Changes in the optical properties of as-deposited plasma polymerized 2,6-diethylaniline thin films by iodine doping

In this study, plasma polymerized 2, 6-diethylaniline (PPDEA) thin films of different thicknesses were synthesized using a glow discharge plasma polymerization method. Scanning electron microscopy showed that the surface morphology of an as-deposited PPDEA thin film was comparatively smooth after iodine doping. The iodine-doped PPDEA was found to be thermally stable up to ca about 560 K, which was slightly lower than that observed for as-deposited PPDEA. Ultraviolet-visible spectroscopic analyses demonstrated that iodine doping resulted in a significant decrease in the optical energy gap. As the doping period increased, the direct optical transition energy gap was reduced from 3.56 to 2.79 eV and the indirect optical transition energy gap was decreased from 2.23 to 1.97 eV. Thus it is observed that, the optical parameters of as-deposited PPDEA thin films with different thicknesses can be modified with different iodine doping periods.     

锗硅合金半导体中无声子参与光跃迁机制研究

研究了Ｓｉ１－ｘＧｅｘ合金半导体中无声子参与光嗅迁的产机制，对由杂质无规分布引起的无声子参与光跃迁给出了一个物理模型。用此模型计算了光跃迁偶极矩，给出了跃迁偶极矩的上限。提出了未掺杂Ｓｉ１－ｘＧｅｘ合金半导体中无声子参与光跃迁的一种跃迁机制，认为是Ｇｅ原子周围波函数畸变的集体行为。     

Rosen--Zener Transition in a Nonlinear System for Two-Component Bose--Einstein Condensates in Optical Lattices

We study the Rosen-Zener transition （RZT） in a nonlinear system for two-component Bose-Einstein condensates in optical lattices. It is found that the percentage of the components could affect the quantum transition dramatically. For the component with large percentage it is equivalent that the effect of the nonlinearity is stronger, whereas for the component with small percentage the effect is weaker. We also find that the nonlinearity c11 can affect the quantum transition dramatically. This is similar to that reported from Ref. [14]. Compared with one-component systems, however, the effect of the nonlinearity is decreased due to the two components of the BEGs in optical lattices. Furthermore, the effect of the coupling nonlinearity between two components c12 is studied. The component with large percentage is more affected by the nonlinearity than that with small-percentage component.     

Shifting of transition temperature of ferroelectric liquid crystals due to addition of dye-An optical and dielectric study

In order to study the shifting of phase transition temperature of ferroelectric liquid crystals due to addition of dye molecules, we have investigated two ferroelectric liquid crystal materials (Felix 16/030 and Felix 16/100) and their five mixtures with Anthraquinone dye (1%, 2%, 3%, 4% and 5% wt/wt). The phase transition scheme has been investigated and analyzed by results obtained from the optical transmittance and the dielectric permittivity study with variation of temperature in the range of 30 to 100 °C. Both the samples clearly show the shifting of phase transition temperature with dye concentration, especially the SmC*-SmA phase transition temperature. It is also clear from the study that SmC*-SmA phase transition phenomenon also becomes stronger with the addition of dye molecules. A theoretical explanation has also been given for shifting of phase transition temperature. The amount of shift in transition temperature agrees well as obtained from optical and dielectric studies.     

Nanostructure model and optical properties of InAs/GaAs quantum dot in vertical cavity surface emitting lasers

We apply 8-band k.p model to study InAs/GaAs quantum dots (QDs). The strain was calculated using the valence force field (VFF) model which includes the four nearest-neighbour interactions. For the optical properties, we take into account both homogeneous and non-homogeneous broadening for the optical spectrum. Our simulation result is in good agreement with the experimental micro-photoluminescence (μ-PL) result which is from InAs/GaAs QD vertical cavity surface emitting lasers (VCSELs) structure wafer at room temperature. Accordingly, our simulation model is used to predict the QD emission from this QD-VCSELs structure wafer at different temperature ranging from 200–400 K. The simulation results show a decrease of 41 meV of QD ground state (GS) transition energy from 250–350 K. The changes of QDGS transition energy with different temperature indicate the possible detuning range for 1.3-μm wave band QD-VCSELs applications without temperature control. Furthermore, QD differential gain at 300 K is computed based on this model, which will be useful for predicting the intrinsic modulation characteristics of QD-VCSELs.     

Non-quantum liquefaction of coherent gases

We show that a gas-to-liquid phase transition at zero temperature may occur in a coherent gas of bosons in the presence of competing nonlinear effects. This situation can take place in atomic systems like Bose-Einstein condensates in alkali gases with two-body and three-body interactions of opposite signs, as well as in laser beams which propagate through optical media with Kerr (focusing) and higher order (defocusing) nonlinear responses. The liquefaction process takes place in the absence of any quantum effect and can be formulated in the framework of a mean field theory, in terms of the minimization of a thermodynamic potential. We study from a thermodynamic point of view all the stationary solutions of the cubic-quintic nonlinear Schrödinger equation which describes our system. We show that solitonic localized solutions connect the gaseous and liquid phases. Furthermore, we also perform a numerical simulation in the presence of linear gain and three-body recombination where a rich dynamics, including the emergence of self-organization behavior, is found.     

