Synthesis of N3-substituted methyl exo-3,4-diazatricyclo[5.2.1.02,6]dec-4-ene-5-carboxylates |
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| Authors: | V. A. Gorpinchenko D. V. Petrov L. V. Spirikhin V. A. Dokichev Yu. V. Tomilov |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, 450054, Russia;(2) Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia |
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| Abstract: | Reactions of methyl exo-3,4-diazatricyclo[5.2.1.02.6]dec-4-ene-5-carboxylate with methyl diazoacetate, methyl iodide, ethylene oxide, acetic acid, nitrosonium cation, and sulfur led to the formation of a series of N3-substituted exo-3,4-diazatricyclo[5.2.1.02,6]dec-4-enes. |
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