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1.
本文计算了Heusler合金Li2AlGa和Li2AlIn的晶格参数、体积模量、体积模量的一阶导数、 电子能带结构、声子色散曲线和声子态密度,并与密度泛函理论中的广义梯度近似计算结果进行比较. 计算的晶格参数与文献有很好的一致性. 两个Heusler合金的电子能带结构表明它们是半金属结构. 并利用声子色散曲线和声子密度图研究Heusler合金晶格动力学. Li2AlGa和Li2AlIn Heusler合金在基态呈现动力学稳定. 相似文献
2.
Summary The lattice dynamics of Li-intercalated FePS3 has been studied by means of a force constant model generated by a set of short-range two-body potentials. The intercalated
phases have been investigated for the three stoichiometric compositions: Li0.5FePS3, LiFePS3, Li1.5FePS3, with the aim of analysing the evolution of the host lattice normal modes as a function of the concentration, and of finding
the dispersion of the new phonon branches induced by lithium. The above special values of lithium concentration have been
chosen because the size of the unit cell keeps the same as in the host material. The force constants are fitted to the infrared
data and the phonon dispersion curves and the phonon energy densities have been calculated. A spectroscopic method for monitoring
lithium migration in the host material is proposed. 相似文献
3.
In this paper we present a microscopic model that allows us to study the effects of charge fluctuations on the phonon dispersion of the high-temperature superconductor YBa2Cu3O7 and its insulating counterpart, YBa2Cu3O6. An ab-initio rigid-ion model with pair potentials calculated by the Gordon-Kim method from the free-ion charge densities is used as a reference system. Starting from this reference system, charge fluctuations at the copper- and oxygen ions are introduced into the model. The charge fluctuations are treated as adiabatic degrees of freedom in a non-phenomenological way. The parameters entering the model are estimated consistently with the reference system from first principles rather than refering to the experimentally determined phonon dispersion. In addition to the metallic behavior (appropriate to YBa2Cu3O7) obtained in this way, insulating behavior (appropriate to YBa2Cu3O6) is simulated by requiring the polarizability function to fulfill a corresponding long. wavelength sum rule. Screened site-potential changes are defined that (besides the charge fluctuations) constitute a qualitative measure of the electron-phonon-interaction potential. Furthermore we investigate the long-wavelength limiting behavior of the most important quantities occurring in our formalism. We derive formulae that allow us to calculate the contribution of the charge fluctuations to the macroscopic dielectric constant and the transverse effective charges in the insulating phase. 相似文献
4.
Venu MankadHimadri R. Soni Sanjeev K. GuptaPrafulla K. Jha 《Physica B: Condensed Matter》2011,406(19):3599-3604
We present results of first principles total energy calculations of the structure, electronic and lattice dynamics for beryllium semiboride and its three ternary alloys using generalized gradient and local density approximations under the framework of density functional theory. The generalized gradient approximation is used for all compounds except MgBeB using the Perdew-Burke-Ernzehorf exchange correlation functional while local density approximations use the Perdew-Zunger ultrasoft exchange correlation functional. The calculated ground state structural parameters are in good agreement with those of experimental and previous theoretical studies. The electronic band structure calculations show that Be2B may transform to a semiconductor after Al substitution. A linear response approach to density functional theory is used to calculate phonon dispersion curves and vibrational density of states. The phonon dispersion curves of Be2B and AlBeB are positive indicating a dynamical stablility of the structure for these compounds. The phonon dispersion curves of NaBeB and MgBeB show the imaginary phonons throughout the Brillouin zone, which confirms dynamical instability as indicated in band structures for these alloys. We also present the partial phonon density of states for different species of Be2B and AlBeB to bring out the details of the participation of different atoms in the total phonon density of state, particularly the role played by Al atom. The first time calculated phonon properties are clearly able to bring out the significant effect of isoelectronic substitution in Be2B. 相似文献
5.
Renu Choithrani Mala N. RaoS.L. Chaplot N.K. GaurR.K. Singh 《Journal of magnetism and magnetic materials》2011,323(12):1627-1635
A shell model has been used to study the structure, phonon dynamics and phase coexistence of perovskite manganites RMnO3 (R=Tb, Dy, Ho). The calculated crystal structure, Raman and IR frequencies and specific heats are found to be in good agreement with the available experimental data. The phonon density of states, elastic constants, elastic stiffness, shear constants and phonon dispersion curves have been computed for these manganites. A zone center imaginary Au mode is revealed in these phonon dispersion curves, which indicates the occurrence of the metastability of the perovskite phase. The Gibbs free energy values calculated as a function of temperature and pressure for RMnO3 in the orthorhombic phase, when compared with those of the hexagonal phase, reveal the possibility of coexistence of these two phases in the present multiferroic manganites under ambient conditions. 相似文献
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7.
