Poly(4-vinylpyridinium tribromide) as metal-free and recoverable oxidizing agent for the selective oxidation of alcohols, and oxidative deprotection of trimethylsily ethers |
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| Authors: | Mohammad Ali Zolfigol Maryam Hajjami Arash Ghorbani-Choghamarani |
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| Institution: | 1. Faculty of Chemistry, Bu-Ali Sina University, P.O. Box 6517838683, Hamadan, Iran
2. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran
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| Abstract: | Poly(4-vinylpyridinium tribromide) was found to be an efficient oxidizing polymer for the chemoselective oxidation of a wide range of alcohols into aldehydes and ketones. In addition it was used for the oxidative deprotection of trimethylsilyl ethers into alcohols or carbonyl compounds depending on the structure of trimethylsilyl ether. |
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