzed (preliminarily). Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997.  相似文献   

15.
A multi-conjugate adaptive optics (MCAO) can offer a possibility of widening field of view (FOV) characterized by the isoplanatic angle, and the choose of conjugate height becomes a basic problem for MCAO, which influences the size of iosplanatic angle. Considering the application of lidar, the isoplanatic angle's expressions of two deformable mirrors (DMs) MCAO for uplink and downlink are deduced. The effects of conjugate heights for dual-conjugate AO are thoughtfully discussed, and the isoplanatic angles are further analyzed. The results show that the isopanatic angle varies with the conjugate height and reaches the maximum as the conjugate height is at the optimal altitude. Moreover, the optimal conjugate height changes with the propagation distance.  相似文献   

16.
Due to the limit of response speed of the present single-photon detector, the code rate is still too low to come into practical use for the present quantum key distribution (QKD) system.A new idea is put up to design a quick single-photon detector.This quick single-photon detector is composed of a multi-port optic-fiber splitter and many avalanche photo diodes (APDs).Au of the ports with APDs work on the time division and cooperate with a logic discriminating and deciding unit driven by the clock signal.The operation frequency lies on the number N of ports, and can reach N times of the conventional single-photon detector.The single-photon prompt detection can come true for high repetition-rate pulses.The applying of this detector will largely raise the code rate of the QKD, and boost the commercial use.  相似文献   

17.
18.
The performance of port/starboard discrimination of dual-line array will be seriously degraded when the space between the two line arrays of the dual-line array is mismatched. The directivity function of the delay-sum and delay-subtract beamforming is deduced and the port/starboard discrimination of the delay-sum and delay-subtract beamforming is also studied both under the ideal status and the status under which the space between the two line arrays of the dual-line array is mismatched. Analysis results show the delay-subtract beamforming has better performance of port/starboard discrimination. At last, the sea trial results demonstrate the theoretical results.  相似文献   

19.
The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper.  相似文献   

20.
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