Computational Studies of Atmospheric-Pressure Methane–Hydrogen DC Micro Glow Discharges

Atmospheric-pressure methane–hydrogen micro glow discharges were computationally investigated using a 2-D hybrid model. The plasma model was solved simultaneously with a model for the external circuit. Simulations were conducted for a pin-to-plate electrode configuration with an interelectrode separation of 400 ${rm mu}hbox{m}$. The spatiotemporal evolutions of electrons, species densities, electric field, and electron and gas temperatures were studied. A total of 81 reactions were considered, which included electron–neutral, electron–ion, ion–neutral, and neutral–neutral reactions. An 84-step reaction mechanism consisting of 15 surface species and four deposited bulk species was considered. A time-stepping technique was employed to address the time scales of plasma transport (in microseconds) and neutral and fluid transport (in milliseconds) in 2-D simulations with detailed volume and surface chemistry. The simulations indicated $hbox{H}_{3}^{+}$ and $hbox{CH}_{5}^{+}$ ions to be the most prominent hydrogen and hydrocarbon ions. The gas temperature predictions suggested the discharge to be operating as a nonthermal glow discharge. The effect of discharge current on both plasma and deposition characteristics was studied. The simulations predicted a flat voltage–current characteristic, indicating the discharge to be operating in normal glow mode. The predicted voltage–current characteristic was found to be in favorable agreement with the experimental measurements. With an increase in discharge current, the deposition rate profile expanded in the lateral direction, suggesting that deposition occurred at the cathode spot.      

Numerical modeling of ozone production in a pulsed homogeneousdischarge: a parameter study

The pulsed volume discharge is an alternative for the efficient generation of ozone in compact systems. This paper presents a parameter study of the reactions in this kind of homogeneous discharge by using a numerical model which solves plasma chemical kinetic rate and energy equations. Simulations are performed for 10^-9-10^-5 s single pulses and oxygen gas density in the range 10<300 K and normalized electric field of 1000 decreased. The maximum concentration is 3% at 10 amagat and 100 K. The results on ozone accumulation in multiple pulse discharges are presented. In contrast to the single pulse case, higher efficiency is achieved at lower gas density. This scaling can be explained by losses due to ion currents     

Sustain Driving Method With High-Impedance State for Plasma Display Panel

A new sustain driving method with a high-impedance state for alternating current plasma display panels (ac PDP) is proposed. In this method, the voltage applied to scan and common electrodes of the ac PDP has three states during one sustain cycle, namely, positive-voltage, high-impedance, and negative-voltage states. The positive- and negative-voltage states occur alternately. The high-impedance state occurs between the positive- and negative-voltage states. During the positive and negative states, the glow discharge forms in the on-state cells, and the wall charges are accumulated on the dielectric layer. The high-impedance state is used to interrupt the current flow during the polarity change of the applied voltage and can suppress the loss of wall charges between adjacent gas discharges, thus improving the stability of the sustain discharge in the ac PDP. The experimental results on a 12-in PDP test panel show that the wall charges increase by 15% during the sustain period, the dynamic sustain voltage margin increases by 100%, and the brightness increases by 5%.      

Incomplete ozone recovery effect in the presence of active oxygen species

The degree of ozone recovery after pulsed UV laser photolysis of O₂-O₃-Ar mixture is measured using time-resolved absorption spectroscopy. The effect of incomplete ozone recovery in the presence of molecular singlet oxygen O₂(a ¹Δ) and atomic oxygen is detected. This effect is caused by the reaction between the vibrationally excited ozone molecule formed due to recombination and atomic oxygen. The branching factor for the chemical channel of reaction products is γ _r = 0.81 ± 0.13.     

Evolution law of Wigner function in laser process

Based on the density operator’s o perator-sum representation r ecently obtained by Fan and Hu for a laser process (Opt. Commun., 2008, 281: 5571; Opt. Commun., 2009, 282: 932; Phys. Lett. B, 2008, 22: 2435), we derive the evolution law of Wigner operator, the law is concisely expressed in the normally ordered formΔ(α,α*,t)=Tπ:exp?[-2T(a?e-(κ-g)t-α*)-(ae-(k-g)t-α)] :, where g and κ are the cavity gain and the loss, respectively, and T≡ (κ-g )(κ+g-2ge^{-2(κ-g) t})^-1. When t=0,Δ(α,α,t)→1π : exp?[-2(a?-α*)-(a-α)] :, which is the initial Wigner operator. Using this formalism the evolution law of Wigner functions in laser process can be directly obtained.     