Manipulation of soliton ensembles by spectral filters

It was shown recently that an ensemble of solitons can be created in a driven optical fiber resonator. The ensemble can exist in either an ordered or a disordered state; these have been referred to as soliton solid or gas (fluid), respectively. We demonstrate through numerical simulation that the transition from one state to the other or vice versa, and further manipulation of the ensemble, can be effected through the insertion of spectral filters. Received: 7 July 2000 / Revised version: 1 September 2000 / Published online: 30 November 2000     

Investigation into defects occurring on the polymer surface during the photolithography process

With a view to improving the realisation of polymer optical waveguide some features relevant to the photolithography process are analysed. This paper focuses on defects that occur on the surface of polymer layers involved in the process. For example, depending on the heat treatment or the deposited material, some worm-like defects appear on the polymer surface. When they occur, the waveguide surface roughness becomes too high (about one hundred nm and more). This means that the optical performance of the waveguides is too poor. In this document, we show the changes in temperature on polymer film surfaces which are coated with a thin inorganic layer and the occurrence of these defects is observed. This work confirms that the defect occurrence is clearly linked to the glass transition temperature. The paper reports that, in some cases, the adjustment of thermal properties by annealing can advantageously shift the glass transition, without changing the target optical properties.     

Intersubband optical absorption coefficients and refractive index changes in a parabolic cylinder quantum dot

Optical absorption coefficients and refractive index changes associated with intersubband transition in a parabolic cylinder quantum dot are theoretically investigated. In this regard, the electronic structure of the dot is studied using the one band effective mass theory, and by means of the compact-density matrix approach the linear and nonlinear optical absorption coefficients and refractive index changes are calculated. The effects of the size of the dot, optical intensity and electromagnetic field polarization on the optical absorption coefficient and refractive index changes are investigated. It is found that absorption and refractive index changes are strongly affected not only by the size of the dot but also by optical intensity and the electromagnetic field polarization.     

Noise-Induced Phase Transition: Zero-Dimensional Brownian Particles Varying between Ergodicity and Nonergodicity

We study in phase space a zero-dimensional system of Brownian particles which move in a periodic potential and subject to an internal time derivative Ornstein-Uhlenbeck noise. To resolve the Fokker-Planck equation in such a case, we propose an approximate analytical method. The theoretical predictions exhibit a second order noise-induced nonequilibrium phase transition, which is confirmed by numerical simulation results. The phase transition brings the system from an ergodicity to a nonergodicity phase as the potential barrier height decreases.     

The ferroelastic transition of betaine borate

The ferroelastic transition of betaine borate at about 142 K and the nonlinear temperature dependence of the corresponding critical elastic modulus are related to the softening of optical phonons. The transition has to be considered a ferroelastic one of the optic type, i.e. pseudoproper one, therefore. It is shown by Raman spectroscopic results that the transition is induced by a strong bilinear coupling between a homogeneous strain and at least two optic lattice modes which are of the same symmetry as the strain. Optic and dielectric, investigations support the second-order character of and the classical behaviour at this transition, which have been reported in the literature. Differences and similarities to the ferroelastic transition of betaine fumarate are discussed.     

Effects of magnesium salt concentrations on B-DNA overstretching transition

In this study, we use optical tweezers to investigate the ionic effects of magnesium salt solutions on the overstretching transition of single B-DNA molecules. The experimental data are compared with those in sodium salt solutions. The overstretching transition force increases when the NaCl or MgCl₂ salt concentration increases. Magnesium cations have much stronger effects on the overstretching transition force than sodium cations. For both NaCl and MgCl₂ salt solutions, the overstretching transition force is linear with the natural logarithm of salt concentration, which confirms the theory proposed in previous paper. The modified ZZO model is applied to study the electrostatic contribution of magnesium salt solutions to the overstretching transition of single B-DNA molecules. The consistency between the experimental data and analytical results shows that the modified ZZO model can simulate the transition behavior of single B-DNA molecules in different NaCl and MgCl₂ salt solutions.     

Dynamic triggering of a spin-transition by a pulsed magnetic field

We report the first study of the effect of a high pulsed magnetic field on a spin transition complex in the solid state. The high spin fraction was determined by optical reflectivity. Sizeable effects are observed for the well-known spin transition solid Fe(Phen)₂(NCS)₂. In the hysteresis loop temperature range, an increase in the HS fraction is obtained, with an irreversible (reversible) character in the ascending (descending) branch of the loop. The time dependence of the HS fraction provides information on the kinetics of the spin-crossover process at the spin transition. Received 23 February 1999 and Received in final form 8 June 1999     

Dielectric critical behaviour at a metal-insulator transition under lattice compression

We study dielectric critical behaviour around a continuous metal-insulator transition in crystalline Cesium Iodide induced by changing the lattice parameter. The ab initio calculations of band structure and various quantities related to the dielectric response are performed in the transition region, within the local density approximation of the density functional theory. These calculations allow us to establish the power-law singularities of various quantities on two sides of the transition. The exponents obtained here are mean-field like due to the approximation in which interactions and disorder are treated. The critical behaviour is discussed by applying the scaling principle to the wavevector and frequency dependent dielectric function. We further investigate the effect of dielectric anomalies on optical properties by calculating the reflectance around transition region taking the ionic contribution to the dielectric function also into account. We find that the reflectance as a function of frequency shows very different kind of behaviour on both sides of the metal-insulator transition.     

