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Y3AlsO12.t:e prepared Solid solubility and photoluminescence of YeAl5O12:Ce3+ preparedby using (Y1-xCex)203 as precursor
引用本文:刘思佳,彭同江,宋振,边柳,宋功保,刘泉林.Y3AlsO12.t:e prepared Solid solubility and photoluminescence of YeAl5O12:Ce3+ preparedby using (Y1-xCex)203 as precursor[J].中国物理 B,2014(4):639-643.
作者姓名:刘思佳  彭同江  宋振  边柳  宋功保  刘泉林
作者单位:[1]School of Materials Science & Engineering, Southwest University of Science and Technology, Mianyang 62101 O, China [2]School of Materials Science & Engineering and State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
基金项目:Project supported by the National Natural Science Foundation of China (Grant No. 51272027) and the Ph.D. Program Foundation of Education Ministry of China (Grant No. 20100006110011).
摘    要:Trivalent cerium-doped yttrium aluminum garnet (YAG:Ce3+) phosphors are synthesized by solid-state reaction method through using (Yl-xCex)203 solid solutions as precursors. Solid solubility limits of Ce3+ replacing y3+ in Y203 and YAG are determined to be 40% and 7.5%, respectively, based on the relationship between the lattice param- eter and chemical composition. Using (Y1-xCex)203 as precursors we synthesize YAG:Ce3+single phase at 1450 ~C and N2 atmosphere. However, under the same conditions using CeO2 there exists a second phase YA103 as impurity. The photoluminescence intensity of YAG:Ce3+ increases monotonically with the increase of Ce concentration until it reaches a maximum at solid solubility limits of Ce3+ in YAG.

关 键 词:光致发光  铈掺杂  前驱体  溶解度  固体  YAG激光  制备  固相反应法

Y3AlsO12.t:e prepared Solid solubility and photoluminescence of YeAl5O12:Ce3+ preparedby using (Y1-xCex)203 as precursor
Abstract:luminescence, YAG, solid solubility, LED
Keywords:luminescence  YAG  solid solubility  LED
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