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Properties of Co-Doped 0.92(Na0.5Bi0.5) TiO3-0.08BaTiO3 Lead-Free Ceramics
引用本文:江向平,郑严艳,江福兰,刘利华,郭建荣,陈王丽华.Properties of Co-Doped 0.92(Na0.5Bi0.5) TiO3-0.08BaTiO3 Lead-Free Ceramics[J].中国物理快报,2007,24(11):3257-3259.
作者姓名:江向平  郑严艳  江福兰  刘利华  郭建荣  陈王丽华
作者单位:[1]Department of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001 [2]Department of Applied Physics and Materials Research Center, The Hong Kong Polytechnic University, Hong Kong
基金项目:Supported by the National Natural Science Foundation of China under No 50562002, the New Century Excellent Talents in University (NCET-06-0576), the Key Industrial Project of Jiangxi Provincial Department of Science and Technology [2005]52, Jiangxi Provincial Department of Education [2005]217, the Natural Science Foundation of Jiangxi Province (No 0650074), and the Center for Smart Materials of The Hong Kong Polytechnic University.
摘    要:Lead-free piezoelectric ceramics 0.92(Bi0.5Na0.5)TiO3-0.08BaTiO3 + xmol% Co3+ (BNBT-Co, x = 0-8) are prepared by the solid state reaction method. Effects of the amount of Co^3+ on the electrical properties and phase transition are studied. The results indicate that the addition of Co^3+ enhances the mechanical quality factor Q^3+ significantly, whereas the dissipation factor tanδ has a minimum value at x = 3.5. Meanwhile, addition of Co^3+ leads to small decreases of piezoelectric constant d33, and planar electromechanical coupling kp. The present 0.92(Bio.aNao.5) TiO3-0.08BaTiO3+3.5 moi% Co^3+ ceramics exhibit good performance with mechanical quality factor Qm = 910, piezoelectric constant d33 = 106pC/N, planar electromechanical coupling kp =10% and dissipation factor tanδ = 1.1% at 1 kHz. Saturated polarization hysteresis loops have been obtained for BNBT-Co ceramics. Two dielectric peaks at depolarization temperature Td and Tm appear in the curves of ε33^T vs temperature for the pure BNBT ceramics. However, the first dielectric peak Td disappears after the addition of Co^3+, which means that the transition from ferroelectric to antiferroelectric phase has been eliminated.

关 键 词:陶瓷材料  复合材料  化学物理  物理分析
收稿时间:2007-06-17

Properties of Co-Doped 0.92(Na0.5Bi0.5) TiO3-0.08BaTiO3 Lead-Free Ceramics
JIANG Xiang-Ping,ZHENG Yan-Yan,JIANG Fu-Lan,LIU Li-Hua,KWOK Kin-Wing,CHAN-WONG Lai-Wa.Properties of Co-Doped 0.92(Na0.5Bi0.5) TiO3-0.08BaTiO3 Lead-Free Ceramics[J].Chinese Physics Letters,2007,24(11):3257-3259.
Authors:JIANG Xiang-Ping  ZHENG Yan-Yan  JIANG Fu-Lan  LIU Li-Hua  KWOK Kin-Wing  CHAN-WONG Lai-Wa
Affiliation:Department of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001Department of Applied Physics and Materials Research Center, The Hong Kong Polytechnic University, Hong Kong
Abstract:
Keywords:77  84  Dy  77  80  Bh  77  65  Bn
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