On the entangled fractional squeezing transformation

We propose an entangled fractional squeezing transformation (EFrST) generated by using two mutually conjugate entangled state representations with the following operator: e-iα(a1?a2?+a1a2)eiπa2?a2; this transformation sharply contrasts the complex fractional Fourier transformation produced by using e-iα(a1?a2?+a2?a2)eiπa2?a2 (see Front. Phys. DOI 10.1007/s11467-014-0445-x). The EFrST is obtained by converting the triangular functions in the integration kernel of the usual fractional Fourier transformation into hyperbolic functions, i.e., tanα → tanhα and sinα → sinhα. The fractional property of the EFrST can be well described by virtue of the properties of the entangled state representations.     

Peakon, compacton and loop excitations with periodic behavior in KdV type models related to Schrödinger system

In this Letter, the linear variable separation approach is successfully extended to (1+1)-dimensional Korteweg–de Vries (KdV) type models related to Schrödinger system. Some significant types of solitons such as compacton, peakon and loop solutions with periodic behavior are simultaneously derived from the (1+1)-dimensional soliton system by entrancing appropriate piecewise smooth functions and multivalued functions.     

钽掺杂二氧化钛薄膜的光电性能研究

采用脉冲激光沉积法 (PLD), 以石英玻璃为衬底制备了钽掺杂TiO₂薄膜并研究了薄膜样品的光电性质. 沉积氧气分气压从0.3 Pa变化到0.7 Pa时薄膜样品的帯隙变化范围是3.26 eV到3.49 eV. 通过测量电阻率随温度的变化关系确定了薄膜内部的主要导电机理. 在150 K到210 K温度范围内, 热激发导电机理是主要的导电机理; 而在10 K到150 K范围内; 电导率随温度的变化复合Mott的多级变程跳跃模型 (VRH); 在210 K到300 K范围内, 电阻率和exp(b/T)^1/2呈正比关系. 关键词： 2')" href="#">Ta掺杂TiO₂ 脉冲激光沉积法 薄膜 导电机理     

Study of Intense Electron Beams Produced by High-Voltage Pulsed Glow Discharges

We report the generation of high-current-density (20 A/cm2) pulsed electron beams from high-voltage (48-100 kV) glow discharges using cathodes 7.5 cm in diameter. The pulse duration was determined by the energy of the pulse generator and varied between 0.2 ?s and several microseconds, depending on the discharge current. The largest electron beam current (900 A) was obtained with an oxidized aluminum cathode in a helium-oxygen atmosphere. An oxidized magnesium cathode produced similar results, and a molybdenum cathode operated at considerably lower currents. A small-diameter (<1 mm) well-collimated beam of energetic electrons of very high current density (>1 kA/cm2) was also observed to develop in the center of the discharge. Electrostatic probe measurements show that the negative glow plasma density and the electron beam current have a similar spatial distribution. Electron temperatures of 1-1.5 eV were measured at 7 cm from the cathode. The plasma density (8.5 · 1011 cm-3 at 450 A) was found to depend linearly on the discharge current. In discharges at high currents a denser and higher temperature plasma region was observed to develop at approximately 20 cm from the cathode. We have modeled the process of electron beam generation and predicted the energy distribution of the electron beam. More than 95 percent of the electron beam energy is calculated to be within 10 percent of that corresponding to the discharge voltage.     

