Probabilistically perfect quantum cloning and unambiguous state discrimination

We consider the N → M probabilistically perfect quantum cloning machine that perfectly produces M faithful copies from N identical input states, where the input states are selected, with prior probabilities η₁and η₂ = 1 − η₁, from a given set of the two linearly independent states |ψ₁〉^⊗ N = (cosθ|0〉 + sinθ|1〉)^⊗ N and |ψ₂〉^⊗ N = (sinθ|0〉 + cosθ|1〉)^⊗ N (θ∈(0,π/2)). We derive the optimal distribution of the success probabilities. When M approaches infinite, the probabilistically perfect quantum cloning can be regarded as a kind of the unambiguous state discrimination, and theoretically provides the upper bound of the unambiguous state discrimination. By using the optimal distribution of the success probabilities of the optimal asymmetric 1 → M probabilistically perfect quantum cloning, we can derive the maximum average success probability of the unambiguous discrimination of two nonorthogonal quantum states |ψ₁〉and|ψ₂〉. As an example, we give the explicit transformation of the optimal symmetric 1 → M probabilistically perfect quantum cloning to copy the two input states |ψ₁〉 and |ψ₂〉.     

On the quantum polarization and entanglement of superpositions of two two-mode coherent states

This work discusses the entanglement and quantum polarization of superpositions of two-mode coherent states of the types |ψ₁〉 = N₁(|α, β〉 + |β, α〉) and |ψ₂〉 = N₂(|−α, −α〉 + |α, α〉). We use the concurrence to measure their entanglements and the quantum Stokes parameters and the Q function in order to analyze their polarization and degree of polarization.     

Higher-order Hong-Mandel's squeezing in superposed coherent states

We study 2nth order Hong and Mandel's squeezing of the Hermitian operator, X_θ ≡ X₁cosθ + X₂sinθ in the most general superposition state, |ψ〉 = Z₁|α〉 + Z₂|β〉 of two coherent states |α〉 and |β〉. Here operators X_1,2 are defined by X₁ + i X₂ = a, the annihilation operator, angle θ and complex numbers Z_1,2 , α, β are arbitrary and the only restriction on these is the normalization condition of |ψ〉. We find maximum 2nth-order Hong-Mandel squeezing of X_θ in the superposed coherent state |ψ〉 for an infinite combinations with , and with arbitrary values of (α + β) and θ. Here A_2n is a constant which depends on the order of squeezing. The maximum percentage of 2nth order Hong-Mandel squeezing and their respective constants A_2n have been reported for some values of n. We conclude that any large percentage of squeezing can be obtained by suitably choosing of the order 2n. For the order greater than 128 we obtained more than 99% higher-order squeezing at very low intensity of the optical field. Variations of higher-order squeezing with different parameters near its maxima have also been discussed.     

Efficient multi-party quantum state sharing of an arbitrary two-qubit state

We present an efficient scheme for sharing an arbitrary two-qubit quantum state with n agents. In this scheme, the sender Alice first prepares an n + 2-particle GHZ state and introduces a Controlled-Not (CNOT) gate operation. Then, she utilizes the n + 2-particle entangled state as the quantum resource. After setting up the quantum channel, she performs one Bell-state measurement and another single-particle measurement, rather than two Bell-state measurements. In addition, except that the designated recover of the quantum secret just keeps two particles, almost all agents only hold one particle in their hands respectively, and thus they only need to perform a single-particle measurement on the respective particle with the basis X. Compared with other schemes based on entanglement swapping, our scheme needs less qubits as the quantum resources and exchanges less classical information, and thus obtains higher communication efficiency.     

基于p1-p2与a1+a2共同本征态的相干纠缠态表象的构建及性质

利用有序算符乘积内的积分技术（IWOP）,建立了一种称之为相干纠缠态的两粒子体系的新表象,研究了这种新表象的性质,从理论上探讨了这种相干纠缠态的产生方法.结果表明：本文建立的这种p₁-p₂与a₁+a₂的共同本征态|p,β〉,既具有相干态的特性,又体现了纠缠态的特征,具有超完备性,完全可以作为一个表象使用. 物理上可以用光分束器来实现|< 关键词： IWOP技术 相干纠缠态表象 分束器     

Decoy state quantum key distribution with finite resources

We apply the finite key analysis to the decoy state quantum key distribution scheme and obtain a practical key rate. By simulating an practical experiment setups and the Vacuum + Weak decoy state method, we show that both the key rate and maximal secure distance are reduced when the finite key analysis is considered.     

