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Effect of single-walled carbon nanotubes with imide cycles on the synthesis and properties of polycaproamide
Authors:O. N. Zabegaeva  D. A. Sapozhnikov  A. V. Krestinin  V. A. Kotel’nikov  B. A. Baiminov  Ya. S. Vygodskii
Abstract:The anionic polymerization of ε-caprolactam in the presence of single-walled carbon nanotubes with grafted acyllactam groups or polyimide macromolecules is performed. It is shown that the polymerization of ε-caprolactam slows down with an increase in the filler concentration. The introduction of 0.01 wt % nanotubes with polyimide fragments into polycaproamide leads to a 25% increase in the compressive modulus. In this case, the Izod impact strength is 10 kJ/m2, that is, 150% higher than that for an unfilled polycaproamide or polycaproamide containing other types of nanotubes.
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