Intermolecular Cope-type hydroamination of alkynes using hydrazines |
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Authors: | Cebrowski Pamela H Roveda Jean-Grégoire Moran Joseph Gorelsky Serge I Beauchemin André M |
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Affiliation: | Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, Ottawa, ON, Canada. |
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Abstract: | Metal-free, intermolecular hydroaminations are performed upon heating aryl acetylenes and MeNHNH(2) at 140 degrees C, with preferential formation of the linear, "anti-Markovnikov" hydrazones. |
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