Electrosynthesis of heteroaromatic aldehydes by palladium-catalyzed carbonylation of heteroaromatic iodides in the presence of formic acid |
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| Authors: | Isabella Chiarotto Marta Feroci |
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| Institution: | Università degli studi di Roma “La Sapienza”, Dipartimento di Ingegneria Chimica, dei Materiali delle Materie Prime e Metallurgia, 7, via Castro Laurenziano, Roma I-00161, Italy |
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| Abstract: | The palladium-catalyzed electrocarbonylation of heteroaromatic iodides, performed in the presence of formic acid under one atmosphere of carbon monoxide, affords heteroaromatic aldehydes in moderate to good yields. It has been developed a new application of palladium-catalyzed formylation using carbon monoxide, formic acid and tertiary amines as ligands under electrochemical reducing conditions. |
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| Keywords: | Palladium Homogeneous catalysis Carbon monoxide Heteroaromatic Formic acid Electrochemistry Amines |
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