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Reduced Graphene‐Wrapped MnO2 Nanowires Self‐Inserted with Co3O4 Nanocages: Remarkable Enhanced Performances for Lithium‐Ion Anode Applications
Authors:Qi Zhu  Yunhui Li  Prof Ying Gao  Prof Xiao Wang  Prof Shuyan Song
Affiliation:1. Department of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, P. R. China;2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun, P. R. China
Abstract:A simple synthetic approach for graphene‐templated nanostructured MnO2 nanowires self‐inserted with Co3O4 nanocages is proposed in this work. The Co3O4 nanocages were penetrated in situ by MnO2 nanowires. As an anode, the as‐obtained MnO2–Co3O4–RGO composite exhibits remarkable enhanced performance compared with the MnO2–RGO and Co3O4–RGO samples. The MnO2–Co3O4–RGO electrode delivers a reversible capacity of up to 577.4 mA h g?1 after 400 cycles at 500 mA g?1 and the Coulombic efficiency of MnO2–Co3O4–RGO is about 96 %.
Keywords:Coulombic efficiency  electrochemistry  graphene  nanostructures  reversible capacity
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