A remarkably effective catalyst for the asymmetric transfer hydrogenation of aromatic ketones in water and air |
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| Authors: | Wu Xiaofeng Vinci Daniele Ikariya Takao Xiao Jiangliang |
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| Institution: | Liverpool Centre for Materials and Catalysis, Department of Chemistry, University of Liverpool, Liverpool, UKL69 7ZD. |
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| Abstract: | A Rh(III) complex generated in situ from Cp*RhCl2]2 and (1R,2R)-N-(p-toluenesulfonyl)-1,2-cyclohexanediamine (TsCYDN) serves as a remarkably effective, robust catalyst for the asymmetric transfer hydrogenation of aromatic ketones by HCOONa in water in air, affording alcohols in up to 99% ee. |
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