Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal‐Dinitrogen Complexes |
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| Authors: | Yoshiaki Tanabe Yoshiaki Nishibayashi |
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| Affiliation: | Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo‐ku, Tokyo, Japan |
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| Abstract: | This paper presents recent progress in catalytic transformation of molecular dinitrogen into ammonia or its equivalents, such as silylamine, especially using transition metal‐dinitrogen complexes under ambient reaction conditions. Several catalytic systems have been recently established using molybdenum‐, iron‐, and cobalt‐dinitrogen complexes or their precursors as catalysts, providing new approaches to the development of novel nitrogen fixation under ambient reaction conditions. |
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| Keywords: | catalytic reactions cobalt iron molybdenum nitrogen fixation |
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