Reactions of unsymmetrical α‐diazo‐β‐diketones with imines: Syntheses of 4H‐1,3‐oxazin‐4‐ones |
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Authors: | Jiaxi Xu Liangbi Chen |
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Abstract: | Cycloaddition reactions of an unsymmetrical α‐diazo‐β‐diketone, 2‐diazo‐1‐phenyl‐1,3‐butanedione, with a series of imines having various substituents were studied. The results indicated that only cycloadducts derived from acetylphenylketene, which was generated by the thermal Wolff rearrangement of 2‐diazo‐1‐phenyl‐1,3‐butanedione with phenyl migration, and imines were obtained. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:165–168, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10015 |
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