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投稿时间:2016-10-08 修订日期:2017-01-20
投稿时间:2016-10-08 修订日期:2017-01-20
中文摘要: 以石墨粉为原料,采用改良Hummers方法合成石墨烯,然后通过液相还原法制备出石墨烯负载纳米铁材料(Graphene-supported nanoscale zero-valent iron,G-nZVI),借助扫描电子显微镜(SEM)、红外光谱分析仪(FTIR)进行表征,并以G-nZVI为反应材料,研究其对水体中Cr(VI)的去除效率,结果显示:室温下,当G-nZVI投加量为0.4g/L,Cr(VI)的初始浓度为20mg/L,初始pH值为3.0时,Cr(VI)的去除率在2 h内可以达到95%以上。G-nZVI具有磁性,使用后可通过外加磁力除去,以防对水体的二次污染,具有较好的应用前景。
Abstract:Using graphite as the raw materials, graphene was firstly synthesizedby improved Hummers and then graphene supported zero valence Fe nano particles(G-nZVI) were successfully prepared by liquid phase reduction method. Using scanning electron microscopy(SEM) and fourier transform infrared spectroscopy(FTIR) for materials characterization,the efficiency of removalCr(VI) from water by G-nZVI was studied.The results showed that at room temperature, more than 95% of Cr(VI) was removed from aqueous solution within 2 hours,when the G-nZVI addition amount was 0.4 g/L,an initial Cr(VI) concentration was 20 mg/L and the initial pH value was 3.0. Since G-nZVI is magnetic, so it can be removed by external magnetic force in order to prevent repeated pollution of water, which has good application prospects.
keywords: graphene nanoscale zero-valent iron Cr(VI)
文章编号: 中图分类号: 文献标志码:
基金项目:广西科学研究与技术开发计划项目(桂科能141123006-16)资助
作者 | 单位 |
袁永海 | 中国有色桂林矿产地质研究院有限公司,广西 桂林 541004 |
尹昌慧 | 中国有色桂林矿产地质研究院有限公司,广西 桂林 541004 |
施意华 | 中国有色桂林矿产地质研究院有限公司,广西 桂林 541004 |
杨仲平 | 中国有色桂林矿产地质研究院有限公司,广西 桂林 541004 |
引用文本:
袁永海,尹昌慧,施意华,杨仲平.石墨烯负载零价纳米铁材料的合成及去除水中Cr(VI)的研究[J].中国无机分析化学,2017,7(2):1-5.
YUAN Yonghai,YIN Changhui,SHI Yihua,YANG Zhongping.Synthesis of Graphene-supported Nano Fe (0) and Removal of Cr(VI) from Aqueous Solution[J].Chinese Journal of Inorganic Analytical Chemistry,2017,7(2):1-5.
袁永海,尹昌慧,施意华,杨仲平.石墨烯负载零价纳米铁材料的合成及去除水中Cr(VI)的研究[J].中国无机分析化学,2017,7(2):1-5.
YUAN Yonghai,YIN Changhui,SHI Yihua,YANG Zhongping.Synthesis of Graphene-supported Nano Fe (0) and Removal of Cr(VI) from Aqueous Solution[J].Chinese Journal of Inorganic Analytical Chemistry,2017,7(2):1-5.