Self-rotation of optical polarization in rubidium vapor

We present an experimental and theoretical study of self-rotation of optical polarization in a rubidium vapor.The atomic vapor is placed in a magnetic shielding cavity to suppress the Faraday rotation effect.In our experiment,Doppler-free spectroscopy configuration is used,and F = 2 → F ’ = 3 transition of 87Rb D2 line is chosen.We observe self-rotation of optical polarization effect at different pump light ellipticities.A theoretical analysis is then provided based on the experimental conditions.Theoretical simulation and experimental results are in good agreement.     

Analysis and Simulation of Adiabatic Bend Transitions in Optical Fibers

A low-loss criterion for bend transitions in optical fibers is proposed. An optical fiber can be tightly bent with low loss to be adiabatic for the fundamental mode, provided that an approximate upper bound on the rate of change of bend curvature for a given bend curvature is satistied. Two typical adiabatic bend transition paths, the optimum profile and linear protile, are analyzed and studied numerically. A realizable adiabatic transition with an Archimedean spiral profile is introduced for low bend loss in tightly bent optical fibers. Design of the transitions is based on modeling of the propagation and coupling characteristics of the core and cladding modes, which clearly illustrate the physical processes involved.     

The S-FFT calculation of Collins formula and its application in digital holography

We study analytically and numerically the properties of one-dimensional chain of cold ions placed in a periodic potential of optical lattice and global harmonic potential of a trap. In close similarity with the Frenkel-Kontorova model, a transition from sliding to pinned phase takes place with the increase of the optical lattice potential for the density of ions incommensurate with the lattice period. We show that at zero temperature the quantum fluctuations lead to a quantum phase transition and melting of pinned instanton glass phase at large values of dimensional Planck constant. After melting the ion chain can slide in an optical lattice. The obtained results are also relevant for a Wigner crystal placed in a periodic potential.     

Glass Transition Temperature of Water： from Simulations of Diffusion and Excess Entropy

We report a computer simulation study of the glass transition of water with SP2 potential. The temperature dependences of the diffusion coefficient and the excess entropy on cooling process are calculated. It is found that both the diffusion coefficient and the excess entropy show a break point at 160K. Our results support the viewpoint that the glass transition temperature is 160K. According to the calculated viscosity, we obtain a fragility index of water to be 326, which is much larger than the value accepted before.     

Ab initio calculations study of the electronic, optical and thermodynamic properties of NaMgH3, for hydrogen storage

The structural stability, electronic structure, optical and thermodynamic properties of NaMgH₃ have been investigated using the density functional theory. Good agreement is obtained for the bulk crystal structure using both the local density approximation (LDA) and the generalized gradient approximation (GGA) for the exchange-correlation energy. It is found from the electronic density of states (DOS) that the valence band is dominated by the hydrogen atoms while the conduction band is dominated by Na and Mg empty states. Also, the DOS reveals that NaMgH₃ is a large gap insulator with direct band gap 3.4 eV. We have investigated the optical response of NaMgH₃ in partial band to band contributions and the theoretical optical spectrum is presented and discussed in this study. Optical response calculation suggests that the imaginary part of dielectric function spectra is assigned to be the interband transition. The formation energy for NaMgH₃ is investigated along different reaction pathways. We compare and discuss our result with the measured and calculated enthalpies of formation found in the literature.     

Modeling and design of an optimized patterned electrode liquid crystal microlens array with dielectric slab

To eliminate the occurrence of disclination lines in the hole patterned electrode liquid crystal microlens array (LC MLA), inserting an ultrathin dielectric slab was proved to be an effective method. The thickness of the dielectric slab played an important role in effecting the optical performance of the liquid crystal microlens array device, including the dynamic focal range, focus diameter and symmetry of phase profile. In this paper, we studied the effect of dielectric slab thickness on the optical performance of the liquid crystal microlens array by numerical simulation. It is indicated that the optical performance of the device could be improved by reducing the dielectric slab thickness, assuming that the dielectric slab thickness was larger than the threshold thickness. The dependence of the threshold thickness on some key parameters was investigated and the associated effect on the optical performance by changing these key parameters was also studied. In the end, the approaches to enhance the optical performance, namely the dynamic focal range of the liquid crystal microlens array was proposed and proved to be in effect by numerical simulation results.