Enhancing entanglement of entangled coherent states by single-mode coherent superposition of photon subtraction and addition

We introduce a new entangled quantum state generated by applying single-mode coherent superposition of photon subtraction and addition (a^† cos θ + a sin θ)^m to the entangled coherent state |Ψ_±(α,0)〉$|{\Psi }_{\pm }\left(\alpha ,0\right)〉$, and then investigate the entanglement properties affected by coherent superposition operation. It is shown that this operation can be applied to enhance the entanglement of the state |Ψ₊(α,0)〉$|{\Psi }_{+}\left(\alpha ,0\right)〉$. In addition, the effects of the coherent operation is better to improve the entanglement than that of the creation operation (a^†m) for |Ψ₊(α,0)〉$|{\Psi }_{+}\left(\alpha ,0\right)〉$ in a small-amplitude regime and for |Ψ₋(α,0)〉$|{\Psi }_{-}\left(\alpha ,0\right)〉$ in any regime.     

Nonclassical and non-Gaussian properties of states generated by the superposed photon added-and-subtracted operation on squeezed vacuum

A new kind of non-Gaussian quantum state is constructed by operating the superposed operator (SO) (cos θaa^† + sin θa^†a) on a squeezed vacuum state (SVS) S(r)|0〉. It is found that the SOSVS is just a superposition state between S(r)|0〉 and S(r)|2〉 with only even numbers of photons. The nonclassicality is investigated by exploring the negativity of Wigner function (WF) and the sub-Poissonian distribution of Mandel's Q-parameter. The non-Guassianity is exhibited via the fidelity between the SOSVS and the SVS and the marginal distribution of its Wigner function. It is found that such SO on the SVS can enhance the nonclassicality and change the non-Gaussianity of the SOSVS. This provides the possibility of generating quantum states with specific nonclassical and non-Gaussian properties.     

A theoretical study of FeCN in the Δ electronic ground state

The three-dimensional potential energy and dipole moment surfaces for the electronic ground state ⁶Δ of FeCN have been computed at the MR-SDCI + Q + E_rel/[Roos ANO (Fe), aug-cc-pVQZ (C, N)] level of theory, where MR-SDCI means ‘multi-reference single and double excitation configuration interaction’ and ANO means ‘atomic natural orbital’. Based on these potential energy and dipole moment surfaces, the spectroscopic parameters, rovibronic energies, structural parameters, vibrational transition moments, and the wavenumbers and intensities of selected rotation-vibration transitions have been calculated. The equilibrium structure is linear with r_e(Fe-C) = 2.048 Å and r_e(C-N) = 1.168 Å, and the zero-point averaged structure is bent with 〈r(Fe-C)〉₀ = 2.082 Å, 〈r(C-N)〉₀ = 1.172 Å, and 〈∠(Fe-C-N)〉₀ = 170(5)°. At all the MR-SDCI + Q and the size-extensive multi-reference averaged quadratic coupled-cluster (MR-AQCC) levels of theory, with and without relativistic correction E_rel, that were employed in the present work, ⁶Δ FeCN is predicted to be slightly more stable than ⁶Δ FeNC. For example, the energy difference between the two isomers is approximately 150 cm⁻¹ at the highest level of theory employed, MR-AQCC + E_rel/[Roos ANO (Fe), aug-cc-pVQZ (C, N)] with zero-point energy correction. The electronic structure of ⁶Δ FeCN has also been compared with that of ⁶Δ FeNC. At present, no experimental spectroscopic data are available for ⁶Δ FeCN. It is hoped that the present work will stimulate experimental investigations of this molecule.     