N. Kunitomi Y. Tsunoda N. Wakabayashi R.M. Nicklow H.G. Smith 《Solid State Communications》1978,25(11):921-924
The phonon dispersion relations of disordered alloys Ni1-xPtx were measured for five specimens covering the full range of atomic concentration by means of neutron inelastic scattering. At the resonant frequencies well separated double peak structures were observed in the phonon spectra. For the specimens with , the energy splitting of the phonon dispersion curve for the L-branch takes place at a higher frequency than that for the T-branch. The maximum phonon energy decreases with increasing Pt concentration but deviates from the theoretical prediction based on the mass defect CPA model. For x = 0.95 the localized mode cannot be observed as a well defined peak and does not seem to be split off from the main phonon band. 相似文献
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Mei Zhou Xiaobin Chen Gang Li Fawei Zheng Ping Zhang 《The European Physical Journal B - Condensed Matter and Complex Systems》2017,90(12):247
Accurate modeling of thermal properties is strikingly important for developing next-generation electronics with high performance. Many thermal properties are closely related to phonon dispersions, such as sound velocity. However, random substituted semiconductor alloys A x B1-x usually lack translational symmetry, and simulation with periodic boundary conditions often requires large supercells, which makes phonon dispersion highly folded and hardly comparable with experimental results. Here, we adopt a large supercell with randomly distributed A and B atoms to investigate substitution effect on the phonon dispersions of semiconductor alloys systematically by using phonon unfolding method [F. Zheng, P. Zhang, Comput. Mater. Sci. 125, 218 (2016)]. The results reveal the extent to which phonon band characteristics in (In,Ga)N and Ga(N,P) are preserved or lost at different compositions and q points. Generally, most characteristics of phonon dispersions can be preserved with indium substitution of gallium in GaN, while substitution of nitrogen with phosphorus strongly perturbs the phonon dispersion of GaN, showing a rapid disintegration of the Bloch characteristics of optical modes and introducing localized impurity modes. In addition, the sound velocities of both (In,Ga)N and Ga(N,P) display a nearly linear behavior as a function of substitution compositions. 相似文献
10.
C. Stassis C.-K. Loong J. Zarestky O.D. McMasters R.M. Nicklow 《Solid State Communications》1980,36(8):677-679
Inelastic neutron scattering techniques have been used to measure the phonon dispersion curves of CeSn3 and LaSn3. Close to the zone boundary in the [111] symmetry direction pronounced differences were observed between the measured phonon frequencies of these two compounds. 相似文献
11.
The low-temperature specific heat of freshly prepared and annealed amorphous alloys Zr70Be30, Zr67Cu33, and Zr75Rh25 has been investigated experimentally. The integral parameters of the electronic and phonon spectra have been determined:
the Sommerfeld coefficients and the Debye temperatures. Data from calorimetric and neutron experiments were compared on the
basis of the theory of lattices with off-diagonal disorder and localized modes. It is concluded that a local rearrangement
of the structure occurs in freshly prepared samples as the temperature decreases. A model of a bistable impurity configuration
is proposed to explain this restructuring.
Fiz. Tverd. Tela (St. Petersburg) 39, 145–152 (January 1997) 相似文献
12.
H. Khosroabadi A. Tavana M. Akhavan 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,51(2):161-165
Ab initio total energy calculations have been performed for superconducting
GdBa2Cu3O7 and insulating PrBa2Cu3O7 using the
full-potential linear augmented plane-wave method in the local density
approximation (LDA) and generalized gradient approximation (GGA). The
comparison of the calculated unit cell volume and lattice parameters with
the experimental data indicates the improvement of these parameters in the
GGA relative to LDA. LDA and GGA give the equilibrium unit cell volume about
6% smaller and 1.25% larger than the experimental data, respectively
for both systems. Thus frozen phonon calculations have been performed to
determine the eigenvalues and eigenvectors of the k=0 Ag modes of the
two systems in equilibrium structure have been obtained in GGA. The
calculated frequencies in the GGA are in good agreement with the other LDA
calculations for similar systems. Comparison of computational data with
experimental data indicates that calculations determine the frequencies
about ten percent below the experimental data. Even by improving LDA to GGA
in these calculations, the calculated phonon frequencies have remained
almost ten percent below the experimental data, even though the calculated
unit cell volumes are nearly equal to the experimental data. So, applying
GGA has not considerably decreased the difference between the computational
and experimental data. The effect of Pr doping on the eigenvalues and
eigenvectors have also been investigated. 相似文献
13.
