ESR study of free radicals chemically generated at high pressure |
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| Authors: | F Szcs and M Kimová |
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| Institution: | (1) Polymer Institute of the Slovak Academy of Sciences, 809 34 Bratislava, Czeczhoslovakia |
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| Abstract: | Free radicals generated by the thermal decomposition of benzoyl peroxide in polyacrylnitrile were studied by the ESR method at 700 MPa between 100 and 130°C. The formation and decay of macroradicals were investigated and the mechanism of macroradical generation is discussed.
                          700 MPa 100 130°C.    .
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