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Scission of C–O and C–C linkages in lignin over RuRe alloy catalyst
作者姓名:Xinxin Li  Yangming Ding  Xiaoli Pan  Yanan Xing  Bo Zhang  Xiaoyan Liu  Yuanlong Tan  Hua Wang  Changzhi Li
作者单位:1. CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences;2. University of Chinese Academy of Science
基金项目:The National Natural Science Foundation of China (22078317, 21878288, 21721004, 21690083);
摘    要:The performance of lignin depolymerization is basically determined by the interunit C–O and C–C bonds.Numerous C–O bond cleavage strategies have been developed, while the cleavage of C–C bond between the primary aromatic units remains a challenging task due to the high dissociation energy of C–C bond.Herein, a multifunctional Ru Re alloy catalyst was designed, which exhibited exceptional catalytic activity for the cleavage of both C–O and C–C linkages in a broad range of lignin model compounds(β...

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