High-temperature dispersion relations of the phonon modes in a cubic PbTiO3 single crystal have been investigated along the [ξ 0 0] and [ξ ξ 0] directions by inelastic neutron scattering. Above T c, the phonon dispersions are only temperature-dependent close to the Brillouin zone centre where the mode softening comes through. The measurements indicate large cubic anisotropy of the elastic tensor and relatively low anisotropy of the soft mode dispersion. The differences from an earlier inelastic neutron scattering study are discussed. 相似文献
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N. I. Kourov V. V. Marchenkov V. G. Pushin A. V. Korolev L. N. Buinova H. W. Weber 《Bulletin of the Russian Academy of Sciences: Physics》2008,72(8):1165-1168
The effect of atomic disordering and alloying with d elements (Fe, Pd, Cu) on the transport and magnetic properties of Cu3Pd alloys has been investigated at low temperatures (T < 80 K) in strong magnetic fields (H ≤ 8 MA/m). The specific features of the crystal structure and temperature and field dependences of the electrical resistance, magnetoresistance, Hall effect, and magnetic susceptibility of Cu72Pd28, Cu75Pd25, Cu80Pd20 and Cu74.5Pd24.5Fe1 alloys are discussed. 相似文献
16.
An ab initio pseudopotential plane wave method using linear response approach has been employed to study the lattice dynamics of two cubic antiperovskites AsNBa3 and SbNBa3. The bulk properties, elastic constants, phonon dispersion curves, phonon density of states and temperature dependent thermodynamic quantities of both antiperovskites are obtained. The calculated lattice constants, elastic and bulk properties are compared with the available theoretical data. This is the first systematic and quantitative prediction of phonon and thermodynamical properties of these antiperovskite compounds. 相似文献
17.
Nanocrystalline Fe-based alloys are interesting for their soft magnetic properties. Because these alloys are potentially applicable in outdoor-working components, their corrosion behaviour requires careful analysis. This work presents the results of the atmospheric corrosion tests in industrial and rural environments performed for up to 6 months. We compared the corrosion behaviour of two different compositions of NANOPERM-type alloys: Fe87.5Zr6.5B6 and Fe76Mo8Cu1B15 with classical FINEMET alloys of the nominal composition of Fe73.5Cu1Nb3Si13.5B9 type. The techniques of Mössbauer spectroscopy, conversion electron Mössbauer spectroscopy, X-ray diffraction and transmission electron microscopy have been employed to compare their corrosion rate, characterize corrosion products and inspect the structural changes of the nanocrystalline structure. It was found that the Si-containing FINEMET alloys are the most corrosion-resistant whereas worse corrosion properties were observed for molybdenum-containing Fe76Mo8Cu1B15 alloy. The corrosion product formed on the surface of NANOPERM-type alloys showed a needlelike morphology and a poor crystalline order and has been identified as lepidocrocite, γ-FeOOH. 相似文献
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19.
Wenlei Yu Meijie Han Kai Jiang Zhihua Duan Yawei Li Zhigao Hu Junhao Chu 《Journal of Raman spectroscopy : JRS》2013,44(1):142-146
Anomalous low temperature behaviors in cuprous oxide (Cu2O) film grown on quartz substrate have been investigated by temperature‐dependent Raman and transmittance spectra. The longitudinal optical components of two Γ15‐ phonon modes become sharper and more intense at a low temperature. It can be found that the highest‐order electronic transition located at 6.4 eV exhibits a minimum transmittance near 200 K. Correspondingly, the variations from phonon intensity ratios reveal obvious anomalies with the decreasing temperature, indicating the existence of strong electron–phonon coupling mediated by Fröhlich interaction in the Cu2O films below the temperature of 200 K. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
20.
利用X射线吸收精细结构(XAFS)方法研究机械合金化制备的Fe100-xCux(x=0,10,20,40,60,70,80,100,x为原子百分比)合金中Fe和Cu原子的局域环境结构.对于Fe100-xCux(x≥40)二元混合物,球磨160h后,Fe原子的近邻配位结构从bcc转变为fcc,但Cu原子的近邻结构保持其fcc不变.与之相反,在Fe80Cu20和Fe90Cu10(x≤20)合金中,Fe原子的近邻配位保持其bcc结构而Cu原子的近邻配位结构从fcc转变为bcc结构.XAFS结果还表明,fcc结构的Fe100-xCux样品中Fe的无序因子σ(0.0099nm)比bcc结构的Fe100-xCux中的σ(0.0081nm)大得多;并且在机械合金化Fe100-xCux(x≥40)样品中Fe原子的σ(0.0099nm)比其Cu原子的σ(0.0089nm)大.这表明机械合金化Fe100-xCux样品中Fe和Cu原子可以有相同的局域结构环境但不是均匀的过饱和固溶体,而是由Fe富集区和Cu富集区组成的合金.我们提出互扩散和诱导相变机理来解释在球磨过程中Fe100-xCux合金产生从bcc到fcc和从fcc到bcc变化的结构相变
关键词:
XAFS
100-xCux合金')" href="#">Fe100-xCux合金
机械合金化 相似文献