Investigations of structure and transport in lithium and silver borophosphate glasses |
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| Institution: | 1. Inamori School of Engineering at the New York State College of Ceramics, Alfred University, 1 Saxon Drive, Alfred, NY 14802, USA;2. Department of Physics & Astronomy and Center for High Technology Materials, University of New Mexico, Albuquerque, NM 87131, USA;3. Science and Technology Division, Corning Incorporated, Corning, New York 14831, USA;4. Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vassileos Constantinou Avenue, 11635 Athens, Greece;1. School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan, Shanxi, P. R. China;2. School of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, P. R. China;1. Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA 16802, United States;2. Department of Glass Science, Alfred University, Alfred, NY 14802, United States |
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| Abstract: | Glasses in the system xLi2O·(1−x)0.5B2O3·0.5P2O5] and xAg2O·(1−x)0.5B2O3·0.5P2O5] have been prepared from melt quenching method. Glasses have been characterized for their densities, molar volumes, glass transition temperatures and heat capacities. Structural studies have been done using infrared and high resolution magic angle spinning nuclear magnetic resonance (HR MAS NMR) of 31P, 11B and 7Li nuclei. Boron is present only in tetrahedral coordination except in Li2O-rich glasses. Transport properties have been investigated over a wide range of frequency and temperature. Silver containing glasses are found to possess higher conductivities and lower barriers than lithium containing glasses. A structural model has been proposed in which pure B2O3–P2O5 compositions are assumed to be constituted of BPO4 units and modification occurs selectively on the phosphate moiety. Tetrahedral boron units are thus expected to be retained in the glass structure. |
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