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Rigid-ladder polymers: Polymers containing anthraquinone recurring units
Authors:Byung H Lee  C S Marvel
Abstract:In an attempt to synthesize some processable ladder or partial ladder polymers containing anthraquinone recurring units, leucoquinalizarin was treated with 3,3′-diaminobenzidine. This polymer, which was a black powdery material, was slightly soluble in concentrated sulfuric acid and dimethylsulfoxide. Also, 1,5-diamino-2,6-dimercaptoanthraquinone was condensed with 2,5-dichloro-p-benzoquinone in pyridine to give a black powdery polymer. This was only partially soluble in concentrated sulfuric acid, but could be solubilized in alkali by reduction with sodium dithionite.
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