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Thermal splitting of Bis-Cu(II) octaphyrin(1.1.1.1.1.1.1.1) into two Cu(II) porphyrins
Authors:Tanaka Yasuo  Hoshino Wataru  Shimizu Soji  Youfu Katsuyuki  Aratani Naoki  Maruyama Norihiko  Fujita Shizuo  Osuka Atsuhiro
Affiliation:Department of Chemistry, Graduate School of Science, Kyoto University, Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency (JST), Kyoto 606-8502, Japan.
Abstract:When heated, bis-Cu(II) octaphyrin(1.1.1.1.1.1.1.1) is quantitatively split into two Cu(II) porphyrins both in solution and film states, which is accompanied by large absorption spectral changes.
Keywords:
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