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1.
Adyl Oussaid Fatima Benyaqad Boualem Oussaid Bernard Garrigues 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1605-1616
Carbonylated electrophiles react with furan, thiophene, or pyrrole derivatives in the presence of catalytic amounts of bismuth triflate or chloride, leading to either electrophilic substitution or ene reaction products. 相似文献
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Synthesis and Crystal Structures of Bismuth Chalcogenolato Compounds Bi(SC6H5)3, Bi(SeC6H5)3, and Bi(S‐4‐CH3C6H4)3 Bismuth(III) acetate reacts with thiophenol in ethyl alcohol at 80 °C to yield Bi(SC6H5)3 ( 1 ). Slow cool down of the deep yellow mixture lead to the formation of orange crystals of 1 . The homotype phenylselenolato compound of bismuth Bi(SeC6H5)3 ( 2 ) has been prepared by the reaction of BiX3 (X = Cl, Br) with Se(C6H5)SiMe3 in diethyl ether. In the same way as Bi(SC6H5)3 ( 1 ) the reaction between bismuth(III) acetate and 4‐tolulenethiole results in red crystals of Bi(S‐4‐CH3C6H4)3 ( 3 ). In consideration of three longer Bi–E distances (intermolecular interactions, E = S; Se) the Bi(EPh)3 molecules form via face‐linked octahedra 1‐dimensional chains in the crystal lattice, while for 3 the 1‐dimensional chain is formed by face‐linked trigonal prisma. We reported herein the synthesis and structures of Bi(SC6H5)3 ( 1 ), Bi(SeC6H5)3 ( 2 ), and Bi(S‐4‐CH3C6H4)3 ( 3 ). 相似文献
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Bismuth triflate catalyzed direct-type Mannich reaction of cyclohexanone, aromatic aldehyde, and aromatic amine proceeded smoothly in water to afford the corresponding β-amino ketone with very good yield and moderate to good anti selectivity. 相似文献
5.
Synthesis,Structure and Thermal Decomposition of the Bismuth Silyltellurolate Bi(TeSitBu2Ph)3
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The compound Bi(TeSitBu2Ph)3 ( 1 ) was obtained from the reaction of BiCl3 with tBu2PhSiTeSiMe3 in diethyl ether. The single crystal structure analysis revealed a trigonal pyramidal structure of the BiTe3 core and weak Bi···C(arene) contacts. Compound 1 was characterized by multinuclear NMR spectroscopy, IR spectroscopy and elemental analysis. Thermogravimetric experiments show that compound 1 decomposes with formation of Bi2Te3 or a mixture of elemental bismuth and Bi4Te3, depending on the pressure conditions. 相似文献
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以硝酸铋[Bi(NO)3]和硫化钠(Na2S)为反应原料, 采用水热法在120 ℃下反应12 h, 制备出Bi2S3纳米管. 利用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、选区电子衍射(SAED)和高分辨透射电镜(HRTEM)对其结构和形貌进行了表征. 结果表明, 所制备的产物是结晶良好的正交相Bi2S3纳米管, 其外径为100~500 nm, 内径为50~200 nm, 长为1~5 μm. 根据实验结果讨论了Bi2S3纳米管的生长机理. 初步研究了反应温度和矿化剂种类对产物形貌和结构的影响. 相似文献
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Bismuth triflate was found to be an efficient catalyst for the Claisen rearrangement of allyl naphthyl ethers. The reaction proceeds smoothly with a catalytic amount of bismuth triflate (20 mol %) to afford the corresponding ortho-allyl naphthol in moderate to good yields in most cases. 相似文献
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This work describes the first catalytic bismuth-promoted synthesis of polysubstituted guanidines in good yields through the guanylation reaction of N-benzoyl or N-phenylthioureas with primary and secondary amines, but now employing equimolar amounts of each organic reagent. Both bismuth iodine and bismuth nitrate were efficient as inorganic thiophiles at only 5 mol % in relation to substrates, being the first example of inorganic thiophiles acting in guanylation at catalytic levels. 相似文献
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Dr. Xiuxiu Yang Jennifer Kuziola Dr. Vanessa A. Béland Julia Busch Dr. Markus Leutzsch Dr. Jordi Burés Dr. Josep Cornella 《Angewandte Chemie (International ed. in English)》2023,62(32):e202306447
In this article we report that a cationic version of Akiba's BiIII complex catalyzes the reduction of amides to amines using silane as hydride donor. The catalytic system features low catalyst loadings and mild conditions, en route to secondary and tertiary aryl- and alkylamines. The system tolerates functional groups such as alkene, ester, nitrile, furan and thiophene. Kinetic studies on the reaction mechanism result in the identification of a reaction network with an important product inhibition that is in agreement with the experimental reaction profiles. 相似文献
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The reaction of 8-bromoguanines with aryl and hetaryl stannanes in the presence of a palladium catalyst leads to the formation of the corresponding 8-aryl(hetaryl)guanines. It was found that the addition of triphenylarsine or triphenylbismuth strongly reduces the reaction time and increases product yields. 相似文献
