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Beiträge zur Chemie der Pyrrolpigmente, 82. Mitt.: Wasserlösliche Polymere mit kovalent gebundenen violinoiden und 2,3-dihydro-verdinoiden Gallenfarbstoffen
Authors:Heinz Falk  Karl Grubmayr  Martha Marko
Institution:(1) Institut für Chemie, Johannes-Kepler-Universität, A-4040 Linz, Austria
Abstract:Summary A violinoid and a 2,3-dihydrobilindione chromophore is attachedvia an appendix anchored at rings A of the pigments by means of reacting them with the polyacryl-N-acryloxysuccinimid copolymer to yield water-soluble chromopolymers. They are characterized by a molecular mass of about 4000 to 6000 and a relation of one chromophoric unit per 6 to 22 monomers. Their absorption spectra and circular dichroism recorded in water and dimethylsulfoxide as solvents are discussed with respect to structural aspects, and in comparison with monomeric chromophore derivatives.
Herrn Prof. Dr. K. Schlögl mit den besten Wünschen zum 65. Geburtstag gewidmet
Keywords:Polyacryl-N-acryloxysuccinimid copolymer  Water-soluble polymer  Biladiene-bc  2  3-Dihydrobilindione  Absorption spectra
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