Initial stage of discharge current growth in a triggered vacuum gap

The dynamics of light emission accompanying the initial stage of electric discharge in a substantially undervoltaged vacuum gap was studied with a knock-down model using high-speed photorecording. Voltage across the gap was maintained within the range of 0.5-5 kV, which corresponded to the minimum operating voltage of vacuum-triggered gaps. It was found that front layers of a plasma cloud near a cathode, formed by a firing pulse, scattered at a speed of (5-8)×10⁶ cm/s. During firing, a channel directed to the opposite electrode was formed from the plasma cloud near the cathode. It was found that the average switch-on delay time of the triggered vacuum gap is ~d(1+h/d) I_f^-α, where d is the interelectrode gap length, h is the trigger assembly penetration height, and I_f is the firing current     

纳米FePt颗粒:MgO多层复合薄膜的外延生长、微观结构与磁性研究

采用脉冲激光沉积法,在MgO(100)面上外延生长了FePt:MgO多层纳米复合薄膜,FePt成分为Fe48Pt52.FePt纳米颗粒周期性嵌埋于单晶MgO外延层中.原位反射式高能电子衍射分析结果表明,MgO外延层呈层状生长,而FePt纳米颗粒呈岛状生长.在整个FePt:MgO纳米复合薄膜的生长过程中,成功实现了层状-岛状生长模式的交替控制.高分辨透射电子显微镜分析结果表明,退火热处理后,结晶完整的L10-FePt纳米颗粒粒径约为5 nm,呈扁平六角形状,在MgO基底上形成逐层排列的纳米点阵.磁滞回线结果表明,退火后薄膜矫顽力增大,有序度提高,磁性增强.     

On the cutoff law of laser induced high harmonic spectra

The currently well accepted cutoff law for laser induced high harmonic spectra predicts the cutoff energy as a linear combination of two interaction energies, the ponderomotive energy U_p and the atomic biding energy I_p, with coefficients 3.17 and 1.32, respectively. Even though, this law has been there for twenty years or so, the background information for these two constants, such as how they relate to fundamental physics and mathematics constants, is still unknown. This simple fact, keeps this cutoff law remaining as an empirical one. Based on the cutoff property of Bessel functions and the Einstein photoelectric law in the multiphoton case, we show these two coefficients are algebraic constants, 9 - 42≈ 3.34 and 22- 1 ≈ 1.83, respectively. A recent spectra calculation and an experimental measurement support the new cutoff law.     

Vibrationally Excited Ozone Relaxation by CO

Time profiles of ozone concentration after pulsed UV laser photolysis in the O₂- O₃-Ar-CO mixture, measured using time-resolved absorption spectroscopy, are presented. The experimental results show the dominance of the stabilization channel over the reactive one for the interaction between the vibrationally excited ozone molecule O₃(υ) and carbon monoxide CO. The rate constant of the process O₃(υ)+CO→O₃ + CO, obtained by processing experimental data by the kinetic modeling method is (1.5 ± 0.2) · 10^?13 cm³/s.     

Surface modification of polyester to produce a bacterial cellulose-based vascular prosthetic device

The surface of medical grade polyesters was modified to impart hydrophilic character for attachment to bacterial synthesized cellulose to produce a vascular prosthetic device. The polyesters were treated with UV/ozone, air plasma, and nitrogen plasma for various lengths of time. The unmodified and modified surfaces were analyzed by X-ray photoelectron spectroscopy (XPS) and advancing contact angle measurements. The surfaces were then coated with bacterial produced cellulose to study adhesion properties through tensile testing (peel testing). UV/ozone and plasma treatment XPS results indicated an increase in the oxygen concentration in the form of CO(H) on the treated polyester surfaces. The treatment time to reach steady state in the case of air and nitrogen plasmas took the order of seconds, while 7 min and longer were required for UV/ozone treatment. Peel strength tests to measure adhesion of modified polyester to cellulose reached their maximum values when the CO(H) concentrations were at the highest level. It was also at this level that the contact angle measurements showed no further decrease.     

Preliminary Study on Applications of an Atmospheric-Pressure Argon Plasma Discharge With a Single-Electrode Configuration

An atmospheric-pressure (AP) argon plasma discharge generated in a single-electrode configuration with the power supply operating at a frequency of 45 kHz is employed to perform some applications, such as the treatment of the interior surface of a medical infusion tube, hydrophilic modification of insulator surface, hardening of metal surface, and acidification treatment of water. It is shown that the active gases ( $hbox{O}_{2}$ and $hbox{N}_{2}$) mixed in a carrier gas (Ar) play a significant role in carrying out such applications. A preliminary study on its applications is presented to demonstrate the promising potential of AP single-electrode-configuration plasma jet.      