Λ-Doubling investigation of the 5Πg Rydberg state of Na2 using optical-optical double resonance spectroscopy

The splitting of Λ-doubling in the 5¹Π_g Rydberg state of Na₂, which dissociates to Na(3s) + Na(4d), has been measured using the high-resolution cw optical-optical double resonance technique. The observed data are in the range of 0 ? v ? 22 and 11 ? J ? 83 with Λ-doubling revealed. A set of Dunham coefficients with Λ-doubling constants has been obtained from the experimental results. The splitting of Λ-doubling increases quadratically with the rotational quantum number J and weakly depends on the vibrational quantum number v. These splitting constants are much larger than those in the Na₂B¹Π_u state, which dissociates to Na(3s) + Na(3p). This indicates that the splitting of Λ-doubling in the 5¹Π_g state is affected by both the perturbations by adjacent Σ states and the L-uncoupling.     

真空场注入非对称五态叠加多模泛函叠加态的高次振幅压缩

构造了由多模真空态、多模泛函相干态、多模泛函相干态的相反态、多模复共轭泛函相干态和多模复共轭泛函相干态的相反态这五个宏观上完全可分辩的量子态线性叠加所构成的强度不等的非对称五态叠加多模泛函叠加态光场|Ψ(5)vas〉q.利用多模压缩态理论,首次研究了态|Ψ(5)vas〉q的广义非线性等幂奇数次高次振幅压缩特性.结果发现:在一定的条件下,态|Ψ(5)vas〉q可呈现任意次的广义非线性等幂次高次振幅压缩效应,其压缩程度、压缩深度和压缩幅度与压缩次数、腔模总数、态间叠加几率幅、各模光场的经典强度以及经典初始相位的空间分布函数等强烈地非线性相关联;特别是,在特定条件下,真空场的注入可以提高压缩程度.     

Coherent states of the inverted Caldirola-Kanai oscillator with time-dependent singularities

The coherent states for a system of time-dependent singular potentials coupled to inverted CK (Caldirola-Kanai) oscillator are investigated by employing invariant operator method and Lie algebraic approach. We considered Coulomb potential and inverse quadratic potential as singularities of the system. The spectrum of quantum states is discrete for λ < 0 while continuous for λ ? 0. The probability densities for both Fock state and coherent state are converged to the center as time goes by according to the dissipation of energy. We confirmed that the probability density in the coherent state oscillates back and forth like a classical wave packet.     

Comparison of continuous-wave (CW) and tone-burst (TB) excitation modes in vibro-acoustography: Application for the non-destructive imaging of flaws

This paper describes the application of continuous-wave (CW) and tone-burst (TB) vibro-acoustography (VA) experiments for imaging a flawed composite plate. For both modes, the ultrasound frequency is set at f₁ = 3 MHz and f₂ = 3 MHz + ∣Δf∣. The plate was placed at the focus of the transducer and scanned point-by-point over an area of 60 mm by 50 mm on its frontal face with an increment step equal to 0.25 mm/pixel. The resulting acoustic emission amplitude at ∣Δ f∣ is recorded. For the CW mode the difference frequency was set at ∣Δf∣ = 12.9 kHz. For the TB mode, the burst-emitted signal was 100 μs long at a pulse repetition frequency (PRF) of 100 Hz corresponding to bursts of 300 cycles at 3 MHz, and the difference frequency was set at ∣Δf∣ = 44 kHz. The resulting VA images readily show the shape of the flaws. The images also reveal considerable detail of internal substructures such as the fibers used to reinforce the plate. However, the CW VA image shows an artifact caused by the effect of ultrasound standing waves established between the plate and the concave surface of the transducer, resulting in masking some of the flaws. On the other hand, the TB-VA image is free from such artifact. Despite some advantages of using TB-VA, there are some limitations related to this mode. Advantages and limitations of using the two modes are discussed.     

New observation and analysis of the E(4)Σ state in NaLi

Polarization labeling spectroscopy is applied to study the excited E(4)¹Σ⁺ state of NaLi in the energy range 25 850-27 750 cm⁻¹ above the bottom of the ground state. The potential curve of the E state is constructed using the Inverted Perturbation Approach method.     

