Synthesis and Crystal Structure of a Ni(Ⅱ) Complex of 2'-[4-N,N'-(Dimethylaminobenzyl- idene)]-3,5-dihydroxybenzoylhydrazide and Its Spectral Properties |
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作者姓名: | JIA Wen-Ping ;YANG Jian-Guo ;LI Fang ;PAN Fu-Youa |
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作者单位: | JIA Wen-Ping,LI Fang,PAN Fu-You(Department of Chemistry, Taizhou University, Taizhou 317000, China);YANG Jian-Guo(Office of Assets Administration, Taizhou University, Taizhou 317000, China) |
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基金项目: | Project supported by the Natural Science Foundation of Zhejiang Province (Y406049);Education Committee Foundation of Zhejiang Province (No. 20060079) |
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摘 要: | A new nickel(II) complex NiL2](DMF)4 (HL = 2'-4-N,N'-(dimethylamino- benzylidene)]-3,5-dihydroxybenzoylhydrazide) has been synthesized and its structure was characterized by IR,UV-Vis,1H NMR and elemental analysis. The fluorescence emission mechanism of the complex was discussed by fluorimetric spectra. The single-crystal structure was determined by X-ray diffraction analysis. The crystal belongs to the triclinic system,space group P1 with a = 0.9918(4),b = 1.1297(4),c = 1.1331(4) nm,α = 76.860(7),β = 75.105(6),γ = 89.022(7)°,V = 1.1936(8) nm^3,Z = 1,μ = 0.472 mm^-1,Dc = 1.319 g/cm^3,F(000) = 502 and Rint = 0.0913. In the title compound,the nickel(II) atom is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. The complex is centrosymmetric with nickel located at the center.
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关 键 词: | 镍(Ⅱ)配合物 单晶体结构 氮原子 光谱特性 合成 X射线衍射分析 荧光光谱 标题化合物 |
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