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In the presence of a catalytic amount of Bi(OTf)3·4H2O and under microwave irradiation, neat mixtures of epoxides and amines afforded smoothly the corresponding 2-amino alcohols. A wide variety of aliphatic amines were reacted with cycloalkene oxide, styrene oxide, and stilbene oxide. The reaction proceeded rapidly and afforded the 2-amino alcohols in high up to quantitative yields. All products could be obtained without aqueous work-up by simple filtration. 相似文献
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A series of carboxylic acids were converted into their corresponding methyl esters using bismuth(III) triflate as a catalyst in methanol. Good to excellent yields were obtained for different aliphatic or aromatic starting materials. In the reaction, bismuth triflate acts as a precursor that, upon hydrolysis, liberates sufficient triflic acid to catalyze the esterification. 相似文献
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An efficient synthesis of functionalized 4H-chromenes by the tandem reaction of b,g-unsaturated aketoesters with 2-naphthols,1-naphthols,and 1,3-dihydroxynaphthalenes has been accomplished with high selectivity and excellent yields in the presence of a catalytic amount of bismuth triflate [Bi(OTf)3,5 mol%] under mild conditions.The functionalized 4H-chromene synthesis and our previous 2Hchromene hemiacetal synthesis could complement each other to enrich reaction diversity. 相似文献
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In this study, we demonstrate a straightforward solution-phase method for the selective synthesis of BiOCl, BiVO4 and δ-Bi2O3 nanocrystals by simply manipulating the reaction temperature and the BiCl3-to-NaOH mole ratio in the reaction system of BiCl3-NH4VO3-NaOH. The experimental results revealed that BiOCl, as the sole product, was prepared when designating the reaction temperature ranging from room temperature to 100 °C, regardless of the BiCl3-to-NaOH mole ratio; on the other hand, BiOCl, BiVO4, and δ-Bi2O3 nanocrystals could be selectively prepared at 140-180 °C, depending on the BiCl3-to-NaOH mole ratio in solution. Significantly, we first report on fabricating δ-Bi2O3 sample, the high-temperature cubic phase commonly stabilized at 730-824 °C, at the low reaction temperature of 140-180 °C under solution-phase synthetic conditions. In addition, the δ-Bi2O3 sample exhibits strong emission at room temperature. 相似文献
15.
Syntheses and Crystal Structure Analyses of [SbI3(SbMe3)(THF)]2 and [Li(THF)4]2[Bi2Cl8(THF)2] The reaction of Me3Sb with SbI3 in tetrahydrofuran (THF) gives [SbI3(SbMe3)(THF)]2 ( 1 ). [Li(THF)4]2[Bi2Cl8(THF)2] ( 2 ) is formed by reaction of LiCl and BiCl3 in tetrahydrofuran. The structures of ( 1 ) and ( 2 ) have been determined by X-ray diffractometry. Both structures contain centrosymmetric dimers with the geometry of edge sharing octahedra. 相似文献
16.
Adyl Bernard Bernard Garrigues 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):825-832
In presence of bismuth(III) triflate, a carbonylated electrophile (ethyl mesoxalate or glyoxylate) and usual diene led selectively (60-100) the hetero carbonyl-Diels-Alder reaction with the ene reaction product. Bi(OTf) 3 exhibits strong catalytic activity and reacts under mild conditions. En présence de triflate de bismuth(III) le mésoxalate et le glyoxylate d'éthyle réagissent avec des diènes usuels pour donner un mélange de carbonyl-Diels-Alder et du produit de la ène réaction. Bi(OTf) 3 présente une forte activité catalytique et réagit dans des conditions douces. 相似文献
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Synthesis of indole derivatives bound to pyrroles is a challenge. In this letter, an expeditious synthesis of these types of molecules starting from isatins and 4-hydroxy proline via a bismuth nitrate-catalyzed reaction is described. 相似文献
18.
Michael A. Beswick Nick Choi Alexander D. Hopkins Yvonne G. Lawson Mary McPartlin Alexander Rothenberger Dietmar Stalke Andrew E. H. Wheatley Dominic S. Wright 《Angewandte Chemie (International ed. in English)》1999,38(20):3053-3055
Thermally unstable crystals of the title compound—the first bismuth phosphide complex to be structurally characterized (see picture)—are obtained by the reaction of [Bi(NMe2)3] with [tBuPHLi] (1:3) in THF/hexane. Berry pseudorotation of the pseudo-trigonal-bipyramidal [{(tBuP)3}2Bi]− ion is prevented for steric reasons. 相似文献
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