Ground state spectrum of methylcyanide

The rotational spectrum of methylcyanide (acetonitrile) in the ground vibrational state was measured in the spectral region from 91 to 810 GHz using the Cologne and Tsukuba spectrometers operated in the Doppler-limited and sub-Doppler saturation layouts. The resolution of the saturation Lamb-dip measurements is estimated to be about 1 kHz at the best of circumstances and the measuring accuracy of 10-60 kHz depending very sensitively on the quality of the spectrum. In the cases of rotational transitions with the low quantum number J (J<18) and with a low difference of the rotational quantum numbers J−K, the resolved or partly resolved hyperfine structures of the rotational transitions were observed. Together with the most accurate data from the literature, the newly measured experimental data were analyzed using the traditional polynomial energy formula as well as the Padè approximant for the effective rotational Hamiltonian. The resulting rotational, centrifugal distortion, and hyperfine structure spectroscopic constants were obtained with a significantly higher accuracy than the ones listed in the literature. In addition, an anomalous accidental resonance was detected between the K=14 ground state levels and the K=12, +l levels in the excited v₈=1 vibrational state.     

High-resolution laser spectroscopy of the potassium-argon molecule: The BΣ state

The absorption spectrum of the KAr molecule has been observed with high resolution between 13 032 and 13 077 cm⁻¹ using tunable laser diodes as light sources, a supersonic beam for production of the molecules, and laser-induced fluorescence for detection. In addition, optical-optical double resonance (OODR) experiments have been performed to simplify the spectrum and to get rotational assignment. Altogether, 670 lines due to the transition B²Σ⁺ ← X²Σ⁺ have successfully been assigned with vibrational levels of the B state ranging from v = 0 to v = 6. The corresponding energy values were fitted to the well-known Dunham expansion. In addition, we were able to analyse a local perturbation between the vibrational level v = 1 of the B state and v = 14 of the A²Π_3/2 state. Unexpected extra lines in the OODR spectra are most probably due to a collision-induced population of other levels. For the equilibrium distance and the well-depth of the B state we obtain from the Dunham expansion 7.03 (8) Å and 26.2 (8) cm⁻¹, respectively.     

Large amplitude bending motion in CsOH, studied through ab initio-based three-dimensional potential energy functions

The large-amplitude bending motion in CsOH, a ‘classical’ molecule whose microwave spectrum was first recorded in 1967, has been studied ab initio. The three-dimensional potential energy surface has been calculated at the RCCSD(T)_DK3/[QZP + g ANO-RCC (Cs, O, H)] level of theory and employed in MORBID calculations of the rotation-vibration energies and intensities. The ground electronic state is ¹Σ⁺ with the equilibrium structure r_e(Cs-O) = 2.3930 Å, r_e(O-H) = 0.9587 Å, and ∠_e(Cs-O-H) = 180.0°. The O-H moiety is bound to Cs by an ionic bond and the molecule can be described as Cs^δ+(OH)^δ-. Hence, the bending potential is shallow and gives rise to large-amplitude bending motion. The ro-vibrationally averaged structural parameters, determined as expectation values over MORBID wavefunctions, are 〈r(Cs-O)〉₀ = 2.3987 Å, 〈r(O-H)〉₀ = 0.9754 Å, and 〈∠(Cs-O-H)〉₀ = 163°. Although the averaged structure in the vibrational ground state is far from being linear, the Yamada-Winnewissi-linearity parameter for CsOH is γ₀≈-1.0, the value characteristic for a linear molecule.     

On the cΠ (v = 0) state of carbon monoxide

A full analysis of the near infrared c³Π-b³Σ⁺ (0-0) band is given and term values for both states determined. The c³Π (v = 0) state was jointly analysed with the perturbing k³Π (v = 2) state and data from the c³Π-X¹Σ⁺ (0-0) transition and 3A band system were included. It is shown that the available data are consistent with the c³Π (v = 0) state having near Hund’s case b coupling with a spin-orbit constant of A = 0.45 ± 0.02 cm⁻¹, a homogeneous perturbation with the k³Π (v = 2) state, and Λ-type doubling arising predominantly from its interaction with the j³Σ⁺ state. A discrepancy with a more recent report of the 3A band system is identified and discussed. The perturbed b³Σ⁺ state term values are consistent with a previously reported five state interaction model.     

