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| 混配配合物[Zn(acac)2(C5H4NOH)]的合成、晶体结构及表征 | |
| 引用本文： | 马卫兴,钱保华,程青芳,许兴友,陆路德,宋海斌.混配配合物[Zn(acac)2(C5H4NOH)]的合成、晶体结构及表征[J].无机化学学报,2006,22(11):2101-2104. |
| 作者姓名： | 马卫兴 钱保华 程青芳 许兴友 陆路德 宋海斌 |
| 作者单位： | 1. 江苏省海洋生物技术重点建设实验室,淮海工学院,连云港,222005;淮海工学院化学工程系,连云港,222005 2. 淮海工学院化学工程系,连云港,222005;南京理工大学材料化学实验室,南京,210094 3. 淮海工学院化学工程系,连云港,222005 4. 南京理工大学材料化学实验室,南京,210094 5. 南开大学化学学院,天津,300071 |
| 基金项目： | 江苏省自然科学基金;江苏省高校自然科学基金;江苏省海洋生物技术重点建设实验室研究基金;淮海工学院校科研和教改项目 |
| 摘 要： | The complex Zn(acac)2(C5H4NOH)] was synthesized based on the reaction of zinc(Ⅱ) acetate, acetylaceton and 3-hydroxypyridine(C5H4NOH) in methanol medium. The structure of the complex was confirmed by IR, 1H NMR, elemental analysis, thermal analysis and X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group P21/n, and a=0.743 7(3) nm, b=0.829 5(3) nm, c=2.612 5(9) nm, β=95.026(6)°, V=1.605 4(9) nm3; Dc=1.484 g·cm-3; Z=4; F(000)=744; μ=1.551 mm-1. Zinc(Ⅱ) atom lies at the center of an coordination of the distorted square pyramidal formed by four O atoms which come from two different acetylaceton ions and one N atom from the 3-hydroxypyridine molecule. CCDC: 600232. |
| 关 键 词： | Zn(Ⅱ)配合物 混配配合物 谱学表征 晶体结构 |
| 文章编号： | 1001-4861（2006）11-2101-04 |
| 收稿时间： | 2006-03-23 |
| 修稿时间： | 2006-08-31 |
Synthesis, Crystal Structure and Spectral Characterization of the Complex [Zn(acac)2(C5H4NOH)] |
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| MA Wei-Xing,QIAN Bao-Hu,CHENG Qing-Fang,XU Xing-You,LU Lu-De and SONG Hai-Bin.Synthesis, Crystal Structure and Spectral Characterization of the Complex [Zn(acac)2(C5H4NOH)][J].Chinese Journal of Inorganic Chemistry,2006,22(11):2101-2104. | |
| Authors: | MA Wei-Xing QIAN Bao-Hu CHENG Qing-Fang XU Xing-You LU Lu-De and SONG Hai-Bin |
| Institution: | Jiangsu Provincial Key Laboratory of Ocean Biotechnology, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005;Department of Chemical Technology, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005,Department of Chemical Technology, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005;Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Department of Chemical Technology, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005,Department of Chemical Technology, Huaihai Institute of Technology, Lianyungang, Jiangsu 222005;Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094,Materials Chemistry Laboratory, Nanjing University of Science & Technology, Nanjing 210094 and College of Chemistry, Nankai University, Tianjin 300071 |
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