Dynamics of strong and radiative decays of D_s-mesons in the hadrogenesis conjecture

The positive parity scalar D ＊ s0 （2317） and axial-vector D ＊ s1 （2460） charmed strange mesons are generated by coupled-channel dynamics through the s-wave scattering of Goldstone bosons off the pseudoscalar and vector D（D s ）-meson ground states.The specific masses of these states are obtained as a consequence of the attraction arising from the Weinberg-Tomozawa interaction in the chiral Lagrangian.Chiral corrections to order Q 2 χ are calculated and found to be small.The D ＊ s0 （2317） and D ＊ s1 （2460） mesons decay either strongly into the isospin-violating π 0 D s and π 0 D ？ s channels or electromagnetically.We show that the π 0-η and （K^ 0 D ^＋-K^ ＋ D^ 0 ） mixings act constructively to generate strong widths of the order of 140 keV and emphasize the sensitivity of this value to the KD component of the states.The one-loop contribution to the radiative decay amplitudes of scalar and axial-vector states is calculated using the electromagnetic Lagrangian to chiral order Q 2 χ .We show the importance of taking into account processes involving light vector mesons explicitly in the dynamics of electromagnetic decays.The radiative width are sensitive to both η D s and KD components,hence providing information complementary to the strong widths on the positive parity D s-meson structure.     

Low-Pressure Helicon-Plasma Discharge Initiation via Magnetic Field Ramping

Discharge initiation at low pressures and flow rates is investigated in the Madison Helicon Experiment flowing helicon source. At low pressures (below 14-sccm flow rate), a threshold magnetic field exists for discharge initiation which depends on RF power and gas flow rate. Above the threshold magnetic field, RF discharges start only after a significant delay (approximately seconds) and sometimes will not start at all. This threshold magnetic field is interpreted using electron multipactor arguments. A technique is described for initiating discharges at low flow rates and pressures $(lambda_{{rm en}, {rm iz}} ≫ L_{rm system})$ and high magnetic fields (above the threshold value). Without a static magnetic field present, the RF power is turned on, and a lower density $(≪ 10^{11} hbox{cm}^{-3})$ unmagnetized discharge occurs. The magnetic field is then applied, and the discharge transitions to the higher density (up to $10^{13} hbox{cm}^{-3}$) regime. Using this method, magnetized discharges can be started at flow rates as low as 1 sccm ( $1.8 times 10^{-4} hbox{torr}$ at $z = -91 hbox{cm}$ , $1.7 times 10^{-5} hbox{torr}$ at $z = 105 hbox{cm}$) at 500 W in a 1.04-kG magnetic field. This technique can be used to initiate low-pressure helicon discharges for basic plasma science experiments and other applications.      

Conditions for ponderomotive resonances in the Kapitza–Dirac effect

By applying a nonperturbative quantum electrodynamic theory, we study ponderomotive resonances when an electron beam is scattered by a standing photon wave. Our study shows that the ponderomotive parameter u_p, the ponderomotive energy per laser-photon energy, for each of the two traveling laser modes possesses a minimum value ℏω/(mec2). Ponderomotive resonances occur only when the ratio of the laser photon energy to the electron rest-mass energy is a fraction, where the denominator is twice the square of a positive integer and the numerator is the total ponderomotive number, which is also a positive integer.     

Photoacoustic detection of ozone using a quantum cascade laser

A 9.5-m pulsed quantum cascade laser (QCL) and a differential photoacoustic (PA) detector were used to measure trace concentrations of 100 ppbv ozone at ambient pressure with high selectivity. The QCL was tuned by temperature variation between -41 °C and 30.6 °C and the corresponding wavelengths were determined by the PA spectrum of CO₂. Good agreement was found between the measured PA spectrum and the simulated HITRAN spectrum of ozone. The PA signal showed a linear dependence on the ozone concentration in the investigated 4300–100 ppbv range. In comparison with recently published results, in which a similar QCL in combination with an optical absorption analysis technique was applied, an improvement in the ozone-detection sensitivity by a factor of about 200 was achieved. PACS 42.62.Fi; 82.80.Kq; 82.80.Gk; 92.60.Sz