Thermal evolution of surface blistering and exfoliation due to ion-implanted hydrogen monomers into Si〈1 1 1〉

This study investigated the dependence of surface blistering and exfoliation phenomena on post-annealing time in H⁺-implanted Si〈1 1 1〉. Czochralski-grown n-type Si〈1 1 1〉 wafers were room-temperature ion-implanted with 40 keV hydrogen monomers to a fluence of 5×10¹⁶ cm⁻², and followed by furnace annealing treatments at 400 and 500 °C for various durations ranging from 0.25 to 3 h. The corresponding analysis results for Si〈1 0 0〉 [1] (Liang et al., 2008); [2] (Bai, 2007) were adopted in order to make comparisons. The evolution of blister formation and growth for Si〈1 1 1〉 at 400 °C has a shorter characteristic time compared to Si〈1 0 0〉. However, there is a longer characteristic time when annealing takes place at 500 °C. In addition, no craters were observed for Si〈1 1 1〉 annealed at 400 °C while the opposite is true for Si〈1 0 0〉. The evolution of crater development for Si〈1 1 1〉 annealed at 500 °C has a longer characteristic time compared to Si〈1 0 0〉. These results are attributed to the fact that compared to Si〈1 0 0〉, Si〈1 1 1〉 has a smaller surface binding energy of silicon atoms and a larger areal number density of silicon atoms on the plane perpendicular to the incident-ion axis. Furthermore, Si〈1 1 1〉 has a greater areal number density, smaller diameter, and a similar covered-area fraction of optically-detectable blisters compared to Si〈1 0 0〉. However, Si〈1 1 1〉 has a lower areal number density and a smaller covered-area fraction of craters than does Si〈1 0 0〉. Increasing post-annealing temperature from low (e.g. 400 °C) to high (e.g. 500 °C) revealed that Si〈1 1 1〉 tends to create more blisters while Si〈1 0 0〉 tends to develop larger blisters as well as create more craters.     

The electronic spectrum of AgBr2: Ab initio benchmark vs. DFT calculations on the lowest ligand-field states including spin-orbit effects

The X²Π_g, ²Σ_g⁺ and ²Δ_g states of AgBr₂ have been studied through benchmark ab initio CASSCF + Averaged Coupled Pair Functional (ACPF) and DFT calculations using especially developed valence basis sets to study the transition energies, geometries, vibrational frequencies, Mulliken charges and spin densities. The spin-orbit (SO) effects were included through the effective hamiltonian formalism using the |ΛSΣ〉 ACPF energies as diagonal elements. At the ACPF level, the ground state is ²Π_g, in contradiction with ligand-field theory and Hartree-Fock results. The ACPF adiabatic excitation energies of the ²Σ_g⁺ and ²Δ_g states are 3825 and 20 152 cm⁻¹, respectively. The inclusion of the SO effects leads to a pure Ω = 3/2 (²Π_g) ground state, a Ω = 1/2 (97% ²Π_g + 3% ²Σ_g⁺) A state, a Ω = 1/2 (3% ²Π_g + 97% ²Σ_g⁺) B state, a Ω = 5/2 (²Δ_g) C state and a Ω = 3/2 (99% ²Δ_g) D state. The B97, B3LYP and PBE0 functionals, which were shown to yield accurate transition energies for CuCl₂, overestimate the X²Π_g-²Σ_g⁺ T_e by around 25% but provide a qualitative energetic ordering in agreement with CASSCF and ACPF results. The nature of the bonding in the X²Π_g ground state is different from that of AgCl₂ since the Mulliken charge on the metal is 0.95 while the spin density is only 0.39. DFT strongly delocalizes the spin density providing even smaller values of around 0.13 on Ag not only for the ground state, but also for the ²Σ_g⁺ state.