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Crystal structure of the hemitoluene solvate of racemiccis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate,a species with disordered PPr3 and toluene moieties |
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| Authors: | Melvyn Rowen Churchill Ronald F. See Carol A. Bessel Kenneth J. Takeuchi |
| Affiliation: | (1) Department of Chemistry, Natural Sciences & Mathematics Complex, North Campus, University at Buffalo, State University of New York, 14260-3000 Buffalo, New York, 14260-3000;(2) Present address: Department of Chemistry, Saint Louis University, 63103 St. Louis, Missouri;(3) Department of Chemistry, Villanova University, 19085 Villanova, Pennsylvania |
| Abstract: | The complexcis-[Ru(bpy)2(PPr3)Cl+][ClO4–] · 0.5 (toluene) crystallizes as a racemate in the monoclinic space group P21/n. Both the PPr3 ligand and the toluene of crystallization are subject to disorder. Ruthenium—ligand distances are: Ru–PPr3=2.348(2) Å, Ru–Cl=2.426(2) Å and Ru–N(bpy)=2.035(6)–2.112(5) Å. |
| Keywords: | Ruthenium(II) complex tri-n-propylphosphine bipyridyl crystal structure disorder |
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